夏季北半球500 hPa位势高度场持续性异常的地理分布及区域特征   总被引：10，自引：3，他引：10  

李金龙  纪立人 《大气科学》1994,18(2):163-172

本文利用２３年夏季3个月的５００ hPa位势高度场，对２０°Ｎ以北的热带以外地区的位势高度异常进行了分析，着重研究了持续时间超过天气尺度扰动时间（大约1周）的持续异常。结果表明:５００ hPa高度场上持续异常的产生?具有很大的地理依赖性，在以下几个地区最容易产生持续异常:（１）北太平洋中东部到阿拉斯加南部（ＮＥＰ）。（２）北大西洋东部到欧洲大陆西海?岸（ＥＡＴ）。（３）前苏联西北部的新地岛附近（ＷＮＳU）。（４）加拿大北部的哈得逊湾附近（ＮＣＡ）。（５）白令海峡以北的北冰洋地区（ＡＲＣ）。进一步对异常关键区统计分析得到:异常多发区特征显著地不同于异常少发区，正异常与负异常也有所差别。  相似文献   

Aqueous geochemistry of rare-earth elements in karst lakes, southwestern China     

Zhongliang WANG Congqiang LIU Zhaozhou ZHU 《中国地球化学学报》2006,25(B08):171-171

Due to the unique chemical properties that are similar but still progressively change, the rare earth elements （REEs） are useful tracers of various geochemical processes in the lithosphere and hydrosphere. However, despite many studies of REE geochemistry in the ocean, the aqueous geochemistry of REEs in lake waters has been poorly documented. In the present study, two special karst lakes are chosen as case studies to investigate the distributions of dissolved REEs in lake water. Although the two lakes, Hongfeng and Aha, are both alkaline and have high pH from 7.9 to 8.7 and high carbonate concentrations, the Aha Lake has been more severely affected by acidic mining drainage with high Fe, Mn and SO42 concentrations. In the present study, the concentrations of dissolved rare-earth elements in lake waters were determined by inductively coupled plasma mass spectrometry. The result shows that the concentrations of dissolved REEs in the studied alkaline karst lakes, as compared to the concentrations of REEs in seawater, are much lower than the other investigated terrestrial surface waters in previous studies. The key factor controlling dissolved REE distributions is pH value which is negatively correlated with REE concentrations. Due to high concentration of carbonate ion and alkaline character of water chemistry, the shale （PAAS） normalized patterns of dissolved REEs show marked HREE enrichment in all water samples. This is primarily the result of the preferential formation of stronger carbonate complexes with the HREEs. In alkaline or intermediate waters, REE-carbonate complexes are the dominant and typical species, which account for about more than 90% of the total dissolved REEs.  相似文献   

贵州瓮安磷矿陡山沱组地层元素地球化学特征   总被引：2，自引：0，他引：2  

吴凯  马东升  潘家永  聂文明  周健  夏菲  刘莉 《华东地质学院学报》2006,29(2):108-114

瓮安陡山沱组上磷矿层含有大量早期多细胞动物化石(瓮安生物群),而陡山沱组下磷矿层未发现该生物群,说明上下两个磷矿层体现了不同的沉积环境。上磷矿层的氧化还原敏感元素Mo,U,V含量较下磷矿层要低很多。底部白云岩层、下磷矿层和中部白云岩层,无Ce异常,而上磷矿层和灯影组白云岩层Ce为负异常。这些表明,瓮安陡山沱组地层形成的海水沉积环境由下部的缺氧环境向上部的氧化环境转变。  相似文献   

Characteristics of rare earth elements of lacustrine exhalative rock in the Xiagou Formation of Lower Cretaceous in Qingxi sag, Jiuxi basin   总被引：1，自引：0，他引：1  

Wen Huaguo  Zheng Rongcai  Geng Wei  Fan Mingtao  Wang Manfu 《Frontiers of Earth Science》2007,1(3):333-340

