西秦岭三个典型金矿床稳定同位素地球化学特征   总被引：15，自引：2，他引：15       下载免费PDF全文

冯建忠汪东波  王学明邵世才 《中国地质》2004,31(1):78-84

据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素研究,金矿床δ34S比正常沉积岩变化范围窄,比岩浆-火山岩型矿床宽,硫源是海水硫酸盐还原硫与深部热液来源硫所组成的混合硫。石英包裹体流体氢、氧同位素分布于岩浆水、大气降水的重叠过渡区,更靠近岩浆水区,岩浆水的同位素特征更明显。八卦庙金矿石英脉3He/4He高于地壳3He/4He值(n×10-8),低于地幔3He/4He值(n×10-5),为壳-幔混合源。上述同位素地球化学证据表明,金成矿与岩浆岩有一定的成因关系。岩浆岩与金矿床空间关系密切,矿区内脉岩发育,脉岩为矿体的上下盘。含矿岩石中发育斑点构造,斑点为黄铁矿、磁黄铁矿、毒砂、绿泥石、石英、绢云母、黑云母、堇青石、红柱石、电气石、碳酸盐等热变质矿物和热液交代矿物,表明花岗岩为成矿提供热动力。据八卦庙金矿、李坝金矿、小沟里金矿稳定同位素地球化学研究,结合成矿地质背景分析和区域成矿地质特征对比,认为凤太、西成、礼岷地区金矿与微细浸染型(卡林型)金矿有明显的差别,该区金矿类似于岩浆热液矿床。  相似文献   

Kinetic-simulating experiment combined with GC-IRMS analysis: application to identification and assessment of coal-derived methane from Zhongba Gas Field (Sichuan Basin, China)   总被引：2，自引：0，他引：2  

Yongqiang Xiong  Ansong Geng  Jingzhong Liu 《Chemical Geology》2004,213(4):325-338

The main purpose of this study is to model the δ¹³C values of methane derived from coal by combining kinetic-simulating experiment with the gas chromatography-isotope ratio mass spectrum (GC-IRMS) analysis. The stable carbon isotopic variation of methane in pyrolysates with heating temperature indicates that the assumptions for both a constant kinetic isotope effect (α) and a uniform initial isotopic composition (δ¹³C_o) are impractical for explaining the carbon isotopic fractionation during coalification. For purposes of simplification, two approaches are used in this paper to deal with the heterogeneity of terrestrial organic matter. One is that, assuming a uniform initial isotopic composition (i.e., δ¹³C_{i, o}=δ¹³C_o) for all methane-generating precursors in coal, the isotopic variation of methane is fitted by adjusting ΔE_{a, i} (E_{a¹³C, i}−E_{a¹²C, i}) for each hypothetical reaction. The other is that, assuming a constant kinetic isotope effect during the whole gas formation, that is all ΔE_{a, i} values are identical, the modeling of methane isotopic composition is achieved by changing the ¹³CH₄ generation potential of each reaction (f_{i, ¹³C}), namely, by adjusting the initial δ¹³C value (δ¹³C_{i, o}) for each methane-generating precursor. Results of the kinetic calculation shows that the two simulating methods can yield a similar result at a geological heating rate of 2 °C/My, which further demonstrates that those natural gases with methane δ¹³C value being approximately −36‰ are possibly sourced from the upper Triassic coal measure strata in the Northwestern Sichuan Basin.  相似文献   

Petrology and Geochemistry of Early Cretaceous Bimodal Continental Flood Volcanism of the NW Etendeka, Namibia. Part 1: Introduction, Mafic Lavas and Re-evaluation of Mantle Source Components   总被引：9，自引：4，他引：9  

EWART  A.; MARSH  J. S.; MILNER  S. C.; DUNCAN  A. R.; KAMBER  B. S.; ARMSTRONG  R. A. 《Journal of Petrology》2004,45(1):59-105

The bimodal NW Etendeka province is located at the continentalend of the Tristan plume trace in coastal Namibia. It comprisesa high-Ti (Khumib type) and three low-Ti basalt (Tafelberg,Kuidas and Esmeralda types) suites, with, at stratigraphicallyhigher level, interstratified high-Ti latites (three units)and quartz latites (five units), and one low-Ti quartz latite.Khumib basalts are enriched in high field strength elementsand light rare earth elements relative to low-Ti types and exhibittrace element affinities with Tristan da Cunha lavas. The unradiogenic²⁰⁶Pb/²⁰⁴Pb ratios of Khumib basalts are distinctive, most plottingto the left of the 132 Ma Geochron, together with elevated ²⁰⁷Pb/²⁰⁴Pbratios, and Sr–Nd isotopic compositions plotting in thelower ¹⁴³Nd/¹⁴⁴Nd part of mantle array (EM1-like). The low-Tibasalts have less coherent trace element patterns and variable,radiogenic initial Sr (  相似文献   

The Relationship between Tectono-metamorphic Evolution and Argon Isotope Records in White Mica: Constraints from in situ 40Ar-39Ar Laser Analysis of the Variscan Basement of Sardinia     

DI VINCENZO  GIANFRANCO; CAROSI  RODOLFO; PALMERI  ROSARIA 《Journal of Petrology》2004,45(5):1013-1043

