石灰性土壤中有效磷的电感耦合等离子体发射光谱法测定     

李小娜  王金云  程丽娅  刘文长 《安徽地质》2014,(4):296-299

方法采用0.5 mol/L NaHCO3浸提石灰性土壤中的有效磷,电感耦合等离子体原子发射光谱法测定。研究了土壤滤液的酸化、颜色、浸提温度以及振荡时间等对浸提结果的影响,方法检出限(3s)为0.18 mg/kg,定量限(6s)为0.36 mg/kg,通过对石灰性土壤有效态标准物质GBW07413a、GBW07459和GBW07460的12次测定,方法准确度和精密度均小于4.5%。  相似文献   

Stratigraphy,age and petrography of the Beni Issef successions (External Rif; Morocco): Insights for the evolution of the Maghrebian Chain   总被引：1，自引：0，他引：1  

Angelida Di Staso  Vincenzo Perrone  Sonia Perrotta  Mohamed Najib Zaghloul  Michel Durand-Delga 《Comptes Rendus Geoscience》2010,342(9):718-730

In the Beni Issef Massif, nearly 30 km west of Chefchaouen (Morocco), the thickest post-nappe succession within the Rifian sector of the Maghrebian Chain seals the tectonic contact between the Intrarifian External Tanger and Loukkos Units, related to the Rifian External Domain. This succession is very important for the reconstruction of the deformation timing of the Rifian Maghrebids. The age of its base, in fact, is an important constraint for defining an upper boundary to the stacking of both the Intrarifian and Maghrebian Flysch Basin Units, because clasts fed by the Melloussa and Numidian Flysch Nappes are abundant in the conglomerate layers. Field and biostratigraphic analyses pointed out the presence of a Lower Beni Issef Fm, unconformable on the Intrarifian External Tanger and Loukkos Units, and an Upper Beni Issef Fm, unconformable on both the Intrarifian Units and the Lower Beni Issef Fm. The Lower Beni Issef Fm, 150 m thick, consists of lenticular conglomerates with huge blocks in a marly-clayey matrix, followed by marls and minor sandstones. It deposited in a siliciclastic platform, shows a fining upward trend and is affected by metre- to hectometre-sized, locally reversed, folds. Samples collected 45–50 m above the base of the formation resulted not older than Late Tortonian in age, but an older age for the base of the formation cannot be excluded. The Upper Beni Issef Fm, up to 550 m thick, starts with coarse conglomerates followed by medium- to coarse-grained well-bedded sandstones and by grey-blue marls and mudrocks. It indicates deposition in a channelized marine delta, with evolution towards pro-delta pelites, and shows sub-horizontal or gently dipping beds towards the east. Biostratigraphic data indicate a probable Messinian age for this formation. The composition of the arenites of both Lower Beni Issef and Upper Beni Issef Fms is quartzolithic and all samples show a notable content of monocrystalline well-rounded quartz and sedimentary lithic fragments. Detrital modes, all falling in the Quartzose Recycled and Transitional Recycled fields, suggest a provenance from recycling of sedimentary successions, easily recognizable in the Flysch Basin and External Units, mainly the Numidian Nappe sandstones. A Tortonian age of the Lower Beni Issef Fm would agree with the Late Serravallian age of the uppermost beds of the External Tanger Unit and indicate that the most probable age for the stacking of the Intrarifian Units falls in the Late Serravallian-Middle Tortonian time span. The Lower Beni Issef Fm was involved in a compressive tectonic phase testified by north-south striking folds. Later, probably during Messinian, the Upper Beni Issef Fm deposited in a younger intramontane basin, resting on both the Intrarifian Units and the Lower Beni Issef Fm. Successively, the Upper Beni Issef Fm was passively transported piggyback on top of the fold and thrust belt during later tectonic evolution of the Rifian Maghrebids. This tectonic evolution results quite similar to that recognized in the Tellian and Sicilian Maghrebids and also in the southern Apennines.  相似文献   

