Preservation of coal-waste geochemical markers in vegetation and soil on self-heating coal-waste dumps in Silesia,Poland     

《Chemie der Erde / Geochemistry》2016,76(2):211-226

Occurrence and distributions of geochemical markers on vegetation and in soils covering two self-heating coal waste dumps were investigated with gas chromatography-mass spectrometry (GC–MS) and compared with those of bitumen expelled on the coal waste dump surface. Presence of biomarkers, alkyl aromatic hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), and such polar compounds as phenols indicate that components of self-heating coal wastes indeed migrate to soils and plants surface and their characteristic fingerprints can be applied in passive monitoring to investigate migration of contaminants from self-heating coal wastes. Moreover, results allow to discriminate between the Upper- and Lower Silesian coal basins, notwithstanding value shifts caused by heating. Mechanisms enabling the migration of geochemical compounds into soils include mixing with weathered coal-waste material, transport in gases emitted due to self-heating and, indirectly, by deposition of biomass containing geochemical substances. Transport in gases involves mostly lighter compounds such as phenols, methylnaphthalenes, methylbiphenyls, etc. Distributions and values of geochemical ratios are related to differences in their boiling temperatures in the case of lighter compounds but preserve geochemical features in the case of heavier compounds such as pentacyclic trierpanes.  相似文献   

Petrogenesis and geodynamic evolution of the Kajan Neogene subvolcanic rocks,Nain, Central Iran     

《Chemie der Erde / Geochemistry》2016,76(4):567-578

Kajan subvolcanic rocks in the Urumieh–Dokhtar magmatic arc (UDMA), Central Iran, form a Late Miocene-Pliocene shallow-level intrusion. These subvolcanics correspond to a variety of intermediate and felsic rocks, comprising quartz diorite, quartz monzodiorite, tonalite and granite. These lithologies are medium-K calc-alkaline, with SiO₂ (wt.%) varying from 52% (wt.%) to 75 (wt.%). The major element chemical data also show that MgO, CaO, TiO₂, P₂O₅, MnO, Al₂O₃ and Fe₂O₃ define linear trends with negative slopes against SiO₂, whilst Na₂O and K₂O are positively correlated with silica. Contents of incompatible trace elements (e.g. Ba, Rb, Nb, La and Zr) become higher with increasing SiO₂, whereas Sr shows an opposite behaviour. Chondrite-normalized multi-element patterns show enrichment in LILE relative to HFSE and troughs in Nb, P and Ti. These observations are typical of subduction related magmas that formed in an active continental margin. The Kajan rocks show a strong affinity with calc-alkaline arc magmas, confirmed by REE fractionation (La_N/Yb_N = 4.5–6.4) with moderate HREE fractionation (Sm_N/Yb_N = 1.08–1.57). The negative Eu anomaly (Eu/Eu* <1), the low to moderate Sr content (< 400 ppm) and the Dy/Yb values reflect plagioclase and hornblende (+- clinopyroxene) fractionation from a calc-alkaline melt Whole–rock Sr and Nd isotope analyses show that the ⁸⁷Sr/⁸⁶Sr initial ratios vary from 0.704432 to 0.705989, and the ¹⁴³Nd/¹⁴⁴Nd initial ratios go from 0.512722 to 0.512813. All the studied samples have similar Sr-Nd isotopes, indicating an origin from a similar source, with granite samples that has more radiogenic Sr and low radiogenic Nd isotopes, suggesting a minor interaction with upper crust during magma ascent. The Kajan subvolcanic rocks plot within the depleted mantle quadrant of the conventional Sr-Nd isotope diagram, a compositional region corresponding to mantle-derived igneous rocks.  相似文献   

