Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry   总被引：1，自引：0，他引：1  

Shifeng Dai  Xiaoqiang Hou  Deyi Ren  Yuegang Tang   《International Journal of Coal Geology》2003,55(2-4):139-150

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.  相似文献   

Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector     

M. Barbaro  R. Herrera Urbina  C. Cozza  D. Fuerstenau  A. Marabini 《International Journal of Mineral Processing》1997,50(4):275-287

A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation.  相似文献   

Evidence of early generation of liquid hydrocarbon from suberinite as visible under the microscope   总被引：1，自引：0，他引：1  

Wan Hasiah Abdullah   《Organic Geochemistry》1997,27(7-8)

The early generation of liquid hydrocarbons from suberinite can be clearly observed under the microscope. The generation of this oil-like material, mainly in the form of exsudatinite, from the maceral suberinite occurs at a maturity level of about 0.4% vitrinite reflectance. Hydrocarbons appear to be naturally expelled from coal initially through sweating and agglomeration of suberinite which subsequently forms exsudatinite. It is suggested that extensive expulsion of exsudatinite causes cracks to develop in vitrinite whereas limited expulsion of exsudatinite will only impregnate the vitrinite matrix. If cracks are formed, it is possible they could progressively develop to form an exsudatinite-crack network. The formation of such a network is believed to represent an effective way of hydrocarbon expulsion from coal source rocks.  相似文献   

链子崖T_8－T_（12）缝段地下水的侵蚀性及其工程对策     

张明霞  刘传正 《地质灾害与环境保护》1996,(1)

在简述地形地貌、气象水文、构造部位和岩石组成等地质环境因素的基础上．本文重点研究了链子崖危岩体煤层采空区地下水的水化学类型及其对工程结构的侵蚀等级．并提出了地上排水、地下排水与采用抗侵蚀工程材料等综合的工程治理对策。  相似文献   

中国南方晚二叠世乐平煤的成因及成煤物质     

陈能贵 《海相油气地质》1996,1(2):29-33,T001

乐平煤是分布于苏浙皖赣地区龙潭组中的特有煤种(俗称树皮煤),也是一种具良好生烃潜力的烃源岩。乐平煤中,壳质组和可溶有机质含量高,母质类型为高等植物和低等生物双重来源,元素组成具富氢、低氧、高含硫的特征,应属海相成因的泥炭坪沉积。成煤物质主要来源于真蕨、种子蕨和科达类等植物的树皮体。树皮体又可分为茎皮体和根皮体两种亚组分。依据煤的显微组分组成和树皮体富集程度的不同,乐平煤可分为原地型、过渡型和微异地型三种成因类型。乐平煤的研究对整个南方二叠纪煤成烃资源的评价具重要的地质意义。  相似文献   

华北石炭——二叠纪煤系粘土岩夹矸中铝的氢氧化物矿物研究   总被引：4，自引：0，他引：4       下载免费PDF全文

梁绍暹  任大伟 《地质科学》1997,32(4):478-486

华北石炭——二叠纪煤系太原组和山西组不同煤层粘土岩夹矸中,广泛含有一水软铝石、一水硬铝石和三水铝石。大多数一水铝石矿物呈薄纹层状、似层状及层状聚集于富岩质及富有有机质粘土岩夹矸条带中,有的呈细脉状沿炭质条带及粘土岩夹矸层理的节理裂隙分布,并与玉髓、方解石、高岭石或迪开石和铵云母细脉共生。铝的氢氧化物矿物可以作为成岩古温度和成岩阶段划分的标志矿物。最后还讨论了该矿物的成因。  相似文献   

江苏煤层气资源分析     

傅学海  马筱英 《江苏地质》1997,21(2):120-123

简要地归纳了江苏省煤层气的成矿地质环境，分析了成煤区地质构造特征、煤层及围岩储层的物性特征，在此基础上，对主要地区煤层气资源进行了估算。  相似文献   

Predisposition to Induced Seismicity in Some Czech Coal Mines     

K. Holub 《Pure and Applied Geophysics》1997,150(3-4):435-450

—Mining-induced seismicity associated with longwall face operations in the Ostrava- Karviná coal mines, Czech Republic, has been investigated in order to establish the conditions leading to a focal zone generation. The study, based on macroseismic and instrumental observations, proved that seismicity is influenced by natural as well as mining conditions. The first group includes the influence of faults, washouts and red beds, while the second one is represented by shaft and/or crosscut safety pillars and various types of remnant pillars. All the cases discussed show that many focal zones are generated in overstressed strata as a consequence of interaction of natural conditions and/or old workings with the active coal face. Received June 18, 1996, accepted March 10, 1997  相似文献   

华北地台北缘拴马桩煤系   总被引：1，自引：0，他引：1  

张泓 《地层学杂志》1997,21(1):20-21,T001

狼山—色尔腾山和大青山的拴马桩煤系曾被认为是分布于华北地台北缘“内蒙地轴”上的晚古生代纯陆相山间盆地沉积。新的研究证明，上述两地的拴马桩煤系的时代并不完全等同，也不是纯陆相地层，更不是同一盆地的含煤沉积  相似文献   

恩洪-老厂地区煤层气成藏条件研究     

桂宝林 《云南地质》2004,23(4):421-433

煤层气盆地、煤层气系统、煤层气区带的存在及发育程度是煤层气藏形成的充分与必要条件。恩洪盆地和老厂一圭山盆地老厂煤矿区具备了形成煤层气藏的条件。研究其形成煤层气藏的特定条件，总结其煤层气藏模式，是煤层气勘探目标评价的基础。  相似文献