Mg-Cr~(2+)橄揽石、辉石和尖晶石的晶胞参数测定及Cr~(2+)在各晶体结构中的占位     

李建平  HughSt．C．O’Neill 《矿物学报》1995,(4)

本文用Mg－Cr2+做榄石、辉石、尖晶石的粉晶X射线衍射数据，采取“整体图谱最小二乘Rietveld”方法计算了上述矿物的晶胞参数和摩尔体积，并对Cr2+在各晶体结构中的占位情况进行了研究。结果显示，各矿物的晶胞参数随含Cr2+量的增大而增大。据Vegard定律，推算出各端元组分铬橄榄石（Cr2SiO1）、铬辉石（Cr2SiO2O6）及立方铬尖晶石（Cr3O4）的摩尔体积分别为47．7，68．0，44．9cm3。精化结构参数指示，在橄榄石中，Cr2+随机分配在两个八面体（M1，M2）位置；在辉石中，Cr2+优先选择八面体M2位置；在尖晶石中，Cr2+占置四面体位置。这种晶体内离子分配可从离子半径差别或晶体场稳定能大小得到解释。  相似文献   

尖晶石族矿物的热辐射性质研究   总被引：8，自引：1，他引：8  

姜泽春  陈大梅 《矿物学报》1993,13(4):382-390

本文主要研究晶石族矿物在５０－６５０℃，２－４０μｍ波长范围内的红外光谱发射率和总发射率。文中共研究了三十余种尖晶石族矿物的发射率。测试结果表明，尖晶石族矿物的发射率的大小受其成分、晶体结构、温度和波长的制约。过渡族中的着色离子将大大增加矿物在红外短波段的发射率。  相似文献   

新发现的沂蒙矿类质同象系列矿物──K(Ti_5Fe_3Cr_2Mg_2)_(12)O_(19)及Ba(Ti_5Fe_4Mg_2Cr)_(12)O_(19)     

陆琦  周湖云 《矿物学报》1994,(3)

在山东蒙阴金伯利岩中，首次发现了沂蒙矿类质同象系列新的富Ti矿物（变）种。理想的晶体化学式可表达为：K（Ti5Fe3Cr2Mg2）12O19（简称K－Ti沂蒙矿）（Ba，K）（Ti5Fe4Mg2Cr）12O19（简称Ba－Ti沂蒙矿）从而与原来确定的沂蒙矿K（Cr5Ti3Fe2Mg2）12O19和钡钛铁铝矿（Ba，K）（Cr4Fe4Ti3Mg）12O19一起构成了金伯利岩中AM12O19磁铁铅矿型矿物的K-Cr、Ba－Cr、K-Ti、Ba-Ti四种端元类型的复杂类质同象系列。新发现的两个矿物（变）种均产出于具叶片状尖晶石出溶体的镁钛铁矿中。根据结构已知的沂蒙矿中原子的占位和配位多面体情况，分析了K－Ti，Ba－Ti沂蒙矿中各原子的占位和配位多面体，认为新发现的两个（变）种在成分上与沂蒙矿和钡钛铁铬矿有明显的区别。根据镁钛铁矿、尖晶石、沂蒙矿新（变）种、钙钛矿之间的相互关系，探讨了它们的形成环境，从而为这类矿物的地幔成因提供了直接证据。  相似文献   

尖晶石中的Si含量及其存在形式     

李建平  Hugh. St.C. O''Neill 《岩石矿物学杂志》1995,14(3):230-235

自然岩石及简单和复杂体系中实验合成或经重新平衡的尖晶石化学成分显示，在中－低压条件下，与橄榄石共存的尖晶石可含一定量的Ｓｉ，其含量随温度和压力的升高而增大。用最小二乘法对简单体系中 实验数据的热力学模拟发现，Ｓｉ在铬尖晶石中以硅酸盐尖晶石（Ｍｇ２ＳｉＯ４）形式存在，Ｍｇ２ＳｉＯ４组份在铬尖晶石中的活度ａＳＤＭＧ２ＳｉＯ４＝（ＮＳＰＭＧ／２）２＊（ＮＳＰＳｉ）２（ＮＳＰＳｉ代表以４个氧为基础的单位尖  相似文献   

