Porosity preservation due to grain coating illite/smectite: Evidence from Buchan Formation (Upper Devonian) of the Ardmore Field,UK North Sea     

Longxun Tang  Jon Gluyas  Stuart Jones 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):202-214

The Buchan Formation sandstone reservoirs from the Ardmore Field in the UK Central North Sea are fluvial-aeolian deposits and provide examples of porosity preservation in deeply-buried reservoirs (2.7–3.2?km) caused by grain-coating illite/smectite (I/S). Here, high reservoir quality commonly correlates with the occurrence of grain-coating I/S and consequent inhibition of quartz cementation in the aeolian dune and interdune sandstones. Porosity is lower in fluvial sandstones lacking grain coating I/S but with intense quartz overgrowths. We propose that the presence of I/S reflects concentration of the smectitic-rich clay bearing water which would have been the deposits of the interdune and/or distal sector of fluvial distributary system, and were introduced into aeolian deposits by mechanical infiltration. Petrographic relationships indicate that these coatings grew mainly before the mechanical compaction as the clays occur at grain contacts. The use of empirical model suggested that about 6–7% porosity have been preserved. The burial-thermal history of the Ardmore area contributed to the high quality reservoir because throughout much of the time since deposition, the Devonian sandstones have been little buried. Only from the Palaeogene the reservoir temperatures exceeded about 70?°C and rapidly buried to today’s maximum depth, which have minimized the negative effect generally ascribed to smectitic clays on reservoir quality. The circumstances of porosity preservation shown in this study may be unusual, but nonetheless have profound consequences for exploration. It is possible to identify new Buchan Formation prospects in areas hitherto dismissed because they were generally assumed to be poor reservoir.  相似文献   

Petrogenesis of carbonatitic lamproitic dykes from Sidhi gneissic complex,Central India     

M.Satyanarayanan  D.V.Subba Rao  M.L.Renjith  S.P.Singh  E.V.S.S.K.Babu  M.M.Korakoppa 《地学前缘(英文版)》2018,9(2):531-547

Petrographic, mineral chemical and whole-rock geochemical characteristics of two newly discovered lamproitic dykes(Dyke 1 and Dyke 2) from the Sidhi Gneissic Complex(SGC), Central India are presented here. Both these dykes have almost similar sequence of mineral-textural patterns indicative of:(1) an early cumulate forming event in a deeper magma chamber where megacrystic/large size phenocrysts of phlogopites have crystallized along with subordinate amount of olivine and clinopyroxene;(2) crystallization at shallow crustal levels promoted fine-grained phlogopite, K-feldspar, calcite and Fe-Ti oxides in the groundmass;(3) dyke emplacement related quench texture(plumose K-feldspar, acicular phlogopites) and finally(4) post emplacement autometasomatism by hydrothermal fluids which percolated as micro-veins and altered the mafic phases. Phlogopite phenocrysts often display resorption textures together with growth zoning indicating that during their crystallization equilibrium at the crystal-melt interface fluctuated multiple times probably due to incremental addition or chaotic dynamic self mixing of the lamproitic magma. Carbonate aggregates as late stage melt segregation are common in both these dykes, however their micro-xenolithic forms suggest that assimilation with a plutonic carbonatite body also played a key role in enhancing the carbonatitic nature of these dykes. Geochemically both dykes are ultrapotassic(K_2 O/Na_2 O: 3.0-9.4) with low CaO, Al_2 O_3 and Na_2 O content and high SiO_2(53.3-55.6 wt.%)and K_2 O/Al_2 O_3 ratio(0.51-0.89) characterizing them as high-silica lamproites. Inspite of these similarities, many other features indicate that both these dykes have evolved independently from two distinct magmas. In dyke 1, phlogopite composition has evolved towards the minette trend(Al-enrichment) from a differentiated parental magma having low MgO, Ni and Cr content; whereas in dyke 2, phlogopite composition shows an evolutionary affinity towards the lamproite trend(Al-depletion) and crystallized from a more primitive magma having high MgO, Ni and Cr content. Whole-rock trace-elements signatures like enriched LREE, LILE, negative Nb-Ta and positive Pb anomalies; high Rb/Sr, Th/La, Ba/Nb, and low Ba/Rb, Sm/La, Nb/U ratios in both dykes indicate that their pareintal magmas were sourced from a subduction modified garnet facies mantle containing phlogopite. From various evidences it is proposed that the petrogenesis of studied lamproitic dykes stand out to be an example for the lamproite magma which attained a carbonatitic character and undergone diverse chemical evolution in response to parental melt composition, storage at deep crustal level and autometasomatism.  相似文献   

