秋茄和榕树叶片中正构烷烃分布和单体化合物δ13C值及其光合作用   总被引：1，自引：0，他引：1  

李宝才  董玉莲  李超  周建元  闻克威  盛国英  傅家谟 《热带海洋学报》2003,22(1):62-69

对深圳福田、阳江、海南新竹红树林秋茄Kandelia candel及海口榕树Ficusm icrocarpa叶中类脂物进行萃取,分离出正构烷烃,通过气相色谱(GC)及色谱-质谱(GC MS)分析,测出了正构烷烃的碳数分布和相对含量.气相色谱-稳定同位素比质谱仪(GC-IRMS)测定了正构烷烃单体化合物的稳定同位素组成δ13C.秋茄叶和榕树叶正构烷烃的碳数分布均为C17C33,主要集中在C23-C31(＞90%).化合物含量最高为C27的有深圳福田秋茄、海南新竹秋茄、海口榕树,而阳江秋茄为C25.单体化合物的稳定同位素δ13C深圳福田秋茄为-31.42‰-34.48‰,阳江秋茄为-31.69‰-33.62‰,海南新竹秋茄为-30.30‰-33.04‰,海口榕树为-29.92‰33.56‰;平均值分别为-32.95‰、32.67‰、31.67‰、-31.74‰.结果表明,秋茄和陆地植物榕树的光合作用都是通过C3途径,是典型C3植物.  相似文献   

TOPCON GTS901A机载程序设计     

洪诗聘  陈雪丰  林鸿荣 《测绘信息与工程》2008,33(6):37-38

介绍了基于Windows CE嵌入式操作系统,开发了TOPCON智能型全站仪GTS901A机载程序的方法,实现了学习测量、自动测量、数据存储及处理等功能。  相似文献   

河南理工大学校园导航系统的设计与实现     

文广超  邓寅生  余永强  谢俊  严明波 《测绘信息与工程》2008,33(2):38-40

利用了SuperMap Objects组件,构建了C/S模式的河南理工大学校园导航系统,实现了信息查询、路径导航、办事指南、地图与数据编辑、数据输出、用户管理及三维虚拟校园导航等功能,并提供了与现有校园系统集成的接口.  相似文献   

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China     

Qi Wang  Xizhun Zhuo  Guojun Chen  Xiaoyan Li 《中国地球化学学报》2008,27(3):249-256

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.  相似文献   

Coalification in Carboniferous sediments from the Lötschberg base tunnel     

David J. A. Williams  Beda A. Hofmann  Ian G. Glasspool 《Swiss Journal of Geoscience》2008,101(3):651-658

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.  相似文献   

封闭体系有机质与有机碳氢氮恢复动力学研究   总被引：3，自引：0，他引：3  

彭平安  秦艳  张辉  刘大永  张善文  隋风贵  李钜源  李政 《海相油气地质》2008,13(2):27-36

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献   

The “Zero-order Model” revisited: Paul Schindler's influence on the development of trace metal scavenging models     

Santschi  Peter H.  Honeyman  Bruce D.  Quigley  Matthew S. 《Aquatic Sciences - Research Across Boundaries》1993,55(4):230-239

In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models.  相似文献   

Kinetics of redox cycling of iron coupled with fulvic acid     

Yiwei Deng  Werner Stumm 《Aquatic Sciences - Research Across Boundaries》1993,55(2):103-111

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.  相似文献   

Diagenesis of vascular plant organic matter components during burial in lake sediments   总被引：12，自引：0，他引：12  

Philip A. Meyers  Mary J. Leenheer  Richard A. Bourbonniere 《Aquatic Geochemistry》1995,1(1):35-52

Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither ¹³C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components.  相似文献   

The role of sediments in the phosphorus cycle in Lake Lugano. I. Geochemical approach     

D. Span  J. Dominik  M. A. Lazzaretti  J. -P. Vernet 《Aquatic Sciences - Research Across Boundaries》1992,54(3-4):277-284

The bottom sediment from three coring stations in Lake Lugano (Lago di Lugano) show major differences in their role in the P-cycles related to their geochemistry and characteristics of sedimentation. In the northern basin, the deepest sediment may be considered practically inactive, due to a permanently reduced condition at the sediment-water interface. In the southern basin, the sediments are active with respect to P-recycling with strong seasonal variations. One of the sites (Figino) behaves as a sink for P due to a high iron content and an important rate of detrital sedimentation.  相似文献