草酸的稳定性及CO_2包裹体压力计实验研究     

田锋  郑海飞  孙樯 《岩石学报》2015,31(11):3477-3483

应用金刚石压腔(diamond-anvil cell)实验技术,对草酸的稳定性进行了研究。草酸在高压低温条件下可以稳定存在,而在低压高温条件下将分解为CO2、H2O等气体。当成矿流体遇到破裂带或裂隙而发生减压沸腾时,可以使成矿流体中的有机络合物迅速发生分解产生大量CO2,从而造成金属元素在有利的空间沉淀、富集成矿。同时,实验研究了高温高压条件下CO2的物理化学性质,得到了CO2包裹体压力计的测定方程:P(MPa)=271.517·(Δν1381.93-0.010987·ΔT)+0.1,式中Δν1381.93(cm-1)为待测包裹体中CO2的拉曼位移相对于常温常压下CO2的拉曼位移1381.93cm-1之差,ΔT(℃)为待测包裹体的温度与常温(23℃)之差,P(MPa)为待测包裹体的内压。由上式计算拉曼位移ν的标准偏差为±0.2cm-1,压力P的误差为±54MPa。该压力标定方程适用于在高压下温度范围为23℃≤T≤390℃的压力标定。  相似文献   

Mangrove development and its response to environmental change in Yingluo Bay (SW China) during the last 150 years: Stable carbon isotopes and mangrove pollen     

《Organic Geochemistry》2015

Located at the interface of terrestrial and marine ecosystems, mangroves are particularly sensitive to environmental change. They provide a sedimentary sink for organic carbon, whereby cores can provide detailed records of mangrove species. We aimed to trace the history of mangrove development over the past 150 years in Yingluo Bay, SW China. Sedimentation rates (avg. 0.32 and 0.37 cm/year) were calculated on the basis of ln(²¹⁰Pb_ex) vs. mass depth, and offset the rate of relative sea level rise (0.22–0.24 cm/year), leading to a seaward expansion of new mangrove habitats. Chemical tracers (δ¹³C_org and C:N) and an isotope mixing model were utilized to trace the contribution of mangrove-derived organic matter (MOM). Changes in the relative abundance of pollen from mangrove plants was used to compensate for diagenetic alteration of the stable isotope values and potential overlaps in isotope values for different sources of organic matter. The result of Pearson correlation analysis showed that the MOM was moderately positive correlated with total mangrove pollen, indicating that stable carbon isotopes and mangrove pollen provide similar information for tracing mangrove ecosystems. Based on results from this study, compositional changes in mangrove communities could be divided into two main stages: a degradation period (1870–1930 AD) and a flourishing period (1930–2011 AD), corresponding to colder temperature and warmer temperature, respectively. Owing to the location being far away from any industrial area and human activity, temperature may be a key factor for mangrove development.  相似文献   

Tradeoffs in carbon commodification: A political ecology of common property forest governance     

《Geoforum》2015

Carbon markets have gained traction worldwide as an ostensibly win–win solution to climate change, providing low-cost emission reductions in the Global North and sustainable development in the Global South. However, sustainable development and livelihood co-benefits have largely failed to materialize in a range of carbon offset projects, particularly those in forest communities. While some scholars explain this failure as an outcome of fundamental tradeoffs between market efficiency and sustainable development, others argue that institutions of common property land tenure can resolve tradeoffs and generate important co-benefits for local communities. Using a political ecology approach, integrating insights of Karl Polanyi and Noel Castree on the commodification of nature and evidence from a carbon forestry project in Chiapas, Mexico, this article grapples with the ways in which carbon market requirements shape forest governance within common property tenure arrangements. I argue that the centralization of forest governance and decision making into the hands of project implementers and brokers, the necessity for legible land rights and boundaries, and the technical requirements for measurement, calculation, and monitoring of carbon have reshaped forest governance in ways that have undermined the social and ecological benefits often associated with common property management schemes. This research therefore demonstrates that so-called tradeoffs between market efficiency and equitable sustainable development goals may not be inherent to carbon forestry and calls into question the reliance on disembedding market mechanisms for climate change mitigation in forest ecosystems. As such, this work has important implications for REDD+.  相似文献   

Hirnantian (Late Ordovician) δ13C HICE excursion in a North Gondwanan (NE Spain) periglacial setting and its relationship to glacioeustatic fluctuations     