Permo-Triassic high-pressure metamorphism in the central western Korean Peninsula,and its link to Paleo-Tethyan Ocean closure: Key issues revisited     

Hyeong Soo Kim  Sanghoon Kwon  Sung Won Kim  M.Santosh 《地学前缘(英文版)》2018,9(5):1325-1335

Permo-Triassic high-pressure(HP) mafic granulites, together with the Bibong retrogressed eclogite,preserved along the central western Korean Peninsula provide important insights into the Late Permian to Triassic collisional orogeny in northeast Asia. The metamorphic pressureetemperatureetime(P-T-t)paths of these rocks, however, remain poorly constrained and even overestimated, owing to outdated geothermobarometers and inaccurate isopleth techniques. Here we evaluate the metamorphic Pe T conditions of Triassic HP mafic granulites including those in Baekdong, Sinri and Daepan and the Bibong Triassic retrogressed eclogite in the Hongseong area, and the Permo-Triassic Samgot mafic granulite in the Imjingang Belt of the central western Korean Peninsula through the application of modern phase equilibria techniques. The Baekdong and Samgot mafic granulites and the Bibong retrogressed eclogite yield a range of 12.0 -16.0 kbar and 800 -900℃, representing HP granulite facies conditions. The Sinri and Daepan granulites from the Hongseong area show relatively lower grade metamorphic conditions between HP granulite and normal granulite facies, and are characterized by sub-isothermal decompression during exhumation. The similarities in the metamorphic ages and the post-collisional igneous activity from the central western Korean Peninsula indicate that the Triassic ages represent the retrograde stage of the metamorphic Pe T paths. In contrast, the Late Permian metamorphic ages, which are older than protolith ages of the post-collisional igneous rocks, correspond to the possible prograde stage of metamorphism. The P-T-t paths presented in this paper, together with the metamorphic ages and post-orogenic igneous events reported from these areas suggest trace of the subduction, accretion and exhumation history, and indicate a tectonic linkage among the northeast Asian continents during the Paleo-Tethyan Ocean closure.  相似文献   

The role of mechanical stratigraphy in the lateral variations of thrust development along the central Alberta Foothills,Canada     

Hyunjung Lee  Yirang Jang  Sanghoon Kwon  Myong-Ho Park  Gautam Mitra 《地学前缘(英文版)》2018,9(5):1451-1464

Fold-thrust belts generally exhibit significant variations in structural styles such as differences in thrust geometries and frequencies in imbrication. A natural laboratory of this pattern is preserved in the central Alberta Foothills of the Canadian Rockies, where differences in thrust geometries are represented by the existence vs. non-existence of triangle zones. To seek the factors that make this difference in these regions in terms of structural geometry, stratigraphic thickness variations and mechanical stratigraphy of the sedimentary layers, structural interpretation is conducted based on admissible cross-sections and well log interpretations. In northern region, a backthrust is detached from an incompetent layer(viz.Nomad Unit of the Wapiabi Formation), which gets thinner from the Foothills to the Plains, indicating that it is developed where the shale layers are pinched out where triangle zone is developed. Backthrust is also developed in the southern region, where mechanical strengths of strata(viz. Bearpaw Formation)increase toward the foreland. In the central region, however, only forethrusts are developed along the weak continuous decollement layers(viz. Turner Valley and Brazeau formations), forming an imbricate fan without development of the triangle zone. Incompetent layers such as the top Wapiabi(Nomad),Brazeau(Bearpaw), Coalspur and Paskapoo formations are also pinched out laterally, forming fault glide horizons in different stratigraphic levels in each region. These results indicate that, along the transport direction, triangle zone is developed in relation to the stratigraphic pinch out of the Nomad Unit in the northern region, and is formed associated with the variations in strengths of the layers constituting the Bearpaw Formation in the southern region. It is notable that all the glide horizons are developed along incompetent layers. However, triangle zones are not developed in the areas of continuous stratigraphy of the Nomad Unit, which does not serve as a glide horizon in the central region. This suggests that factors such as stratigraphic thickness changes of incompetent layers and mechanical stratigraphy of the sedimentary layers play an important role in the development of lateral variations in thrust system evolution in terms of triangle zone vs. imbricate fan in the central Alberta Foothills.  相似文献   

