Trace elements in the Goze Delchev coal deposit, Bulgaria     

G.M. Eskenazy  Y.S. Stefanova 《International Journal of Coal Geology》2007,72(3-4):257-267

The geochemistry of trace elements in the underground and open-pit mine of the Goze Delchev subbituminous coal deposit have been studied. The coals in both mines are highly enriched in W, Ge and Be, and at less extent in As, Mn and Y as compared with the world-wide Clarkes for subbituminous coals. Ni and Ti are also enhanced in the underground coals, and Zr, Cr and Mo in the open-pit mine coals.Characteristic for the trace element contents in the deposit is a regular variation with depth. The following patterns were distinguished for profile I: a — the element content decreases from the bottom to the top of the bed paralleling ash distribution (Fe, Co, As, Sb, V, Y, Mo, Cs, REE, Hf, Ta, Th, P and Au); b — Ge and W are enriched in the near-bottom and near-top coals; c — in the middle part of the bed the content of K and Rb is maximal, while that of U is slightly enriched; d — Ba content decreases from the top to the bottom of the bed. In profile II, W and Be contents decrease from the bottom to the top. The near-bottom, and especially the near-roof samples of profile IV are highly enriched in Ge, while for W the highest is the content of the near-bottom sample.Ge, Be, As, Mn, Cl and Br are mainly organically associated. The organic affiliation is still strong for Co, B, Sr, Ba, Sb, U, Th, Mo, La, Ce, Sm, Tb and Yb in the underground coals, and Fe, Co, Na, W, Sr, Y and Ag in the coals from the open-pit mine. K, Rb, Ti, Zr, Hf and Ta are of dominant inorganic affinity. The chalcophile and siderophile elements correlate positively with Fe and each other and may be bound partly with pyrite or other sulphides and iron containing minerals.Compared statistically by the t-criteria, the elements Na, Li, Cu, Zn, Pb, Cr, Ni, Co, Mo, Fe and Be are of higher content in the open-pit mine. Tungsten is the only element of higher concentration in the underground mine. The contents of Ge, As, Sr, V, Mn, Y, Zr and P are not statistically different in both mines.It was supposed that there were multiple sources of the trace elements in the deposit. The source of the highly enriched elements (W, Ge, Be, and As) most probably were the thermal waters in the source area. The contemporary mineral springs are of high content of these elements. Another source were the hosting Mesta volcanic rocks, which are enriched in Sb, Mo, Hf, U, Th, As, Li and Rb. Some of the volcanics were hydrothermally altered and enriched or depleted of many elements. Thus, the hydrothermal solutions were also suppliers of elements for the coals. It is obvious that the contents, distribution and paragenesis, of the trace elements in both Goze Delchev coals reflect the geochemical specialization of the source area, including rocks, paleo- and contemporary thermal waters.  相似文献   

Control and prevention of gas outbursts in coal mines, Riosa–Olloniego coalfield, Spain     

María B. Díaz Aguado  C. Gonzlez Nicieza 《International Journal of Coal Geology》2007,69(4):253-266

Underground coal mines have always had to control the presence of different gases in the mining environment. Among these gases, methane is the most important one, since it is inherent to coal. Despite of the technical developments in recent decades, methane hazards have not yet been fully avoided. This is partly due to the increasing depths of modern mines, where methane emissions are higher, and also to other mining-related circumstances, such as the increase in production rates and its consequences: difficulties in controlling the increasing methane levels, increasing mechanization, the use of explosives and not paying close attention to methane control systems.The main purposes of this paper are to establish site measurements using some critical parameters that are not part of the standard mining-control methods for risk assessment and to analyze the gas behavior of subvertical coal seams in deep mines in order to prevent gas incidents from occurring. The ultimate goal is the improvement in mining conditions and therefore in safety conditions.For this purpose, two different mines were instrumented for mine control and monitoring. Both mines belong to the Riosa–Olloniego coalfield, in the Asturias Central Basin, Spain and the areas instrumented are mined via subhorizontal sublevels at an actual depth of around 1000 m under the overburden of Mount Lusorio.During this research, a property favoring gas outbursts was site measured for the first time in an outburst-prone coal (8th Coalbed), gas pressure and its variations, which contributed to complete the data available from previous characterizations and to set some guidelines for assessing the potential outburst-prone areas. A gas-measurement-tube set has been designed for measuring gas pressure as well as its variation over time as a result of nearby workings and to calculate permeability.The paper establishes the effect of overlapping of works, but it also shows the efficacy of two preventive measures to be applied: high pressure water infusion and the exploitation of a protective coal seam (7th Coalbed), that must be mined preferably two complete sublevels before commencing the advance in the outburst-prone coalbed. Both measures constitute an improvement in the mining sequence and therefore in safety, and should be completed with a systematic measurement to control the risk: gas pressure in the 8th Coalbed in the area of influence of other workings, to establish the most suitable moment to renew the advance. Further researches could focus on ascertaining the permeability, not only in mined areas but also in areas of the mine that are still not affected by mining work and on tuning more finely the ranges of influence of overstress time and overlap distance of the workings of the 7th Coalbed in the 8th Coalbed.  相似文献   