《Chemie der Erde / Geochemistry》2015,75(3):335-343

In the Iberian Chains of northeastern Spain, the Hirnantian Orea Shale comprises three erosive glaciogenic unconformities punctuating two transgressive glaciomarine sequences. These sequences represent ice retreat episodes of grounded ice on a North Gondwanan region of 50–60°S of estimated palaeolatitude. In contrast, the same formation recorded in the Hesperian Chains repeated episodes of extensional tectonic activity: diamictites were associated with slope-related debris flows and slumps commonly interrupted by truncating discontinuities.An analysis of δ¹³C_org in the Orea Shale has revealed that the lower Orea sequence displays isotopically light baseline values (∼ −27‰) punctuated by minor (2–3‰) shifts. In distal parts, the upper sequence is characterised by a rapid rise in δ¹³C_org values, which mark a positive excursion, in the range of 2.5‰ to 7‰ over 40 cm of thickness. The stratigraphic gap involved in the intra-Orea erosive unconformity appears to be greater both in proximal exposures and slope-related (Hesperian) areas, where the chemostratigraphic shift was not recorded. Upsection in the three studied sections, the δ¹³C values display upsection a sharp return to baseline values of −26‰ to −28‰.The Hirnantian strata of the Iberian and Hesperian Chains have recorded three major correlatable events: (i) a the karstic surface that caps upper Katian limestones and reflects the maximum glacial extension; (ii) a single δ¹³C_org positive peak of ∼6‰ that is recognisable in distal ramp settings, marking the beginning of the second ice retreat episode and probably representing the late Hirnantian HICE shift; and (iii) the erosive unconformity marked by the progradation of the Los Puertos shoreline complexes.  相似文献   

稻田土壤碳循环关键微生物过程的计量学调控机制探讨   总被引：3，自引：0，他引：3  

Wu Jinshui  Ge Tida  Zhu Zhenke 《地球科学进展》2015,30(9):1006-1017

稻田生态系统碳循环是我国陆地生态系统碳循环的重要组成部分,微生物驱动的稻田土壤碳循环(输入、分配、稳定等过程)的生物地球化学过程是土壤碳循环过程研究的核心。目前,对稻田土壤碳循环过程及其机制的认识缺乏基于生态化学计量学层面的研究。因此,系统解析耦合化学—生物—环境要素的稻田土壤碳循环的关键过程是深入研究当前面临的诸多土壤生物化学问题(如土壤碳循环与土壤肥力、温室气体减排等)的科学瓶颈。在综合分析计量学的基本内涵与土壤计量学发展需求的基础上,论述了稻田土壤有明显区别于其他土壤类型的土壤发生学和生物化学特点,重点评述了稻田土壤碳循环的3个主要过程的研究进展,包括:1稻田土壤新鲜有机质转化、矿化的关键微生物过程计量;2典型水稻土CH4产生的关键微生物过程计量;3典型水稻土微生物CO2光合同化功能的计量。在此基础上,探讨了土壤生物化学过程统计学和数学模型在土壤计量学研究中的应用,并提出了稻田土壤碳循环关键微生物过程的计量学特征研究的发展趋势和科学问题展望。期望能够通过这些探讨对推动我国该研究领域的基础理论建设和新技术发展有所贡献。  相似文献   

Marine Carbon Sequestration: Current Situation,Problems and Future     

Wang Jianghai  Sun Xianxian  Xu Xiaoming  Wu Choufei  Peng Juan  Yuan Jianping 《地球科学进展》2015,30(1):17-25

Abuse of fossil energy resources results in the excessive discharge of greenhouse gases, especially CO₂, enhancing the trend of global climate warming. Carbon sequestration is an important method to lower the increasing rate of CO₂ concentration in the atmosphere. Marine carbon sequestration is a novel idea for reducing CO₂ emission, and its reservoir mainly includes seawater and submarine sediment, which not only possess a great potential capacity of carbon sequestration, but also have high safety in relation to continental reservoirs. In this paper, we expounded the technique principle and mechanisms of marine carbon sequestration, potential capacity and time duration of marine carbon sequestration, main factors influencing marine carbon sequestration, CO₂ injection technique, impacts on marine biota from over emission of CO₂ and technique monitoring the leakage of CO₂. Finally, a prospect of marine carbon sequestration was proposed, and its hot topics were accordingly pointed out.  相似文献   

土壤样品中碳的测定     

张哲  李育霖 《化工矿产地质》2015,(2):119-122

红外碳硫分析仪测定碳含量,直接固体进样,经过高温燃烧,红外检测,直接得到碳含量。通过非水滴定法、红外碳硫分析仪两种方法比较,得出红外碳硫分析仪测定方法应用广泛,还能同时测定两种元素,高低含量碳都可以测定。方法简便快速、测定结果准确、灵敏度高。  相似文献   