Comparisons among the Oortsog,Dulaan, and Nomgon mafic-ultramafic intrusions in central Mongolia and Ni-Cu deposits in NW China: implications for economic Ni-Cu-PGE ore exploration in central Mongolia     

Y.-J. Mao  B. Dash  K.-Z. Qin  B. Bujinlkham  D.-M. Tang 《Russian Geology and Geophysics》2018,59(1):1-18

Although there are many mafic-ultramafic intrusions in the western and central regions of Mongolia, Central Asian Orogenic Belt (CAOB), no economic-grade Ni-Cu deposits have yet been discovered. To understand the economic Ni-Cu deposit potential of the intrusions in central Mongolia, the parental magma affinity and sulfide saturation of the Oortsog, Dulaan, and Nomgon Ni-Cu mineralized mafic-ultramafic intrusions are studied. These three intrusions are predominantly gabbroic in composition, while the Oortsog and Dulaan intrusions also contain small proportions of peridotites. The parental magmas of the Oortsog and Dulaan intrusions are tholeiitic, as indicated by their Cr-spinel and clinopyroxene compositions, whereas the parental magma of the Nomgon intrusions is likely calc-alkaline. The compositions of Cr-spinel and clinopyroxene, combined with the presence of significant Nb-Ta depletions, indicate that these rocks were most likely derived from modified mantle sources. Both the Oortsog and Nomgon intrusions form two clusters in terms of their olivine composition, suggesting that multiple magma surges were involved during their emplacement. The relatively low Fo values and Ni contents in olivine from the three intrusions compared to those from Ni-Cu deposits in NW China, as well as those in the Voisey’s Bay deposit in Canada, indicate that the three intrusions were crystallized from relatively evolved magmas. The Cu/Zr ratios of rocks of the Oortsog, Dulaan, and Nomgon intrusions are higher than 1, suggesting that these rocks contain cumulus sulfide. This, coupled with the presence of rounded sulfide inclusions in olivine of the Oortsog and Dulaan intrusions, suggests that sulfide saturation occurred before or during olivine crystallization. The distribution patterns of platinum group elements (PGEs) of the Dulaan and Oortsog intrusions record slight Rh, Pt, and Pd (PPGE) enrichment relative to Os, Ir, and Rh (IPGE). Furthermore, the Ni/Cu ratios of sulfide-bearing rocks from the Oortsog intrusion vary from 1.8 to 3.8, which are consistent with those of the Ni-Cu sulfide deposits in NW China. In contrast, the Ni/Cu ratios of sulfide-bearing rocks from the Nomgon intrusion are extremely low (0.03 to 0.07). This, together with the significant enrichment in PPGE relative to IPGE, suggests that these sulfides of the Nomgon intrusion were segregated from a magma that was extremely enriched in Cu and PPGE but depleted in Ni and IPGE. The characteristics of the chalcophile elements in these intrusions are attributed to the fact that the derivation of the Nomgon magma was significantly different from that of the Dulaan and Oortsog parental magmas. Overall, although the parental magmas of the intrusions in central Mongolia are more evolved than those in NW China, they are comparable in terms of the sizes of their intrusions, constituent minerals, and mineral chemistry. These similarities suggest that the intrusions in central Mongolia have economic Ni-Cu sulfide potential. Furthermore, intrusions similar to the Nomgon intrusion may feature PGE mineralization potential.  相似文献   

