安徽铜陵新桥铜-硫-铁-金矿床中石英闪长岩和辉绿岩锆石SHRIMP年代学及其意义   总被引：48，自引：3，他引：48       下载免费PDF全文

王彦斌刘敦一  蒙义峰曾普胜杨竹森  田世洪 《中国地质》2004,31(2):169-173

对安徽铜陵新桥铜-硫-铁-金矿床区内的石英闪长岩和辉绿岩中的锆石分别进行了SHRIMP精确定年研究,石英闪长岩中锆石206Pb/238U年龄为(140.4±2.2)Ma,辉绿岩中锆石的年龄较复杂,其中发现了元古代锆石颗粒,其锆石207Pb/206Pb年龄为(2261±14)Ma,(1612±8)Ma,(919±12)Ma,(831±17)Ma。另外还有一组早古生代年龄的锆石,锆石206Pb/238U年龄为(443±13)Ma。以上这些新资料说明该区可能存在元古代基底的信息,且燕山期岩浆活动对本区成矿具有重要意义。  相似文献   

Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate   总被引：1，自引：0，他引：1  

L. Paul Bédard  Sarah-Jane Barnes 《Geostandards and Geoanalytical Research》2004,28(2):311-316

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.  相似文献   

Occurrence of Halogen-rich Phlogopite in Late Cenozoic Volcanic Rocks in the Japanese Arcs     

Akira Imai 《Resource Geology》2004,54(2):153-166

Abstract. Halogen-rich phlogopite occurs in the groundmass of andesite and dacite lavas from Late Tertiary to Quaternary volcanoes associated with native sulfur and limonite deposits (Shiretoko-Iwozan, Hachimantai, Adatara, Omeshidake, Masaki) and hydrothermal ore deposits (Harukayama, Muineyama, Hishikari) in Japan. The F contents of the halogen-rich phlogopite range from 3.6 to 5.7 wt%, corresponding to atomic F/(F+C1+OH) ratios ranging from 0.45 to 0.69. On the other hand, the Cl contents of the halogen-rich phlogopite are around 0.2 wt%. The atomic Mg/(Mg+Fe) ratios range from 0.69 to 0.83.
The fluorine intercept value [IV(F)] defined by Munoz (1984) of the phlogopites ranges from 0.79 to 3.17, and the chlorine intercept value [IV(Cl)] ranges from -7.11 to -7.77. The observed IV(F) of the phlogopites broadly overlap the range of the IV(F) for biotites from porphyry copper deposits. On the other hand, the observed IV(Cl) are significantly lower than the IV(Cl) for biotites from porphyry copper deposits. Whereas the F contents of the phlogopite appear more prominent compared to the Cl contents, the calculation of halogen intercept values revealed that the phlogopites are enriched in Cl with respect to the element distribution effect of Mg-Fe substitution. Since the degree of Cl enrichment of the phlogopite is more significant compared to that of biotite in porphyry copper deposits, the phlogopites are considered to have formed under the condition of significantly high activity of halogens. Hydrothermal ore deposits may be formed in magmatic hydrothermal system associated with volcanoes where halogen-rich phlogopite is formed by hypersaline fluid.  相似文献   

Oxidation of As-bearing gold ore—a comparison of batch and column experiments     

《Journal of Geochemical Exploration》2004,81(1-3):59-70

This study deals with the experimental determination of the rate of weathering and As release from Au-bearing sulfide ores of the Mokrsko-West deposit (Czech Republic). The elevated As contents in the ore and the possible As mobilisation must be taken into account due to the close proximity of the deposit to the Vltava River, a source of drinking water for Prague. Crushed and homogenized ore material was divided into four grain-size fractions showing uniform chemical and mineralogical composition and subjected to batch and column leaching experiments. The most important reactions controlling metal leaching include (i) oxidation of sulfides, (ii) carbonate equilibrium and (iii) precipitation of hydrated ferric oxides (HFO). Hydrated ferric oxides were found to be important sorbents of mobilized As. The highest concentration of As in the leachates was obtained from the 64–1000 μm fraction. The oxidation rate in the agitated batch experiment calculated on the basis of sulfate concentrations is an order of magnitude higher (3.8×10⁻⁹ to 4.4×10⁻⁸ mol SO₄²⁻ h⁻¹ g⁻¹) than in the static column experiment (9.6×10⁻¹⁰ to 7.4×10⁻⁹ mol SO₄²⁻ h⁻¹ g⁻¹). The higher oxidation rate of batch experiments is explained by abrasion of oxidation products (mainly HFO) and by further exposition of reaction surfaces of the sulfide grains.  相似文献   

Timing and intensity of groundwater movement during Egyptian Sahara pluvial periods by U-series analysis of secondary U in ores and carbonates     