塔里木北缘震旦纪—寒武纪转折期碳同位素漂移事件及成因机制     

樊奇  樊太亮  李清平  张岩  谷雨  商雅欣 《地学前缘》2021,28(5):436-447

震旦纪—寒武纪转折期是地球演化的关键节点,这一时期的碳-氧同位素记录在塔里木保留完整却关注较少。选取苏盖特布拉克露头震旦系与寒武系交界地层实测采样,并开展了古生物、镜下鉴定、碳同位素漂移事件的综合分析,探讨了N1(BACE)、P1(ZHUCE)等碳同位素漂移事件的成因机制。样品的δ¹³C_carb和δ¹⁸O_carb相关系数(R²=0.05)、δ¹⁸O_carb和Mn/Sr相关系数(R²=0.09)及岩石学特征表明,后期成岩改造并未导致碳-氧同位素的显著分馏,原始碳同位素特征得以基本保留。由下至上,在该剖面识别出P-1事件(δ¹³C_carb峰值1.9‰2.4‰)、N1事件(-6.8‰-10.3‰)、P1事件(1.4‰4.1‰)、N2a-c事件(-0.4‰-2.8‰)、P2a-c事件(0.2‰0.6‰)和N3事件(-3.4‰)。综合碳同位素演化特征与古生物、年代学数据,确认了玉尔吐斯组底部硅质页岩与奇格布拉克组顶部藻云岩的分界面为塔里木震旦系与寒武系的分界线,并实现了该露头与老林、肖滩、三峡、西伯利亚、阿曼和摩洛哥剖面的地层对比。分析认为,塔里木北缘震旦纪—寒武纪转折期的碳漂移事件,更多受控于古海洋氧气含量变化引起的固碳率f_org的波动。玉尔吐斯组早期海侵背景下的大规模缺氧事件导致的初级生产力和固碳率降低,是N1负漂移事件(BACE)的主因;随后海退中氧气含量的增加引起生产力重建和固碳率增加,形成了P1正漂移事件(ZHUCE)。这一成果性认识有助于塔里木盆地寒武纪古环境研究与深层超深层油气远景资源评价。  相似文献   

胶-辽-吉造山带辽河群石墨矿碳同位素特征及成因分析     

朱建江  刘福来  刘福兴  石闯  王舫  徐文涛 《岩石学报》2021,37(2):599-618

作为华北克拉通周缘三条石墨成矿带之一的东部带,胶-辽-吉古元古代石墨成矿带是研究早前寒武纪石墨成矿机制及地球早期气候特征的天然实验室。本文对胶-辽-吉造山带辽河群石墨矿(甜水乡马沟石墨矿)进行了详细的岩相学、地球化学、拉曼光谱学以及碳同位素等方面的研究。研究结果表明辽河群含石墨矿岩石主要为含石墨变质杂砂岩、含石墨黑云母长英质片麻岩和含石墨透闪大理岩,在log(Fe₂O₃/K₂O)-log(SiO₂/Al₂O₃)判别图解中,这些含石墨岩石位于砂岩和页岩区域内,它们具有和太古宙后澳大利亚平均页岩(PAAS)相似的稀土元素特征;地球化学特征表明它们具有低的成熟度,未经历长途搬运,是快速堆积的产物,主要沉积于活动大陆边缘弧后盆地环境。碳同位素研究表明辽河群石墨矿碳同位素值具有很宽的变化范围(δ¹³C_PDB=-16.49‰~-25.93‰),是有机物在变质过程中脱CH_4造成的。结合拉曼光谱学特征,我们认为辽河群石墨矿是由有机物经过变质作用形成的,其变质程度可以达到高角闪岩相(551~627℃)。综合分析前人年代学数据,我们认为辽河群石墨矿的沉积时代为2.13~2.17Ga,在后期的弧-陆碰撞造山以及后碰撞作用过程中(2000~1895Ma;1875~1850Ma),有机物逐渐发生变质形成石墨并聚集形成石墨矿床。华北克拉通周缘大量石墨矿的沉积时代(2.3~2.05Ga)和大氧化事件发生的时间一致,可能是地球早期大氧化事件的沉积响应。  相似文献   

Carbon peak and carbon neutrality in China: Goals,implementation path and prospects     

《China Geology》2021,4(4):720-746

Climate change is a common problem in human society. The Chinese government promises to peak carbon dioxide emissions by 2030 and strives to achieve carbon neutralization by 2060. The proposal of the goal of carbon peak and carbon neutralization has led China into the era of climate economy and set off a green change with both opportunities and challenges. On the basis of expounding the objectives and specific connotation of China’s carbon peak and carbon neutralization, this paper systematically discusses the main implementation path and the prospect of China’s carbon peak and carbon neutralization. China’s path to realizing carbon neutralization includes four directions: (1) in terms of carbon dioxide emission control: energy transformation path, energy conservation, and emission reduction path; (2) for increasing carbon sink: carbon capture, utilization, and storage path, ecological governance, and land greening path; (3) in key technology development: zero-carbon utilization, coal new energy coupling, carbon capture utilization and storage (CCUS), energy storage technology and other key technology paths required to achieve carbon peak and carbon neutralization; (4) from the angle of policy development: Formulate legal guarantees for the government to promote the carbon trading market; Formulate carbon emission standards for enterprises and increase publicity and education for individuals and society. Based on practicing the goal and path of carbon peak and carbon neutralization, China will vigorously develop low carbon and circular economy and promote green and high-quality economic development; speed up to enter the era of fossil resources and promoting energy transformation; accelerate the integrated innovation of green and low-carbon technologies and promote carbon neutrality.©2021 China Geology Editorial Office.  相似文献