Hydrochemical characteristics and geochemistry evolution of groundwater in the plain area of the Lake Baiyangdian watershed,North China Plain   总被引：1，自引：0，他引：1       下载免费PDF全文

ZHANG Yu-qin  WANG Guang-wei  WANG Shi-qin  YUAN Rui-qiang  TANG Chang-yuan  SONG Xian-fang 《地下水科学与工程》2018,6(3):220-233

Water cycle and water quality in the Lake Baiyangdian watershed of the North China Plain have undergone great changes due to over-pumping of groundwater and wastewater discharge.In this paper,hydrogeochemical data was collected to analyze the hydrochemical characteristics and geochemistry evolution of groundwater.The study area was divided into two typical parts.One was in the upstream plain area,where over-pumping had resulted in significant decline of groundwater level;the other one was located in the downstream area near the Fu River and Lake Baiyangdian(Lake BYD region).In addition to the natural weathering of minerals,excessive fertilizer was also a main factor of higher ion concentration in groundwater.According to studies,due to good permeability,these regions were easy to be polluted even with deep groundwater depth.However,upstream shallow groundwater and surface water,including lake water,domestic along with industrial wastewater were all sources of present shallow groundwater in the Lake BYD region.Results indicated that anthropogenic activities rather than minerals much matter to the groundwater in these regions.Particularly,wastewater largely decided the groundwater quality,which suggested that the management and restoration of surface water quality was crucial to groundwater protection.  相似文献   

Mapping abandoned agricultural land in Kyzyl-Orda,Kazakhstan using satellite remote sensing     

《Applied geography (Sevenoaks, England)》2015

In many regions worldwide, cropland abandonment is growing, which has strong and known environmental and socio-economic consequences. Yet, spatially explicit information on the spatial pattern of abandonment is sparse, particularly in post-Soviet countries of Central Asia. When thriving reaching for key Millennium Development Goals such as food security and poverty reduction, the issue of cropland abandonment is critical and therefore must be monitored and limited, or land use transformed into an alternative one. Central Asia experienced large changes of its agricultural system after the collapse of the Soviet Union in 1991. Land degradation, which started already before independence, and cropland abandonment is growing in extent, but their spatial pattern remains ill-understood. The objective of this study was to map and analyse agricultural land use in the irrigated areas of Kyzyl-Orda, southern Kazakhstan, Central Asia. For mapping land use and identifying abandoned agricultural land, an object-based classification approach was applied. Random forest (RF) and support vector machines (SVM) algorithms permitted classifying Landsat and RapidEye data from 2009 to 2014. Overlaying these maps with information about irrigated land parcels, installed during the Soviet period, allowed indicating abandoned fields. Fusing the results of the two approaches, RF and SVM, resulted in classification accuracies of up to 97%. This was statistically significantly higher than with RF or SVM alone. Through the analysis of the land use trajectories, abandoned agricultural fields and a clear indication of abandoned land were identified on almost 50% of all fields in Kyzyl-Orda with an accuracy of approximately 80%. The outputs of this study may provide valuable information for planners, policy- and decision-makers to support better-informed decision-making like reducing possible environmental impacts of land abandonment, or identifying areas for sustainable intensification or re-cultivation.  相似文献   