Experimental calibration of sapphirine–spinel Fe–Mg exchange thermometer: Implication for constraints on P–T condition of Howard Hills, Napier Complex, East Antarctica     

Kei Sato  Tomoharu Miyamoto  Toshisuke Kawasaki 《Gondwana Research》2006,9(4):398-408

The Fe²⁺–Mg distribution coefficients between sapphirine and spinel:were experimentally determined at pressures of 9–13 kbar and temperatures of 950–1150 °C using a natural ultrahigh-temperature (UHT) granulite with paragenesis of these minerals from the Napier Complex in East Antarctica [X_Mg = Mg / (Fe + Mg); X_Fe = Fe / (Fe + Mg)]. A new sapphirine–spinel geothermometer has been obtained as:

We applied the exchange thermometer to UHT or high-grade metamorphic rocks that were reported from various complexes in the world. If the K_D values of 2.63–4.34 obtained from low-Cr mineral pairs such as X_Cr^Spr < 0.016 and X_Cr^Spl < 0.047 were substituted into the equation, their temperature conditions would be estimated as 806–1050 °C at 11 kbar. The X_Cr means Cr / (Al + Cr(+ Fe³⁺)). These temperatures are reasonable retrograde or near peak metamorphic condition.  相似文献   

伊通新生代玄武岩中辉石岩捕虏体的尖晶石成分分带     

贾大成  裴尧  杜有实  M.J.van Bergen  H.van Roermund 《吉林大学学报(地球科学版)》2007,37(3):417-422

伊通新生代玄武岩中存在3种不同成因的捕虏体,其中上地幔岩浆分异结晶形成的辉石岩捕虏体中尖晶石具有独特的成分分带。电子探针分析显示在尖晶石矿物的边缘富Al,而贫Mg、Fe和Cr,矿物中心富Mg、Fe和Cr,而贫Al,从中心向两侧基本对称。从尖晶石成分分带的元素分布特征判断,其形成不是固溶体相平衡过程中的离子扩散,而可能是化学平衡过程中结晶矿物与熔浆之间化学成分平衡的结果,属于化学平衡导致的成分分带。从尖晶石矿物中心到边缘的温度变化不能反映矿物形成后所经历的温度变化状况,与尖晶石共生矿物的二辉石地质温度计所能代表的地质意义是矿物中心的温度(~1 006℃),反映矿物开始结晶时的温度状态。  相似文献   

Empirical geothermometers and geothermobarometers for spinel peridotite phase assemblages     

《International Geology Review》2012,54(15):1940-1974

Experimental synthesis of spinel peridotite phase assemblages for a range of compositions that mimic natural samples is used to derive a set of empirical geothermometers and geothermobarometers represented by multiple linear regression best-fit surfaces that link the variables of temperature, pressure, and composition. The calibrated geothermometers use reactions that govern the solubility of Al and Cr in both pyroxenes and the Mg–Fe exchange between silicates and spinel. Geothermobarometers map the Mg–Fe exchange between coexisting olivine and clinopyroxene and pyroxenes and Ca–Mg exchange between coexisting pyroxenes. Application of the geothermometers and geothermobarometers to suites of naturally occurring samples indicates that while reactions governing the Cr and Al solubility and solvus of orthopyroxene give useful estimates of ‘original’ mantle temperatures and pressures, respectively, comparable reactions for clinopyroxene yield estimates that are variably dependent on the transport phase of the sample suites. Temperature and pressure estimates from reactions governing Mg and Fe exchange between silicates and spinel and coexisting silicates are all sensitive to the later transport stage of the samples.  相似文献   

Implication of corona formation in a metatroctolite to the granulite facies overprint of HP–UHP rocks in the Moldanubian Zone (Bohemian Massif)          下载免费PDF全文