应用遥感图像提取煤层自燃信息时必须考虑的几个影响因素     

万余庆  吴军虎  雷学武 《国土资源遥感》1998,9(1):33-39

煤层自燃是中国北方煤田中普遍存在的灾害现象,它不但烧掉了大量的煤炭资源,而且还污染了环境。实践证明,利用遥感影像判别火区位置、圈定火区范围和对火区进行动态监测,及时为灭火工程提供信息,是一项经济和社会意义很大的工作。由于受多种因素的制约,不同地区、不同波段、不同时相、不同空间分辨率的遥感图像,其影像特征（含与煤层自燃有关的热异常影像特征）都有较大的差异,因而从图像上分析和提取地物的热红外辐射特征时,需要考虑遥感图像类型、成像时间、地形条件、气象条件和岩性特征等因素的影响。本文着重讨论了地表辐射温度与上述各项因素之间的关系。  相似文献   

贵州六盘水地区水城矿区晚二叠世煤的煤质特征及其控制因素   总被引：7，自引：0，他引：7  

曾荣树  庄新国 《岩石学报》1998,14(4):549-558

本文中研究概括了六盘水地区水城矿区晚二叠世煤的煤岩学、煤化学和煤地球化学的研究结果,探讨了煤质的控制因素。研究结果表明水城矿区煤具有适合于炼焦用煤的煤岩煤质特征（中挥发分烟煤和高挥发分烟煤Ａ,适中的显微组分比例,４９．９％～８１．８％镜质组,１１．９％～３１．９％惰性组,０．４％～１６．９％壳质组,中－低的硫含量,０．３４％～１．５％）。水城煤的煤级主要受深成变质作用的影响。水城煤的岩石学特征主要受晚二叠世水城三角洲的控制。将水城矿区煤的微量元素含量与世界平均的微量元素进行比较,水城煤具有Ｓｅ、Ｚｒ、Ｃｒ、Ｃｏ、Ｕ和Ｔｈ稍高富集,Ｃｓ、Ａｓ和Ｂａ低富集的特点。煤中Ｂｒ和Ｃｌ具有亲有机性  相似文献   

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece     

K. Christanis  A. Georgakopoulos  J. L. Fernndez-Turiel  A. Bouzinos 《International Journal of Coal Geology》1998,36(3-4)

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.  相似文献   

平顶山矿区矿井突（涌）水水源判别模式   总被引：18，自引：1，他引：17  

王广才  王秀辉 《煤田地质与勘探》1998,26(3):47-50

对在平顶山矿区所采集的地下水样品进行了多元统计分析,以识别一些来源不清的样品归属,建立该区突（涌）水水源判别模型。选择水中６大离子为变量,对３７个水样进行了Ｑ型聚类分析和阳离子三角形分析;以聚类分析所得的结果为基础,应用判别分析方法建立了该矿区寒武系灰岩水、薄层灰岩水（Ｌ２）和砂岩水３类判别模型,并应用马氏距离作Ｆ检验和归属概率“检验”,结果表明所建立的判别模型是有效的。  相似文献   

Correlation of T-log with E-log in coal-bearing formations     

J. R. Kayal 《Pure and Applied Geophysics》1980,119(2):349-355

The profile of temperature gradient versus depth (T-log) has been found to be very useful for correlation with electrical resistivity log (E-log) in coal-bearing formations. A positive correlation between electrical resistivity and thermal resistivity is observed in coal sections whereas a negative correlation is found in sandstone/shale beds, thus helping in coal prospect evaluation. T logs have been used to correct the location of coal bed which had apparently been misinterpreted by the E-log. Hole to hole correlation of T-log and E-log is found to be excellent and it is observed that thermal resistivity characteristics of given formations remain fairly uniform. A rough estimation of coal grade is possible from the detailed study of the T-logs. Abrupt changes of temperature gradient as also its reversals have been observed in burnt coal sections.  相似文献   

The prevention of cracking and water leakage in the concrete inner lining of frozen shafts     

Yu Gongchun 《Geotechnical and Geological Engineering》1986,4(3):247-251

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贵州瓮安玉山煤矿煤质特征及其影响因素          下载免费PDF全文

牛妍 《山东国土资源》2015,31(9)

玉山煤矿含煤地层为吴家坪组,可采煤层2层,具有中灰、中等挥发分、高硫分、低磷分、特低—低氯,低砷、高氟,中高发热量的煤质特征,煤类丰富,呈条带状分布。通过对区内沉积环境和煤的变质作用2个方面的分析,阐述了形成煤层高硫、中灰特征的影响因素,解释了煤类分带现象,并指出了主要煤质指标的变化规律。  相似文献   

煤矿开采对地下水的影响及其脆弱性评价   总被引：2，自引：0，他引：2  

张伟 《地下水》2010,32(1):13-14

在我国由于煤矿的大量开采,地下水资源的数量和质量受到严重影响,并且破坏了水的动态平衡和生态环境。一方面分析了采矿对地下水的破坏,另一方面通过对地下水的脆弱性评价警示人们在开发利用煤炭资源的同时对地下水资源采取有效的防治保护措施。  相似文献