能源地缘政治视角下中国与中亚—俄罗斯国际能源合作模式   总被引：6，自引：1，他引：5  

杨宇  刘毅  金凤君 《地理研究》2015,34(2):213-224

中亚与俄罗斯油气资源丰富,是中国未来开展国际油气资源合作,实现油气进口多元化和能源运输安全的重要战略区域。从俄罗斯、美国、中国以及中亚自身的战略需求方面刻画中亚地区大国博弈的能源地缘政治格局及其演变,并对中国与俄罗斯、中亚各国的能源合作特征进行详细分析。研究发现:中国与中亚各国之间的能源合作进展顺利,并呈现出多元化的发展趋势,已从单纯的油气贸易向油气产业的上下游进行拓展,但是中国与俄罗斯的合作因地缘政治战略、价格因素等一波三折,乌克兰危机之后,双方合作出现新的战略机遇。针对在中亚能源合作可能遇到的大国地缘政治博弈、俄罗斯的政策不确定性、中亚各国的局部冲突以及可能存在的资源国有化和来自国际石油公司的剧烈竞争,提出未来中国可以采取贷款换资源合作模式、双向合作模式与中亚国家石油公司联合经营模式、探索上海合作组织框架内的油气资源供求一体化模式以及油气经贸一体化合作模式,以尽可能地降低能源合作风险。  相似文献   

Total concentration,speciation and mobility of potentially toxic elements in soils around a mining area in central Iran     

《Chemie der Erde / Geochemistry》2015,75(3):323-334

The current study was designed to investigate the extent and severity of contamination as well as the fractionation of potentially toxic elements (As, Cd, Cr, Cu, Pb, Zn, Ni) in minesoils and agricultural soils around a Pb–Zn mine in central Iran. For this purpose, 20 agricultural soils and eight minesoils were geochemically characterized. Results showed that minesoils contained elevated concentrations of As (12.9–254 mg kg⁻¹), Cd (1.2–55.1 mg kg⁻¹), Pb (137–6239 mg kg⁻¹) and Zn (516–48,889 mg kg⁻¹). The agricultural soils were also polluted by As (5.5–57.1 mg kg⁻¹), Cd (0.2–8.5 mg kg⁻¹), Pb (22–3451 mg kg⁻¹) and Zn (94–9907 mg kg⁻¹). The highest recorded concentrations for these elements were in soils influenced directly by tailing ponds. Chromium, Cu and Ni content in agricultural soils (with average value of 74.1, 34.6 and 50.7 mg kg⁻¹, respectively) were slightly higher than the minesoils (with average value of 54.5, 33.1 and 43.4 mg kg⁻¹, respectively). Sequential extraction data indicated that there were some differences between the speciation of PTEs in soil samples. In the agricultural soils, Zn and Cd were mainly associated with carbonate bound fraction, As and Pb with reducible fraction, Cu with oxidisable fraction and Cr and Ni with residual phase. With respect to mobility factor values, Zn and Cd in the agricultural soils have been found to be the most mobile while As mobility is negligible. Also, the mobility factor of As, Cd and Pb in agricultural soils adjoining tailing ponds was high. In minesoil sample Cd was most abundant in the carbonate form, whereas other studied elements were mainly present in the reducible and residual fractions; therefore, despite the high total concentrations of As, Pb and Zn in the minesoils, the environmental risk of these elements was low. Based on the obtained data, a portion of Cu, Cr and Ni input was from agricultural activities.  相似文献   

Middle Jurassic continental to marine transition in an extensional tectonics context: the Genna Selole Fm depositional system in the Tacchi area (central Sardinia,Italy)     

Luca Giacomo Costamagna 《Geological Journal》2016,51(5):722-736

In Eastern Sardinia during the early Middle Jurassic, Alpine Tethys opening triggered the rise of a temporary tectonic high. The high collapsed rapidly, was fragmented into separate blocks, and subsequently covered by continental, transitional, and finally shallow marine deposits forming a narrow depositional system comprising the Genna Selole Fm. Present‐day exposures in the southern part of the palaeo‐high allow the sedimentological evolution of the transgressive cover sequence to be ascertained. Initial terrestrial deposits comprise alluvial fan deposits located at the mouths of palaeovalleys. These pass into braid‐deltas and in the coastal areas located between adjacent valleys mouths, palustrine and coastal plain tidally‐influenced environments developed. These environments interfingered laterally and passed seaward into a transitional, siliciclastic to carbonate tidal environment. With the collapse of the tectonic high, the continental to transitional environments were transgressed with deposition of marine carbonates. A comparison with similar coeval deposits of the W‐Mediterranean domain has been undertaken. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献