泥质岩盖层微观封闭能力的综合评价方法及其应用   总被引：4，自引：0，他引：4  

付广  张建英 《海相油气地质》1997,2(1):36-41

在深入研究盖层微观封闭机理及影响封闭能力的主要因素基础上，选取盖层／储层排替压力差、异常孔隙流体压力和异常含气浓度作为泥质岩盖层微观封闭能力的三个主要评价参数。通过对其划分等级，赋予权值，利用加权法求取泥质岩盖层微观封闭能力的综合评价权值大小，建立了一套泥质岩盖层微观封闭能力的综合评价方法，并对琼东南盆地各构造单元梅山组泥岩盖层微观封闭能力进行综合评价。结果表明，梅山组泥质岩盖层在各构造单元均具有  相似文献   

Petrographic and geochemical study of Jurassic dolostones from Lebanon: Evidence for superimposed diagenetic events     

Fadi H. Nader  Rudy Swennen  Rob M. Ellam   《Journal of Geochemical Exploration》2006,89(1-3):288

The Jurassic rock sequence in Lebanon is characterized by pervasive dolomitization (thickness > 1000 m). Two distinct dolostones are recognized within this rock succession: fine-to-medium crystalline seepage-reflux grey dolostone and coarse-crystalline hydrothermal beige dolostone. In this contribution, field, petrographic, and geochemical investigations on a dolostone ‘tongue’, occurring in Late Jurassic carbonates in central Lebanon, are discussed. The dolostone ‘tongue’ consists predominantly of the beige Late Jurassic hydrothermal dolostones. During and/or after the deposition of the overlying continental sandstones (Early Cretaceous), meteoric water percolated through the sand layers and into the underlying beige dolostones. This resulted first in dolomite intracrystalline dissolution, and then in the precipitation of oxides/hydroxides within the pore space. Finally, the precipitation of ferroan dolomite cement — from reduced fluids during a new stage of burial — took place. This study attempts to explain how superimposed diagenetic events result in a single pervasive dolostone body.  相似文献   

封闭系统中的白云石化作用及其石油地质学和矿床学意义——以四川盆地东北部三叠系飞仙关组碳酸盐岩为例   总被引：9，自引：0，他引：9  

黄思静　QING HaiRuo胡作维  邹明亮冯文立王春梅  郜晓勇王庆东 《岩石学报》2007,23(11):2955-2962

作为优质储层的四川盆地东北部三叠系飞仙关组的结晶白云岩是通过埋藏成岩过程的封闭条件下的白云石化作用形成的.岩石所具有的高孔隙度与封闭体系中的白云石化反应:2CaCO3 Mg2 =CaMg(CO3)2 Ca2 有关.埋藏成岩体系中的高锶流体是该封闭条件下白云石化作用的产物,深埋藏条件下的热化学硫酸盐还原作用是锶进一步富集的原因,因而三叠系的大型和超大型天青石矿床的成因与这些因素有关.结晶白云岩极低的锰含量、与同期海水类似的δ13C值表明白云石化流体具有强烈的海源色彩,同时也说明白云石化过程没有与大气水交换;相对较低的δ18O值表明白云石化发生在较晚的埋藏成岩阶段.大多数已有的白云石化机制都是基于近地表成岩条件建立的,系统具有良好的开放性,但开放体系中的白云石化(或白云石沉淀)作用对油气储集空间和与成岩过程元素迁移有关的沉积层控矿床的形成没有多少实际意义.在四川盆地东北部三叠系飞仙关组地层中,作为非储层的微晶或泥晶白云岩以及原始结构保存的粒屑白云岩的白云石化作用主要是在有大气水介入的开放体系中发生的.  相似文献   

Dissolution Kinetics of Dolomite in Water at Elevated Temperatures   总被引：1，自引：0，他引：1  

Ronghua Zhang  Shumin Hu  Xuetong Zhang  Wenbin Yu 《Aquatic Geochemistry》2007,13(4):309-338