南黄海表层沉积物中钙质超微化石的分布     

芮晓庆  刘传联  梁丹  赵美训 《海洋地质与第四纪地质》2011,(5):89-93

对南黄海地区47个表层沉积物样品进行了钙质超微化石分析.结果表明,该区超微化石组合主要以Emiliania huxleyi和Gephyrocapsa oceanica占优势.钙质超微化石总丰度分布不一,主要受水深和黄海暖流的控制.E.huxleyi和G.oceanica两个优势种的平面分布规律也各不相同,E.huxle...  相似文献   

Astronomical calibration of the Valanginian “Weissert” episode: The Orpierre marl–limestone succession (Vocontian Basin,southeastern France)     

《Cretaceous Research》2013

A high-resolution, biostratigraphic (calcareous nannofossils, calpionellids), chemostratigraphic (C-isotope) and cyclostratigraphic (magnetic susceptibility) study was performed on the marl–limestone alternations of the Upper Berriasian–Valanginian Orpierre section, deposited in the hemipelagic setting of the Vocontian Basin (SE France). The main aims of this study were to detect orbital forcing, to estimate the duration of the Valanginian “Weissert” episode, and to discuss the palaeoenvironmental implications. Detailed calcareous nannofossil biochronology allowed the recognition of Upper Berriasian–Lower Hauterivian biohorizons. The general trends of the δ¹³C curve and the major positive C-isotope excursion (amplitude of 1.8‰) recorded at the Orpierre section are very similar to those found in other sections worldwide. Spectral analysis applied on high-resolution magnetic susceptibility (MS) variations coupled with frequency ratio method reveals a strong cyclic pattern related to the Earth's orbital parameters (precession, obliquity and eccentricity). The prominent 405 kyr eccentricity cycle in the MS signal and has been used as a geochronometer to time calibrate the section. The duration of the Weissert episode was estimated as 2.08 Myr. This duration is coherent with those obtained from the Umbria Marche Basin (∼2.3 Myr) and from the Angles section (∼2.14 Myr). Durations of more than 2 Myr suggest that a long perturbation in the dynamic of the global carbon cycle that is not compatible with the rapid and intense volcanic activity. Our cyclostratigraphic study indicates a minimal duration of 4.29 Myr for the Valanginian stage. The comparison between the MS signal at Orpierre and the spectral gamma-ray signal recently obtained in two composite sections of the Vocontian Basin allows to propose a revised duration for the Valanginian stage of 4.695 Myr instead of 5.08 Myr.  相似文献   

The Jurassic/Cretaceous boundary in the Apulco area by means of calpionellids and calcareous dinoflagellates: An alternative to the classical Mazatepec section in eastern Mexico     

《Journal of South American Earth Sciences》2013

A detailed bed-by-bed sampling within the Pimienta and the Lower Tamaulipas Formations from a section in the Apulco area (Puebla State, Eastern Mexico), allows the delimitation of the Jurassic/Cretaceous boundary. The Late Tithonian was identified by the presence of calpionellids of the Crassicollaria Zone (Colomi Subzone) and calcareous dinocysts of the Proxima Zone. The Tithonian/Berriasian boundary was placed at the acme of Calpionella alpina (small forms) between samples MZT 45–46. The Berriasian was divided into two main units, namely the Calpionella Zone, further subdivided into the Alpina, Ferasini and Elliptica subzones, and the Calpionellopsis Zone, within which only the Oblonga subzone was identified. The vertical distribution of calpionellids and their assemblages in the biozones of this Mexican section fit those from other Tethyan areas.  相似文献   

Calcareous Nannofossils and Molecular Fossils in Cobalt-rich Crusts and their Response to the P/E Global Event   总被引：1，自引：0，他引：1  

ZHANG Haisheng  ZHAO Jun  HAN Zhengbing  LU Bing  WU Guanghai  PULYAEVA  I. A. 《《地质学报》英文版》2013,87(5):1264-1274