The exhalative rock occurring in the Xiagou Formation of Lower Cretaceous in Qingxi sag, Jiuxi basin is a sort of a rare lacustrine white smoke type, rich in ferrodolomites and albites. This paper introduces the geological background, mineral association, and lithology of the exhalative rock, and discusses its REE geochemical characteristics and connection with hydrothermal environment. It is shown that the exhalative rock has basal characteristics of hydrothermal depositional formation of LREE>HREE, with positive δCe and negative δEu, which is different from the characteristics of marine exhalative rock. Since the REE pattern and exceptional distribution of δEu and δCe are highly similar to the characteristics of alkalescent tholeiitic basalt in the same layer, the exhalative rock of Xiagou Formation is considered to be closely related to the origin of basalt in the same horizon. The fact that the amount of REE of exhalative rock decreases outwards indicates that exhalative rock in the Xiagou Formation may be connected with lacustrine hydrothermal convection circulation. Translated from Journal of Mineral and Petrology, 2006, 26(4): 41–47 [译自: 矿物岩石]  相似文献   

Cerium and Ytrium in apatite as records of magmatic processes: Insight into fractional crystallization,magma mingling and fluid saturation     

Arkadiusz Przybyło  Anna Pietranik  Grzegorz Zieliński 《Chemie der Erde / Geochemistry》2022,82(2):125864

Apatite is a versatile mineral crystallizing at different stages of silicic magma evolution. Its composition may record that of magma, but could also be affected by interaction with fluids. The focus of this study is the well-recognized magma mingling process that was previously detected using plagioclase composition and in this study complementary record is sought in apatite. The apatite was analysed in two dioritic enclaves (primitive and hybrid) and host quartz monzonite, which is an igneous rock emplaced at ca. 340 Ma in mylonitized Góry Sowie gneisses (NE Bohemian Massif). The apatite was analysed in-situ by microprobe that allowed for chemical characterization of different apatite populations in quartz monzonite and analyses of thin acicular apatite in the enclaves. Apatite population in the quartz monzonite was chemically distinct from that in both enclave types and characterized by higher Y and lower Ce contents, such values are usually typical for peraluminous magmas. As such, the apatite transfer from felsic to mafic magma should be well recorded in apatite composition, which was not the case. Monzonite apatite composition was not commonly observed in the hybrid enclave despite massive plagioclase transfer and only rare resorbed cores with low Ce and Y contents were present. However, such low Ce and Y cores crystalized at the latest stage of apatite crystallization in the quartz monzonite, whereas the plagioclase transfer was an early episode. Therefore, we conclude that apatite transfer was limited during mingling and the apatite composition in the quartz monzonite is best explained by an early Cl-Ce-rich fluid removal and then fractional crystallization, while apatite in the primitive enclave is affected only by fractional crystallization. Altogether, Ce and Y composition of apatite is a valuable tool to record diverse magmatic processes such as fluid removal and precipitation from fluid in addition to fractionation of different REE phases and should be further explored.  相似文献   

鲜水河断裂带富硼地热水中稀土元素分布特征及其对硼来源的指示意义          下载免费PDF全文

袁建飞  邓国仕  刘慧中 《沉积与特提斯地质》2023,43(2):428-441

高温地热系统地热水中普遍富含高浓度的硼,其来源的研究一直是地热地质学者关注的热点问题。尽管众多的学者对地热水中硼形成机理开展了广泛的研究,但富硼地热水中稀土元素的分布特征及其迁移规律能否指示热水中硼的来源尚不清楚。本研究以鲜水河断裂带富硼地热水为研究对象,通过野外调查取样、室内测试分析、水文地球化学模拟和综合研究等技术手段和方法,探究断裂带地热水中硼和稀土元素的分布特征和迁移规律。研究结果显示：鲜水河断裂带地热水中硼含量90%超过我国饮用水标准规定值0.5 mg/L(地热水中硼含量最大值为10.50 mg/L);地热水中稀土元素含量为0.08～3.49μg/L,且主要以LnCO₃⁺和Ln(CO₃)₂^-的络合物形态存在。地热水稀土元素PAAS归一化模式表现为重稀土元素相对于轻稀土元素富集((Nd/Yb)SN均值为0.41),且具有较显著的Eu(均值为0.34)和Ce(均值为0.07)正异常特征。地热水中硼和稀土元素的迁移均受到赋热含水层长英质和碳酸盐岩类矿物溶解过程的影响,且地热...  相似文献   

汶川8.0级地震前上报的宏观异常现象及分析     

程万正  吴小平  官致君  朱航  路茜 《四川地震》2010,(1)