The basement of Sardinia represents a nearly complete sectionof a segment of the Variscan belt that experienced a polyphasetectono-metamorphic evolution and Barrovian metamorphism. Thisbasement is well suited to investigate the relationship betweentectono-metamorphic evolution and argon isotope records in whitemica. Micaschists from the garnet zone (maximum T of up to 520–560°C)contain two texturally and chemically resolvable generationsof white mica: (1) deformed celadonite-rich flakes, defininga relict S₁ foliation preserved within the main S₂ foliationor enclosed in rotated albite porphyroblasts; (2) celadonite-poorwhite micas aligned along the main S₂ foliation. The S₁ foliationdeveloped earlier and at a deeper crustal level with respectto that at which the thermal peak was reached. From the staurolitezone (T of up to 590–625°C) to the sillimanite + K-feldsparzone, white mica is nearly uniform in composition (muscovite)and is predominantly aligned along the S₂ foliation or is oflater crystallization. In situ ⁴⁰Ar–³⁹Ar laser analysesof white mica yielded ages of  相似文献   

Comparisons on seasonal and annual variations of δ~(18)O in precipitation     

ZHANG Xinping  YAO Tandong 《地理学报(英文版)》2004,(2)

interpretationofpaleoclimaticrecordsinicecore(Dansgaardetal.,1969;Rozanskietal.,1997;Yao,1999;Thompsonetal.,2000).SincethefirstdeepicecorewasdrilledinGreenlandin1966(Dansgaardetal.,1969),hundredsoficecoreswereobtainedsuccessivelyfromicesheetsinAntarcticaandArctic,andmountainglaciersatmid-highlatitudes,fundedbynumerousresearchprogramsonglobalclimateandenvironmentalchange.Theseicecoresprovideuniqueandvaluablefirst-handinformationinrecoveringglobalpaleoenvironmentalrecordsandforecastingfuturecl…  相似文献   

环境同位素记录中共生碳酸盐氧同位素分馏差值的影响          下载免费PDF全文

曾承  余俊清 《盐湖研究》2004,12(2):14-18

湖泊化学沉积碳酸盐δ18O是研究区域气候演变的重要环境指标之一。青海湖等闭流湖泊的研究结果证实,在对δ18O环境记录进行共生碳酸盐氧同位素分馏效应校正时,应依据具体情况,采用0-1‰的分馏差值。由高温实验结果推断出的常温分馏差值(4‰-7‰)不能被应用到自然条件下湖泊共生碳酸盐氧同位素分馏效应的校正。  相似文献   

Modern stable isotopic (δ18O, δ2H, δ13C) variation in terrestrial,fluvial, estuarine and marine waters from north‐central Sarawak,Malaysian Borneo     

Mark Stephens  James Rose 《地球表面变化过程与地形》2005,30(7):901-912

Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta¹⁸O, δ²H and δ¹³C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ¹⁸O ?4·6‰; δ²H ?29·3‰; δ¹³C ?4·8‰) from the tributary stream (δ¹⁸O ?8·4‰; δ²H ?54·7‰; δ¹³C ?14·5‰) to up‐river (δ¹⁸O c. ?8‰; δ²H c. ?51‰; δ¹³C c. ?12‰) and down‐river values (δ¹⁸O c. ?7·5‰; δ²H c. ?45‰; δ¹³C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ¹³C (plant respiration and decay) with enriched δ¹³C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ¹³C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Geochemistry of ore-forming fluids and geological significance of the Kuoerzhenkuola gold field in Xinjiang, China     

SHEN Ping  SHEN Yuanchao  LIU Tiebing  LI Guangming & ZENG Qingdong Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing  China 《中国科学D辑(英文版)》2005,48(11)

The Kuoerzhenkuola gold field (including the Kuo- erzhenkuola and the Buerkesidai gold deposits), lo- cated 68 km east of Jimunai County in northern Xing- jiang, China, is an important component of the Sawuer gold belt which is the eastward extending part of the Zarma-Sawur gold-copper belt in Kazakhstan. Some studies are concerned with the geology of the gold ores[1―3], the associated volcanic rocks[4], radiogenic isotope[5―8], and the ore-forming environment[8]. Most researchers inferr…  相似文献   

Isotopic evidence of TSR origin for natural gas bearing high H_2S contents within the Feixianguan Formation of the northeastern Sichuan Basin, southwestern China   总被引：9，自引：0，他引：9  

ZHU Guangyou  ZHANG Shuichang  LIANG Yingbo  DAI Jinxing & LI Jian Research Institute of Petroleum Exploration  Development  PetroChina  Beijing  China 《中国科学D辑(英文版)》2005,48(11)

Isotopic evidence of TSR origin for natural gas bearing high H2S contents 1961 As the hazardous component of natural gas, the ex-istence of H2S, due to its extremely strong toxicity and corrosivity, not only decreases the percentage of hy-drocarbon gas within natural gas and reduces its in-dustrial value, it also threatens each aspect of drilling and exploitation. It frequently causes serious safety accidents[1] and leads to the E&P cost and risk of natural gas with higher H2S contents be…  相似文献   

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China   总被引：2，自引：0，他引：2  

WANG Min 《中国地球化学学报》2005,24(4):297-305

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.  相似文献