A biostratigraphic study on calcareous nannofossils from the CM3D06 Co-rich ferromanganese crust from the Magellan seamounts in the northwestern Pacific enabled estimation of depositional age.The bio-imprinting of calcareous nannofossils and other fossil species suggests six age ranges for the nannofossils: late Cretaceous,late Paleocene,(early,middle,late) Eocene,middle Miocene,late Pliocene,and Pleistocene.Gas chromatography(GC) and gas chromatography-mass spectrometry(GC-MS) were used to test the Co-rich crusts,and a variety of molecular fossils were detected,such as chloroform bituminous "A",n-alkane,isoprenoid and sterol.Peak carbon and molecular indices(such as ΣC23 /ΣC24 +,CPI,Pr/Ph,Pr/nC17,Ph/nC18 and δ13C) indicate that the parent organic matter is dominated by marine phytoplankton and thallogen whereas there is little input of terrestrial organic matter.Researches on calcareous nannofossils,molecular fossils and molecular organic geochemistry data reveal that the Paleocene/Eocene(P/E) global event is recorded in the cobaltrich crusts from the northwestern Pacific Ocean.A succession of biomes can be observed near the 85 mm boundary(about 55 Ma),i.e.,the disappearance of the late Cretaceous Watznaueria barnesae and Zigodicus spiralis,and Broisonia parka microbiotas above the P/E boundary,and the bloom of Coccolithus formosus,Discoaster multiradiatus,Discoaster mohleri and Discoaster sp.below the boundary.Typical parameters of molecular fossils,such as saturated hydrocarbon components and carbon-number maxima,Pr/Ph,Pr/C17,Ph/C18,distribution types of sterols,Ts/Tm ratios and bacterial hopane,also exhibit dramatic changes near the P/E boundary.These integrated results illustrate that the biome succession of calcareous nannofossils,relative content of molecular fossils and molecular indices in the cobalt-rich crusts near the 85 mm boundary faithfully record the P/E global event.  相似文献   

Lago Mare and the Messinian Salinity Crisis: Evidence from the Alboran Sea (S. Spain)     

《Marine and Petroleum Geology》2014

This paper provides a new environmental, sedimentological and stratigraphic context of the Lago Mare deposits from the North Alboran region and clarifies their chronologic location with respect to the Messinian Salinity Crisis. We present new micropalaeontological data (dinoflagellate cysts, calcareous nannoplankton, planktonic foraminifers), correlated with field observations and offshore seismic interpretations. We show that the Lago Mare event known in three onshore localities (Río Mendelín near Malaga, Zorreras near Sorbas, Gafares near Níjar) follows the marine reflooding of the Mediterranean Basin which ended the Messinian Salinity Crisis. Chronologically, these Lago Mare deposits last from the latest Messinian to the early Zanclean. In fact, the first influx of Paratethyan organisms is revealed by the dinoflagellate cyst record from near Malaga within a Gilbert-type fan delta overlying the Messinian Erosional Surface. Invading molluscs and/or ostracods may have persisted in lagoonal coastal areas more or less affected by discontinuous marine influxes (Sorbas and Níjar). The Malaga area is convenient for a palaeogeographic and sedimentary reconstruction which shows the prevalent forcing of sea-level changes during the time-interval 5.600–5.332 Ma at the difference of the usually solicited prevalent tectonics. The studied Lago Mare event is the third episode resulting in such a palaeobiological assemblage in the Mediterranean region and corresponds to the final two-way water exchange at high sea level between the Mediterranean and the former Paratethys. It documents the onset of the modern marine circulation in the Mediterranean after the reflooding ending the Messinian Salinity Crisis.  相似文献   

Using a Simple Soil Column Method to Evaluate Soil Phosphorus Leaching Risk   总被引：3，自引：0，他引：3  

Yuyuan Li  Ru Gao  Rui Yang  Hongan Wei  Yong Li  Heai Xiao  Jinshui Wu 《洁净——土壤、空气、水》2013,41(11):1100-1107

