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91.
Diagenetically altered mudstones compact mechanically and chemically. Consequently, their normal compaction trends depend upon their temperature history as well as on the maximum effective stress they have experienced. A further complication is that mudstones are commonly overpressured where clay diagenesis occurs, preventing direct observation of the hydrostatic normal compaction trend. A popular way to estimate pore pressure in these circumstances is to calculate the sonic normal compaction trend in a well with a known pressure–depth profile by applying Eaton's method in reverse, and then to estimate pore pressure in offset wells using Eaton's method conventionally. We tested this procedure for Cretaceous mudstones at Haltenbanken. The results were inconsistent because the sonic log responds differently to disequilibrium compaction overpressure and unloading overpressure, and their relative contributions vary across the basin. In theory, a two-step method using the density and sonic logs could estimate the contributions to overpressure from disequilibrium compaction and unloading. The normal compaction trend for density should be the normal compaction trend at the maximum effective stress the mudstones have experienced, not at hydrostatic effective stress. We advocate the Budge-Fudge approach as a starting point for pore pressure estimation in diagenetically altered mudstones, a two-step method that requires geological input to help estimate the overpressure contribution from disequilibrium compaction. In principle, the Budge-Fudge approach could be used to estimate the normal compaction trend for mudstones at the maximum effective stress they have experienced, and so form the basis of the full two-step method through the use of offset wells. Our initial efforts to implement the full two-step method in this way at Haltenbanken produced inconsistent results with fluctuations in estimated pore pressure reflecting some of the fluctuations in the density logs. We suspect that variations in the mineralogical composition of the mudstones are responsible.  相似文献   
92.
This study presents results for pyrolysis experiments conducted on immature Type II and IIs source rocks (Kimmeridge Clay, Dorset UK, and Monterey shale, California, USA respectively) to investigate the impact of high water pressure on source rock maturation and petroleum (oil and gas) generation. Using a 25 ml Hastalloy vessel, the source rocks were pyrolysed at low (180 and 245 bar) and high (500, 700 and 900 bar) water pressure hydrous conditions at 350 °C and 380 °C for between 6 and 24 h. For the Kimmeridge Clay (KCF) at 350 °C, Rock Eval HI of the pyrolysed rock residues were 30–44 mg/g higher between 6 h and 12 h at 900 bar than at 180 bar. Also at 350 °C for 24 h the gas, expelled oil, and vitrinite reflectance (VR) were all reduced by 46%, 61%, and 0.25% Ro respectively at 900 bar compared with 180 bar. At 380 °C the retardation effect of pressure on the KCF was less significant for gas generation. However, oil yield and VR were reduced by 47% and 0.3% Ro respectively, and Rock Eval HI was also higher by 28 mg/g at 900 bar compared with 245 bar at 12 h. The huge decrease in gas and oil yields and the VR observed with an increase in water pressure at 350 °C for 24 h and 380 °C for 12 h (maximum oil generation) were also observed for all other times and temperatures investigated for the KCF and the Monterey shale. This shows that high water pressure significantly retards petroleum generation and source rock maturation. The retardation of oil generation and expulsion resulted in significant amounts of bitumen and oil being retained in the rocks pyrolysed at high pressures, suggesting that pressure is a possible mechanism for retaining petroleum (bitumen and oil) in source rocks. This retention of petroleum within the rock provides a mechanism for oil-prone source rocks to become potential shale gas reservoirs. The implications from this study are that in geological basins, pressure, temperature and time will all exert significant control on the extent of petroleum generation and source rock maturation for Type II source rocks, and that the petroleum retained in the rocks at high pressures may explain in part why oil-prone source rocks contain the most prolific shale gas resources.  相似文献   
93.
Results are presented from an organic geochemical investigation of a suite of rock samples taken from the Upper Kimmeridge Clay near Kimmeridge, Dorset. All samples contain immature organic matter of marine origin, although one horizon, the Whitestone Band, contains an additional secondary input of partially biodegraded mature hydrocarbons, due to an oil seepage of unknown origin. With the exception of increased relative abundances of 4-methylsteroidal hydrocarbons in the more organic-rich samples, the immature molecular distributions are very similar, suggesting a consistent source of organic matter. The results are in agreement with the palaeoenvironmental model proposed by Tyson et al. (1979) for the deposition of the Kimmeridge Clay, where the different lithologies are controlled by a fluctuating oxic/anoxic boundary, with only the organic-poor mudstones being deposited in relatively oxygenated waters.  相似文献   
94.