以SRTM-DEM为控制的光学卫星遥感立体影像正射纠正   总被引：3，自引：1，他引：2  

张浩  张过  蒋永华  汪韬阳 《测绘学报》2016,45(3):326-331

针对全球测图缺少统一的控制基准的问题,提出了利用SRTM-DEM作为控制基准,对光学卫星遥感影像进行正射纠正的方法。首先,对光学卫星影像构建的立体影像对进行自由网平差并制作DEM;然后,以SRTM-DEM作为控制,将DEM作为单元模型,进行独立模型法DEM区域网平差,获得单元模型的定向参数;最后,改正立体影像的成像几何模型参数,进行正射纠正。选取湖北咸宁和江西某地两个测区的资源三号数据进行试验,试验结果表明,资源三号正视全色影像的平面定向精度由12.93像素提高到6.85像素。  相似文献   

城区地表形变差分TomoSAR监测方法     

王爱春  向茂生  汪丙南 《测绘学报》2016,45(12):1413-1422

压缩感知技术(CS)的差分TomoSAR技术解决了中高分辨率SAR数据在城区出现的叠掩问题,实现了城区地表形变信息的重构,但是该方法仅利用了目标的稀疏特性并没有考虑目标的结构特性,对具有这两种特性的目标进行重构时其性能较差。针对这一问题,本文采用联合Khatri-Rao子空间和块压缩感知(KRS-BCS),提出了一种差分SAR层析成像方法。该方法依据目标的结构特性和重构观测矩阵具有的Khatri-Rao积性质,将稀疏结构目标的差分TomoSAR问题转化为Khatri-Rao子空间下的BCS问题,然后对目标进行块稀疏的l1/l2范数最优化求解,最后通过理论分析和仿真试验对分辨能力和重构估计性能进行了定性和定量评价,仿真结果表明本文所采用的KRS-BCS方法不仅保持了高分辨率的优点,而且有效地降低了虚假目标出现的概率,大幅度提高了散射点准确重构概率,切实可行地解决了CS方法的不足。应用实例研究中,利用34景Envisat卫星ASAR时间序列影像对日本千叶县茂原市城区进行地表形变监测,并以一等水准点和实时测量的GPS站点观测数据作为参考形变结果进行验证,试验结果表明采用KRS-BCS方法反演的结果与参考形变结果保持了良好的一致性且形变速率整体偏差也较小,实现了较高精度的城区地表形变估计。  相似文献   

基于有理多项式模型的GF4卫星区域影像平差处理方法及精度验证     

皮英冬  杨博  李欣 《测绘学报》2016,45(12):1448-1454

分析了我国首颗静止轨道光学遥感卫星高分四号(GF4)特有的区域成像模式的几何特性,基于静止轨道成像基高比较小的几何特性提出一种利用平均高程面的区域网平差方法。该方法针对GF4卫星影像构建了基于有理多项式模型RFM的区域网平差模型,并在无控制条件下,对GF4卫星区域影像进行区域网平差处理,解决了GF4号区域影像由于定轨误差、定姿误差、大气折光以及镜头畸变等因素导致的拼接精度较低的问题。最后,通过两组真实数据试验对本文方法的精度及有效性进行了验证,同时分析了采用不同的误差补偿模型对于平差结果精度的影响。  相似文献   

一种天绘一号卫星影像精确定位方法     

周欣  王海岩  杨国鹏 《测绘科学》2016,41(11):5-9,129

针对如何最大程度地减小天绘一号卫星RPC模型系统误差,真实反映像方坐标与物方坐标关系的问题,该文介绍了天绘一号卫星的基本情况及相应的RPC参数模型,给出了求解RPC参数的基本方法和流程。结合天绘一号卫星采用等效框幅式光束法平差进行无控定位的特点,利用平差后计算得到的加密点坐标,提出了一种基于像点仿射变换的RPC模型区域网平差方法,并进行了RPC参数修正。经天绘一号卫星精度检测实验表明,修正后的RPC参数能有效地弥补系统性误差,具有更高的定位精度。  相似文献   

一种基于灰度块匹配的视野监测算法     

肖恭伟  欧吉坤  曹淑敏  高腾飞 《测绘科学》2016,41(12):43-46

针对视野移动方向的判断问题,该文介绍了运动补偿的常用方法及应用,提出了基于灰度块匹配的视野移动监测算法。通过对比各种算法计算复杂度和计算时间,发现灰度投影算法准确率低、计算量较小;块匹配搜索算法中的穷尽搜索算法准确率高,但是计算量较大。为了发挥以上两者算法的优势,将两者结合形成了灰度块匹配算法,并通过实验证实了灰度块匹配算法在实时监测系统中的可行性。  相似文献   