Kinetic experiments of dolomite dissolution in water over a temperature range from 25 to 250°C were performed using a flow through packed bed reactor. Authors chose three different size fractions of dolomite samples: 18–35 mesh, 35–60 mesh, and 60–80 mesh. The dissolution rates of the three particle size samples of dolomite were measured. The dissolution rate values are changed with the variation of grain size of the sample. For the sample through 20–40 mesh, both the release rate of Ca and the release rate of Mg increase with increasing temperature until 200°C, then decrease with continued increasing temperature. Its maximum dissolution rate occurs at 200°C. The maximum dissolution rates for the sample through 40–60 mesh and 60–80 mesh happen at 100°C. Experimental results indicate that the dissolution of dolomite is incongruent in most cases. Dissolution of fresh dolomite was non-stoichiometric, the Ca/Mg ratio released to solution was greater than in the bulk solid, and the ratio increases with rising temperatures from 25 to 250°C. Observations on dolomite dissolution in water are presented as three parallel reactions, and each reaction occurs in consecutive steps as where the second part is a slow reaction, and also the reaction could occur as follows: The following rate equation was used to describe dolomite dissolution kinetics where refers to one of each reaction among the above reactions; k _ij is the rate constant for ith species in the jth reaction, a _i stands for activity of ith aqueous species, n is the stoichimetric coefficience of ith species in the jth reaction, and define . The experiments prove that dissolved Ca is a strong inhibitor for dolomite dissolution (release of Ca) in most cases. Dissolved Mg was found to be an inhibitor for dolomite dissolution at low temperatures. But dissolution rates of dolomite increase with increasing the concentration of dissolved Mg in the temperature range of 200–250°C for 20–40 mesh sample, and in the temperature range of 100–250°C for 40–80 mesh sample, whereas the Mg²⁺ ion adsorption on dolomite surface becomes progressively the step controlling reaction. The following rate equation is suitable to dolomite dissolutions at high temperatures from 200 to 250°C.where refers to dissolution rate (release of Ca), and are molar concentrations of dissolved Ca and Mg, k _ad stands for adsorption reaction rate constant, K _Mg refers to adsorption equilibrium constant. At 200°C for 40–60 mesh sample, the release rate of Ca can be described as:  相似文献   

Why does emissions trading under the EU Emissions Trading System (ETS) not affect firms’ competitiveness? Empirical findings from the literature     

Eugénie Joltreau 《Climate Policy》2019,19(4):453-471

Environmental policies may have important consequences for firms’ competitiveness or profitability. For the European Union Emissions Trading System (EU ETS) the empirical literature documents that significant emissions reductions have resulted from it. Surprisingly, however, the literature shows that there have been hardly any concurrent negative effects on firms’ competitiveness during the first two phases of the scheme (2005–2012). We show that the main explanations for the absence of negative impacts on competitiveness are a large over-allocation of emissions allowances leading to a price drop and the ability of firms to pass costs onto consumers in some sectors. Cost pass-through combined with free allocation, in turn, partly generated windfall profits. In addition, the relatively low importance of energy costs indicated by their average share in the budgets of most manufacturing industries may have limited the impact of the EU ETS. Finally, small but significant stimulating effects on innovation have been found so far. Several factors suggest that over-allocation is likely to remain substantial in the upcoming periods of the scheme. Therefore, we expect to see no negative competitiveness effects from the EU ETS in Phases III and IV (2013–2030).

Key policy insights

• Empirical literature on the EU ETS shows that there have been hardly any effects on firms’ competitiveness or profitability.

• One main explanation is a large over-allocation of emissions allowances leading to a price drop. This reduced incentives for innovation.

• Moreover, firms were able to pass costs on to consumers in some sectors which partly generated windfall profits.

• Innovation effects have so far been small but positive.

• We expect to see no negative competitiveness effects on regulated firms in the near future suggesting that no further reliefs for regulated firms are required.

  相似文献   

Recent changes in the feeding of cod (Gadus morhua) off the Flemish Cap, Newfoundland 1989-1993   总被引：1，自引：0，他引：1  

Casas  J. M.; Paz  J. 《ICES Journal of Marine Science》1996,53(5):750-756

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Developing soil indices based on brightness,darkness, and greenness to improve land surface mapping accuracy     

Bingwen Qiu  Ke Zhang  Zhenghong Tang  Chongcheng Chen  Zhuangzhuang Wang 《地理信息系统科学与遥感》2017,54(5):759-777

Soil, as one of the three basic biophysical components, has been understudied using remote sensing techniques compared to vegetation and impervious surface areas (ISA). This study characterized land surfaces based on the brightness–darkness–greenness model. These three dimensions, brightness, darkness, and greenness, were represented by the first Tasseled Cap Transformation (TC1), Normalize Difference Snow Index (NDSI), and Normalized Difference Vegetation Index (NDVI), respectively. The Ratio Index for Bright Soil (RIBS) was developed based on TC1 and NDSI, and the Product Index for Dark Soil (PIDS) was established by TC1 and NDVI. Their applications to the Landsat 8 Operational Land Imager images and 500 m 8-day composite Moderate Resolution Imaging Spectroradiometer (MODIS) in China revealed the efficiency. The two soil indices proficiently highlighted soil covers with consistently the smallest values, due to larger TC1 and smaller NDSI values in bright soil, and smaller NDVI and TC1 values in dark soil. The RIBS is capable of distinguishing bright soil from ISA without masking vegetation and water body. The spectral separability bright soil and ISA were perfect, with a Jeffries–Matusita distance of 1.916. And the PIDS was the only soil index that could discriminate dark soil from other land covers including ISA. The soil areas in China were classified using a simple threshold method based on MODIS images. An overall accuracy of 94.00% was obtained, with the kappa index of 0.8789. This study provided valuable insights into developing indices for characterizing land surfaces from different perspectives.  相似文献   