清理了汶川8.0级地震前四川省地震局收到的每周、月度各单位或个人上报的各类异常资料.这些宏观异常现象主要包括居民生活用井水质变化、泉水变化,气象、动、植物异常现象等.2002～2003年宏观异常现象集中分布在凉山州,多数沿安宁河-则木河构造带以及川滇交界西侧分布;2004～2008年5月宏观异常现象散布在龙门山、龙泉山、鲜水河-安宁河-则木河构造带以及川滇交界地区.四川地区宏观异常项数在2002年4～6月,2003年6～8月间为最为集中出现的两个时段,之后零星出现.对震前龙门山构造带附近出现的宏观现象进行分析后,我们看不出与地震间的必然联系,难以作为预测未来大地震的依据.  相似文献   

新矿物丁道衡矿的晶体结构   总被引：3，自引：1，他引：2  

李国武  杨光明  马喆生  施倪承  熊明  沈敢富  范海福 《矿物学报》2005,25(4):313-320

对产于内蒙白云鄂博晶态富Ti和Fe2+的硅钛铈矿族新矿物丁道衡矿Ce4Fe2+(Ti,Fe2+)2Ti2Si4O22进行了晶体结构的精测,求得晶胞参数:a=1.34656(15)nm,b=0.57356(6)nm,c=1.10977(12)nm,β=100.636(2)°,晶胞体积V=0.84239(16)nm3。单位晶胞中的分子数Z=2。晶体结构测定中分别用P21/a和C2/m空间群来进行晶体结构解析,解析表明,两种结构模型最终得到的R因子分别为0.026和0.021。两种结构精修后的原子坐标、键长键角都完全合理。根据结构分析及衍射数据消光规律统计认为,丁道衡矿的空间群应该为P21/a,而C2/m为赝对称空间群,结构属于具有C2/m赝对称的P21/a超结构,是一种超结构的新类型。  相似文献   

Electronic and optical properties of pure and Ce³⁺-doped CaS single crystals: a first-principles prediction     

陈中钧  田东斌 《海洋学报(英文版)》2010,29(11)

This paper investigates the electronic and optical properties for pure and Ce³⁺-doped CaS crystals by using the first-principles total energy calculations. The results show that CaS:Ce has a direct band gap of 2.16 eV, and the top of the valence band is determined by S 3p states and the bottom of the conduction band is determined by Ce 4f states, respectively. Our results validate that the yellow emission from CaS:Ce is produced by doped cerium and the green emission quenches at 12.5% cerium concentration. The Ce-S bond shows more covalent character than the Ca-S bond.  相似文献   

The geochemical characteristics of aqueous rare-earth elements in shallow karst groundwater in Guiyang City,China     

Shouyang He  Lijun Zhu  Ruidong Yang  Zheng Shen  Xiaohong Yu 《中国地球化学学报》2011,30(1):114-124

Fifty-seven shallow groundwater samples were collected from Guiyang karst basin, China, to analyze the aqueous rare-earth elements in low-water seasons and it is shown that the total amount of rare-earth elements (ΣREE) in karst groundwater is exceedingly low compared with that in carbonate rocks or weathering crusts of carbonate rocks, and ranges from 0.01 to 0.43, from 0.03 to 0.27, from 0.03 to 0.19 and from 0.05 to 1.38 μg·L-1 for dolomite, dolomitic & limestone, limestone and clastic rock aquifer, respectively. Both distributions and contents of rare-earth elements (REE) in karst groundwater reflect the lithology of host rocks or weathering crusts of carbonate rocks through which groundwater flows. The chondrite-normalized patterns show a non-flat profile with higher enrichment of slightly light rare-earth elements (LREE) than heavy rare-earth elements (HREE), prominent fractionation between LREE and HREE, negative Ce anomalies and negative or positive Eu anomalies. There is more obvious fractionation between LREE and HREE in groundwater than that in carbonate rocks and their weathering crusts due to high contents of HCO3? and PH in groundwater. In shallow karst groundwater, REE(CO3)n2n-3 (n=1 and 2) is the main inorganic species of REE. But for a clastic rock aquifer, both REESO4+ and REECO3+ are the main inorganic species of REE. Species of REE in groundwater is closely associated with the hydrochemical type of groundwater which is predominated by the lithology of host rocks, groundwater-rock interaction and weathering-pedogenesis of carbonate rocks.  相似文献