Multiple statistical approaches for the discrimination of mangrove species of Rhizophoraceae using transformed field and laboratory hyperspectral data   总被引：1，自引：0，他引：1  

Kumar Arun Prasad 《国际地球制图》2016,31(8):891-912

This study aims at discriminating eight mangrove species of Rhizophoraceae family of Indian east coast using field and laboratory spectra in spectral range (350–2500 nm). Parametric and non-parametric statistical analyses were applied on spectral data in four spectral modes: (i) reflectance (ii) continuum removed, (iii) additive inverse and (iv) continuum removed additive inverse. We introduced continuum removal of inverse spectra to utilize the advantage of continuum removal in reflectance region. Non-parametric test gave better separability than parametric test. Principal component analysis and stepwise discriminant analysis were applied for feature reduction and to identify optimal wavelengths for species discrimination. To quantify the separability, Jeffries–Matusita distance measure was derived. Green (550 nm), red edge (680–720 nm) and water absorption region (1470 and 1850 nm) were found to be optimal wavelengths for species discrimination. The continuum removal of additive inverse spectra gave better separability than the continuum removed spectra.  相似文献   

Quantification of LST and CO2 levels using Landsat-8 thermal bands on urban environment     

Venkatesh Reddy Chejarla  Pramod Kumar Maheshuni 《国际地球制图》2016,31(8):913-926

Land surface temperature (LST) is an important aspect in global to regional change studies, for control of climate change and balancing of high temperature. Urbanization is one of the influencing factors increasing land surface and atmospheric temperature, by the emission of greenhouse gases (e.g. CO₂, NO and methane). In the present study, LST was derived from Landsat-8 of multitemporal data sets to analyse the spatial structure of the urban thermal environment in relation to the urban surface characteristics and land use–land cover (LULC). LST is influenced by the greenhouse gases i.e. CO₂ plays an important role in increasing the earth’s surface temperature. In order to provide the evidence of influence of CO₂ on LST, the relationship between LST, air temperature and CO₂ was analysed. Landsat-8 satellite has two thermal bands, 10 and 11. These bands were used to accurately to calculate the temperature over the study area. Results showed that the strength of correlation between ground monitoring data and satellite data was high. Based on correlation values of each month April (R² = 0.994), May (R² = 0.297) and June (R² = 0.934), observed results show that band 10 was significantly correlating with air temperature. Relationship between LST and CO₂ levels were obtained from linear regression analysis. band 11 was correlating significantly with CO₂ values in each of the months April (R² = 0.217), May (R² = 0.914) and June, (R² = 0.934), because band 11 is closer to the 15-micron band of CO₂. From the results, it was observed that band 10 can be used for calculating air temperature and band 11 can be used for estimation of greenhouse gases.  相似文献   

Application of Zn isotopes in environmental impact assessment of Zn–Pb metallurgical industries: A mini review     

《Applied Geochemistry》2016

Zn and Pb smelters are the major contributors to Zn and Pb emissions among all anthropogenic sources, thus, it is essential to understand Zn isotopic variations within the context of metallurgical industries, as well as its fractionation in different environments impacted by smelting activities. This mini review outlines the current state of knowledge on Zn isotopic fractionation during the high-temperature roasting process in Zn and Pb refineries; δ⁶⁶Zn values variations in air emissions, slags and effluents from the smelters in comparison to the geogenic Zn isotopic signature of ores formation and weathering. In order to assess the environmental impact of these smelters, the available and measured δ⁶⁶Zn values are compiled for smelter impacted natural water bodies (groundwater, stream and river water), sediments (lake and reservoir) and soils (peat bog soil, inland soil). Finally, the discussion is extended to the fractionation induced during numerous physicochemical reactions and transformations, i.e. adsorption, precipitation as well as both inorganic and organic surface complexation.  相似文献