S. W. Faryad  V. Kachlík  J. Sláma  G. Hoinkes 《Journal of Metamorphic Geology》2015,33(3):295-310

Corona and inclusion textures of a metatroctolite at the contact between felsic granulite and migmatites of the Gföhl Unit from the Moldanubian Zone provide evidence of the magmatic and metamorphic evolution of the rocks. Numerous diopside inclusions (1–10 μm, maximum 20 μm in size) in plagioclase of anorthite composition represent primary magmatic textures. Triple junctions between the plagioclase grains in the matrix are occupied by amphibole, probably pseudomorphs after clinopyroxene. The coronae consist of a core of orthopyroxene, with two or three zones (layers); the innermost is characterized by calcic amphibole with minor spinel and relicts of clinopyroxene, the next zone consists of symplectite of amphibole with spinel, sapphirine and accessory corundum, and the outermost is formed by garnet and amphibole with relicts of spinel. The orthopyroxene forms a monomineralic aggregate that may contain a cluster of serpentine in the core, suggesting its formation after olivine. Based on mineral textures and thermobarometric calculations, the troctolite crystallized in the middle to lower crust and the coronae were formed during three different metamorphic stages. The first stage relates to a subsolidus reaction between olivine and anorthite to form orthopyroxene. The second stage involving amphibole formation suggests the presence of a fluid that resulted in the replacement of igneous orthopyroxene and governed the reaction orthopyroxene + anorthite = amphibole + spinel. The last stage of corona formation with amphibole + spinel + sapphirine indicates granulite facies conditions. Garnet enclosing spinel, and its occurrence along the rim of the coronae in contact with anorthite, suggests that its formation occurred either during cooling or both cooling and compression but still at granulite facies conditions. The zircon U–Pb data indicate Variscan ages for both the troctolite crystallization (c. 360 Ma) and corona formation during granulite facies metamorphism (c. 340 Ma) in the Gföhl Unit. The intrusion of troctolite and other Variscan mafic and ultramafic rocks is interpreted as a potential heat source for amphibolite–granulite facies metamorphism that led to partial re‐equilibration of earlier high‐ to ultrahigh‐P metamorphic rocks in the Moldanubian Zone. These petrological and geochronological data constrain the formation of HP–UHP rocks and arc‐related plutonic complex to westward subduction of the Moldanubian plate during the Variscan orogeny. After exhumation to lower and/or middle crust, the HP–UHP rocks underwent heating due to intrusion of mafic and ultramafic magma that was generated by slab breakoff and mantle upwelling.  相似文献   

西南天山东德沟镁铁-超镁铁岩中尖晶石的矿物学特征及其地质意义   总被引：4，自引：0，他引：4  

孔凡梅  李旭平  李守军  吴苏 《岩石矿物学杂志》2011,30(5):951-960

中国西南天山东德沟镁铁-超镁铁岩出露于天山伊犁-中天山板块和塔里木板块之间的碰撞造山带中,岩石类型主要为(方辉)橄榄岩,且普遍经历了含水流体(熔体)的渗透交代作用,含有形态和成分变化复杂的尖晶石,表现为从红褐色到黄褐色、再到深绿色和浅绿色,尖晶石的Cr2O3和FeO的含量依次降低,Al2O3和MgO的含量逐渐增高。研究认为红褐色和黄褐色的铬尖晶是原生矿物,而绿色的镁铝尖晶石为次生矿物。原生铬尖晶石的Cr#为0.41~0.87,Mg#为0.21~0.61,且成分变化大,显示其可能具多期熔融的复杂成因;次生绿色的尖晶石形态不一、成分相对有较大变化,表明其至少形成于两个期次的变质作用或流体交代过程。原生铬尖晶石具有SSZ环境橄榄岩的特征,指示其寄主岩石可能是俯冲上板片地幔楔岛弧环境的橄榄岩残片。  相似文献   

察尔汗地区130ka B.P.以来湖相沉积物颜色记录的气候变化探讨          下载免费PDF全文

陈宗颜  陈克龙  罗正霞 《盐湖研究》2011,19(4):1-7,14

通过柴达木盆地察尔汗地区湖相沉积物的L*、a*和b*值与有关地球化学指标的相关关系分析,对湖相沉积物颜色指标在古气候研究中的意义进行了探讨,并据此分析了130 ka B.P.以来该区的古气候演变过程。结果表明,L*值与沉积物碳酸盐含量正相关,L*值高时,气候冷干,碳酸盐含量较高;反之,气温上升,湿度增加。b*值和a*值与沉积物中Fe、Mg含量相关,高a*值反映气温较高,b*值可用于反映湖水深度变化和有效湿度的变化,b*值高,湖水浅,氧化作用增强。察尔汗地区色度曲线反映的气候变化特征与其他的气候指标曲线相吻合。  相似文献