The impacts of soil P leaching on water eutrophication have widely been concerned. However, there is no dependable method to quantitatively estimate the P leaching risk of soils. In this study, a simple soil column method was developed using two calcareous Fluvisols, silt loam and loam. The soil column was 20 cm in length and 5 cm in diameter, and distilled water was continuously supplied from the top. The volume and dissolved reactive P (DRP) concentrations of leachate were measured. Results showed that DRP concentrations in leachate increased slowly for the low soil Olsen‐P levels but rapidly for the high Olsen‐P levels. According to these two‐phase changes in the DRP versus soil Olsen‐P contents, the thresholds of P leaching risk were estimated to be 41.1 and 62.3 mg P kg^?1 (Olsen‐P) for silt loam and loam, respectively. The P leaching intensity of soils increased by 3‐ to 540‐fold if the soil Olsen‐P contents accumulated from 6.6 to 155.5 mg P kg^?1. The outcomes derived from this study regarding the determination of P leaching threshold and intensity by the soil column method also need a further verification on more soils with a wide range of physical and chemical properties.  相似文献   

High‐frequency subbottom reflection types and lithologic and physical properties of sediments     

Sunit K. Addy  E. William Behrens  Trent R. Haines  Donald J. Shirley  J. Lamar Worzel 《Marine Georesources & Geotechnology》2013,31(1):27-49

Abstract

Eight types of reflections are interpreted from 3,800 km of 3.5 kHz profiles taken over a 25,000 km² area of the upper continental slope and shelf in the northeastern Gulf of Mexico off Panama City, Florida. The corresponding sediments in five of the reflection types were sampled in 77 piston cores from which data were obtained on in situ acoustic velocities (V), bulk densities (gr), sediment texture (mean grain size = Mz), CaCO₃ content (C), sedimentary structures, and gross sediment composition. A distinct bottom echo with numerous subbottom reflectors (Type I) is observed in deeper areas where terrigenous clay or lutite (Mgi = 9.9 to, gr = 1.4 g/cc, porosity (P) = 74 percent, C = 28 percent, and V (upper 2 m) = 1,435 m/s) predominates. Type I reflection grades upslope into Type IV, which shows a distinct bottom echo with fewer subbottom reflectors, and the corresponding sediment is a foraminiferal silty clay (mz = 9.4 to, gr = 1.43 g/cc, P = 73 percent, V = 1,447 m/s, and C = 37 percent). The uppermost slope gives indistinct, semiprolonged bottom echoes with faint subbottoms (Type VI) where calcareous silt (Mz = 6.6 to, gr = 1.57 g/cc, P = 65 percent, C = 70 percent, and V = 1,482 m/s) is the main sediment type. The shelf sediments (gr = 1.66 g/cc, P = 58 percent, V = sl1,530 m/ s), varying from coarse silt (Mz = 5.3 to) to very coarse sand (Mz = ‐0.3 to) and 25 to 100 percent carbonate, show indistinct, semiprolonged bottom echoes with intermittent or mushy subbottoms (Type VII). Prolonged echoes with no subbottoms (Type VIII) are observed in areas where algal sands of variable grain size (Mz ‐ ‐0.9 to 2.7 to, gr = 1.66 g/cc, P = 59 percent, V = 1,530 to 1,690 m/s) occur.

The major trends in reflection types (loss in depth of penetration, loss in number of reflectors, and prolongation of initial bottom reflections) follow gradients of sedimentary and physical properties of the sediments, which are increases in mean grain size, bulk density, in situ acoustic velocity, CaCO₃ content, and decrease in porosity. Increases in the reflection coefficient and attenuation of the sound energy in the shelf sediments are probably important factors in the observed decrease in the depth of penetration of the sound energy in the shelf sediments.  相似文献   

Experimental study on the phase transformation point of crushable and noncrushable soils     

Habib Shahnazari  Mohammad Amin Tutunchian 《Marine Georesources & Geotechnology》2017,35(2):176-185

Two marine calcareous deposits as crushable soils and a siliceous sand as a noncrushable soil were used in this study to compare their monotonic response. Undrained monotonic triaxial tests were conducted on samples, which were prepared in different relative densities and consolidated under various confining pressures. The location of phase transformation point in undrained response of the sands in different initial conditions was evaluated. The effect of important parameters including relative density, confining pressure, particle shape, and particle breakage on phase transformation point was assessed. The input energy applied per unit volume of the soils was used to interpret the shearing response of crushable and noncrushable soils. The results showed that calcareous sands have more tendencies in contraction. Particle shape and breakage play a key role in engineering behavior of crushable soils.  相似文献