内蒙古白云鄂博REE-Nb-Fe矿床成因问题研究     

任伊苏  杨晓勇 《地质论评》2016,62(S1):401-402

白云鄂博REE-Nb-Fe矿床是世界上已知的最大的稀土矿床,稀土储量48 Mt（6wt% RE2O3）,该矿床的成因和成矿年龄至今存在较大争议。本文观察白云鄂博矿床岩相学、矿物学特征,通过激光拉曼等技术鉴定重要的稀土矿物,电子探针测出白云鄂博矿床单矿物化学成分,结合前人同位素年代学数据,进一步探讨白云鄂博矿床的成因机制。  相似文献   

Effectiveness of various dispersed alkaline substrates for the pre-treatment of ferriferous acid mine drainage     

《Applied Geochemistry》2016

Dispersed alkaline substrates (DAS) have been successfully used in passive treatment of highly contaminated acid mine drainage (AMD) to limit coating and clogging issues. However, further optimization of DAS systems is still needed, especially for their long-term efficiency during the treatment of ferriferous AMD. In the present study, three types of DAS comprised of natural alkaline materials (wood ash, calcite, dolomite), in different proportions (20%v/v, 50%v/v, 80%v/v), and a substrate with high surface area (wood chips) were tested in 9 batch reactors. The testing was carried out, in duplicate, for a period of 91 days, to evaluate the comparative performance of the mixtures for iron pre-treatment in ferriferous AMD (2500 mg/L Fe, at pH 4). Results showed increasing of pH (between 4.15 and 7.12), regardless of the proportion of alkaline materials in the DAS mixtures. Among the tested mixtures, wood ash type DAS were more effective for Fe removal (99.9%) than calcite or dolomite type DAS (up to 66%). All tested DAS had limited efficiency for sulfate removal and an additional treatment unit, such as a sulfate-reducing biochemical reactor, is needed. Moreover, due to the similar performances of the calcite and dolomite DAS, they could be potentially substituted and rather be used in a polishing treatment unit. Based on these findings, the most promising mixture was the 50% wood ash type DAS (WA50-DAS).  相似文献   

Mineralogy and trace-element geochemistry of the high-grade iron ores of the Águas Claras Mine and comparison with the Capão Xavier and Tamanduá iron ore deposits, Quadrilátero Ferrífero, Brazil     

Carlos Alberto Spier  Sonia Maria Barros de Oliveira  Carlos Alberto Rosière  José Domingos Ardisson 《Mineralium Deposita》2008,43(2):229-254

Several major iron deposits occur in the Quadrilátero Ferrífero (QF), southeastern region of Brazil, where metamorphosed and heterogeneously deformed banded iron formation (BIF) of the Cauê Formation, regionally called itabirite, was transformed into high- (Fe >64%) and low-grade (30%?2O₃, with a higher amount of detrimental impurities, especially MnO, in the soft ore. Both hard and soft ores are depleted in trace elements. The high-grade ores at the Águas Claras Mine have at least a dual origin, involving hypogene and supergene processes. The occurrence of the hard, massive high-grade ore within “fresh” dolomitic itabirite is evidence of its hypogene origin. Despite the contention about the origin of the dolomitic itabirite (if this rock is a carbonate-rich facies of the Cauê Formation or a hematite–carbonate precursor of the soft high-grade ore), mineralogical and geochemical features of the soft high-grade ore indicate that it was formed by leaching of dolomite from the dolomitic itabirite by meteoric water. The comparison of the Águas Claras, Capão Xavier and Tamanduá orebodies shows that the original composition of the itabiritic protore plays a major role in the genesis of high- and low-grade soft ores in the QF. Under the same weathering and structural conditions, the dolomitic itabirite is the more favorable to form high-grade deposits than siliceous itabirite. Field relations at the Águas Claras and Capão Xavier deposits suggest that it is not possible to form huge soft high-grade supergene deposits from siliceous itabirite, unless another control, such as impermeable barriers, had played an important role. The occurrence in the Tamanduá Mine of a large, soft, high-grade orebody formed from siliceous itabirite and closely associated with hypogene hard ore suggests that large, soft, high-grade orebodies of the Quadrilátero Ferrífero, which occur within siliceous itabirite, have a hypogene contribution in their formation.  相似文献