J.K Osmond  Adel A Dabous 《Quaternary Research》2004,61(1):85-94

Wet climatic episodes are known to have prevailed in the Egyptian Sahara several times during the late Quaternary, most recently during the Holocene 8000 yr ago. Earlier wet episodes have been recognized as having occurred during the past 300,000 yr and have been dated by U-series methods in speleothems and in lake travertines. We show here that the times of enhanced groundwater movement can also be determined by ²³⁰Th/²³⁴U dating of secondary U in ores of uranium, iron, and phosphate. We also present evidence that such acceleration of groundwater movements is indicated by relatively low ²³⁴U/²³⁸U activity ratios in the secondary uranium. Our new data show that pluvial periods in Egypt occurred during marine oxygen isotope stages 4, 5, 6, and 7 and therefore are consistent with the view that the wet episodes are the results of migration of the tropical monsoonal belt driven primarily by the 23,000-yr precession cycle of the Milankovich curve, modulated by the 100,000-yr eccentricity cycle.  相似文献   

数学地质在矿山研究中的应用--判别分析归类矿体属性实例     

王友谊  曹宪双  李林山  于林辉 《吉林地质》2005,24(2):101-106

数学地质方法为宏观地质研究提供了定量的可能。判别分析对研究未知属性矿体的归属有着重要的意义。苏州西部地区通安——潭山多金属成矿带中，小茅山铜铅锌矿段，潭山铅锌银铁矿段位于成矿带的两端，属性已知。该成矿带中有一未知属性的铜铅锌银迂里矿段，用判别分析方法对其归类。研究结果表明，未知属性的迂里矿段归属潭山多金属硫化物矿床类型，即高—中温多金属硫化物矿床类型。  相似文献   

山东泰安朱家庄自然硫矿床地质概要     

郝尔宏 《化工矿产地质》2005,27(3):129-138,149

山东省泰安朱家庄自然硫矿床,赋存于鲁西断隆古近纪汶东陆相盆地。自然硫矿层在汶口组二段上亚段,泥质灰岩-含泥灰岩-含云灰岩-石膏岩韵律层中的白云岩-石膏岩层段发育。自然硫以胶态、晶态、土态3种形态产出,可划分为顺层型、准顺层型、斑杂型及不顺层型4大类10余种矿石类型。从矿区去膏化作用普遍、自然硫与石膏-硬石膏分别富集轻-重同位素的特征、油气显示明显及地下水主要径流方向自然硫矿化最强等各种证据,表明该矿属生物后生成因的矿床。  相似文献   

金龙——丘岭金矿床成矿流体的储运规律及区域找金方向     

刘新会 刘爽李渊  魏宽义 《地质找矿论丛》2005,20(8):10-14

金龙山——丘岭金矿区含金矿源为层上泥盆统南羊山组和下石炭统袁家沟组。组成含金矿源层岩石为高频互层的细碎屑岩-碳酸盐岩，其中细砂岩、粉砂岩、碳酸盐岩含成矿流体物性较好．页岩、板岩含成矿流体物性较差，构成屏蔽层。金鸡岭Ⅰ级复式向斜控制着金、砷、锑等异常范围；松枣Ⅱ级复式背斜控制着金的矿化带；金龙山-丘岭金矿Ⅲ级背斜控制着金的矿（化）体；镇安——板岩镇断裂的次级断裂是金矿化体的容矿有利位置。在成矿过程中，构造变形与成矿流体的形成、运移及储集密切相关。其规律是：①原生构造导致成矿流体的初次聚集。②第一期构造变形导致成矿流体的聚集。③第二期构造变形导致成矿流体运移及金矿床形成。此期变形是金的主要成矿期。④第三期构造变形使成矿流体进一步聚集和金矿体的富集。⑤第四期构造变形是石英方解石脉的形成时期。总结出矿床形成模式。据此提出了在4种不同的构造部位找金的方向。  相似文献   

西藏自治区乃东县劣布铜矿综合地质特征     

江化寨  陈自康 《地质找矿论丛》2005,20(8):81-86

文章介绍区域地质背景、矿区地物化特征，对成矿时代、流体包裹体特征进行初步研究，并指出找矿远景，希望对矿区的矿产勘查具有借鉴和指导意义。  相似文献   

广西南丹地区有色金属尾砂型人工矿床地质特征及其资源化     

陈志强苏亮  杨保疆 《地质找矿论丛》2005,20(8):139-144

广西南丹地区尾矿分布于大厂、车河、芒场等矿区。尾砂来自以锡石为主的多金属矿床，尾砂中除Sn，Pb，Zn，Ag，Sb的质量分数达到工业指标外，Au亦达到综合利用指标。通过试验证明，对尾矿中的细微粒锡石可采用风力分级选矿、磁选和化学选矿等方法回收；尾砂中的非金属资源可作为填充材料、水泥原料利用，使尾砂型人工矿床充分的资源化。  相似文献