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71.
72.
Free cupric ion concentrations and Cu complexation in selected Swiss lakes and rivers 总被引:1,自引:0,他引:1
Hanbin Xue Andrea Oestreich David Kistler Laura Sigg 《Aquatic Sciences - Research Across Boundaries》1996,58(1):69-87
[Cu2+] and Cu complexation parameters in some selected freshwater systems in Switzerland were determined by the technique of ligand-exchange and DPCSV. Results from the water columns of some eutrophic and oligotrophic lakes are presented and compared to small acid lakes. Cu is strongly complexed by organic ligands which with very high stability constants at low concentrations are probably biologically produced, as indicated by the seasonal variations in the eutrophic lakes and by the relationship between Cu complexation and algal activity in the eutrophic (pCu=15–16), oligotrophic (pCu=13–14) and acidic (pCu=9–10) lakes. The extent of Cu complexation in river waters was generally lower than in the eutrophic lakes, at similar DOC levels. No obvious correlation between Cu complexation and DOC was observed, indicating that Cu complexing ligands are specific organic compounds. 相似文献
73.
吉林基性超基性岩的地质特征及找矿方向 总被引:3,自引:0,他引:3
从多旋回大地构造演化的观点,分析吉林区域多旋回的构造运动,控制多旋回的基性超基性岩浆活动及其相应的成矿作用,认为与含镍有关的基性超基性岩体,主要受“台槽边界”赤峰—开源深断裂控制,沿深断裂一侧或两侧成带分布,分群集中。为铜镍矿床区域勘查工作,提供地质资料。 相似文献
74.
应用轻便型X射线荧光仪进行现场原位测量铜元素含量,可以了解铜元素的分布特征,划分矿与非矿界线,从而指导铜矿床勘查。并列举6个铜矿床应用实例,来说明该技术方法的应用效果。其优点是仪器轻便,原位测量快速,勘查成本降低。 相似文献
75.
By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO3 leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type. 相似文献
76.
湖北省铜山口铜(钼)矿床成矿流体水岩反应数值模拟 总被引:1,自引:1,他引:0
湖北省铜山口铜(钼)矿床是一典型的夕卡岩 斑岩复合型矿床。通过对其流体包裹体的系统研究,确定了成矿流体的成分及温压条件;结合矿床学的研究,将成矿过程分解为两个平行的成矿阶段,即夕卡岩型矿化阶段和斑岩型矿化阶段。根据Johnson和Reed等人建立的水 岩反应模型,对该矿床的成矿流体与围岩的反应并析出金属沉淀的过程进行了数值模拟计算。结果表明:在斑岩型矿化阶段,成矿流体系统出现等焓减压沸腾过程并沉淀出大量的金属矿物,成矿流体分异为低盐度流体和高盐度流体;在夕卡岩型成矿阶段,沉淀出典型的夕卡岩矿物;在整个成矿过程中,成矿流体的pH值逐渐升高。模拟计算结果与实际地质现象非常吻合,说明所建立的水 岩反应模型可以为理解这一类复合型金属热液矿床的形成机制提供一个新的思路。 相似文献
77.
云南铜矿是历史上开发最早的地区之一,至今已知的大-中型矿区(除边远的羊拉、托顶之外),历史上几乎都不同程度地被开采过。也有历史上曾采冶辉煌,但至今却没有铜矿产出,找铜工作者也不知道的“古老铜矿”,俞元(澄江)铜矿即是一例。研究、考证采铜史料,认为澄江铜矿、东川茂麓厂、寻甸铜矿、永平宁台厂等,应列为新世纪重新评价的找铜目标。 相似文献
78.
Evolution of Ore-Forming Fluids and Ag-Cu Polymetal Mineralization in the Lanping Basin, Yunnan 总被引:1,自引:0,他引:1
EVOLUTION OF ORE-FORMING FLUIDS AND Ag-Cu POLYMETAL MINERALIZATION IN THE LANPING BASIN, YUNNAN“KeyProjectforResourcesandEconomics” (95 0 2 0 0 1 0 1)oftheMinistryofLandResources 相似文献
79.
The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions. 相似文献
80.