Thermo‐hydro‐mechanical responses around a cylindrical cavity drilled or excavated in a low‐permeability formation are studied when the cavity is subjected to a time‐dependent thermal loading. The cavity is considered backfilled after it is supported by casing or lining. Solutions of temperature, pore water pressure, stress, and displacement responses are analytically formulated based on Biot's consolidation theory with the assumption that the backfilling material, supporting material, and surrounding low‐permeability formation are poroelastic media. The solution is expressed in Laplace space, and numerical inversion techniques are used to find field variables in the real‐time domain. After the solution is verified with the numerical results, it is applied in a large‐scale in situ heating test – PRACLAY heating test – for a predictive reference calculation and an extensive parametric study. Another medium‐scale in situ heating test – ATLAS III heating test – is also analyzed using the solution, which provides reasonable agreement with measurements. The new analytical solution proves to be a convenient tool for a good understanding of the resulting coupled thermo‐hydro‐mechanical behavior and is therefore valuable for the interpretation of measured data in engineering practices and for a rational design of potential radioactive waste repositories. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
95.
As the soil traction of the track system consisting of a track plate and protruded grousers is generally higher than that of a comparable wheel system, underwater tracked vehicles are the favored platforms for heavy-weight remotely operated vehicles (ROVs). When an underwater tracked vehicle moves on the seafloor, the track system laterally transmits an engine torque to the soil-track interface, resulting in slip displacement and an associated soil thrust acting as a traction force. Therefore, to evaluate the mobility of underwater tracked vehicle, it is critical to evaluate the soil thrust of the track system based on the soil-track interaction. Unlike the soil thrust of sandy soils, a reliable soil thrust assessment method accounting for the failure mechanism of clayey soil has yet to be developed in spite of its significance. An experimental study on the mechanism of the soil thrust of clayey soil was thus performed. Model track experiments were conducted on a model track system with clayey soil. Based on the experiment results, the mechanism of the soil thrust of clayey soil was investigated and was compared with the mechanism of soil thrust derived from the previous soil thrust assessment methods using sandy soil. Particular attention was given to the development of a new soil thrust prediction model for the track system on clayey soil using the limit equilibrium analysis technique.  相似文献   
96.
Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process.  相似文献   
97.
加瑞  赵栋 《工程地质学报》2022,30(1):270-280
孔压静力触探试验(CPTU)是目前使用最为广泛的原位测试方法之一,但CPTU不能原位测量土体最基本的指标——密度。密度孔压静力触探试验(DCPTU)是把核子密度仪结合到孔压静力触探系统中,贯入过程中可以同时测量锥尖阻力、侧壁摩阻力、孔隙水压力和密度的一种新型原位测试方法。本文首先介绍了DCPTU的试验装置和密度测试理论;然后通过与室内试验结果对比评价了利用DCPTU测量砂土、黏土、填土地层以及海底淤泥的密度的可靠性,分析了非均质地层中DCPTU测量密度与真实密度的区别、并提出了真实密度剖面的推求方法;然后综述了DCPTU在判别软弱夹层、评价砂土的液化势、检验地基处理效果、检测块状填土中的空隙、调查浮泥层的厚度和密度分布等方面的工程应用;最后展望了DCPTU在工程勘察中的发展趋势和应用前景。  相似文献   
98.
对鄂尔多斯盆地北部铀成矿带产铀层位中侏罗统直罗组砂岩进行系统采样和分析,以探讨砂岩中粘土矿物特征与氧化带成因之间的关系。采用X?射线粉晶衍射、电子探针分析等现代分析手段,测定粘土矿物相对含量、微观形貌特征。结果表明:研究区古层间氧化的演变序列为砂体原始灰色→古氧化作用(红色或黄色)→碳酸盐化(残留了部分红色)→后期还原作用(绿色),对应的岩石蚀变期次为早期氧化酸性蚀变→氧化期后弱碱性蚀变→晚期还原弱碱性蚀变;早期氧化砂岩在还原性气体作用下,Fe3+还原转化为Fe2+,高岭石在有Fe2+存在的条件下会向绿泥石转化,这一反应在碎屑颗粒表面,形成许多极细小的针叶状绿泥石,从而使古层间氧化亚带呈现特征的绿色。  相似文献   
99.
《The Journal of geography》2012,111(3):110-120
Abstract

Teaching methods in the 1880s and 1890s were influenced by the energies and publications of the Herbartians from Illinois State Normal University. Memorization was replaced by inductive questioning, field trips and the use of visual aids. Four men and one woman were followed by Douglas Clay Ridgley who built up the geography major and made tools for the teachers. Name recognition is now weak but much of what they taught is now accepted and practiced.  相似文献   
100.
研究了处理粘土沉积物时不同浓度盐酸和用量对溶出硼量及硼同位素组成的影响。结果表明,粘土沉积物中硼的溶出量随盐酸浓度的增加而增加,当盐酸浓度相同时,溶出的硼量随所加盐酸用量的增加而增加,加热有利于硼的溶出。实验结果还表明,粘土沉积物硼的溶出量对测定的硼同位素组成没有明显的影响。  相似文献   
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