Calcium Isotopic Fractionation during Ion‐Exchange Column Chemistry and Thermal Ionisation Mass Spectrometry (TIMS) Determination          下载免费PDF全文

Hong L. Zhu  Zhao F. Zhang  Gui Q. Wang  Yu F. Liu  Fang Liu  Xin Li  Wei D. Sun 《Geostandards and Geoanalytical Research》2016,40(2):185-194

Significant isotopic fractionation can occur during column chemistry and determination by mass spectrometry. Improper correction may produce uncertainties in the isotopic composition of geological samples. We investigated calcium isotopic fractionation during these two processes and set up a model to check data quality. The δ^44/40Ca_915a value of IAPSO seawater in different Ca cuts (e.g., 0–20, 20–40, 40–60, 60–80 and 80–100%) on column chemistry ranged from ~ 4‰ to 0‰. The more Ca was eluted, the lower the δ^44/40Ca_915a value of the elution was found. The isotopic fractionation of calcium on the column appeared to follow the exponential law. However, TIMS instrumental fractionation during Ca runs did not always follow the exponential law due to mixing effects from sample reservoirs on the filament. Our results show that errors could be caused if the instrumental fractionation deviates from the exponential law, especially when the fractionation degree is large. To improve the measurement uncertainty, a model is proposed to check the behaviour and degree of instrumental fractionation, which will provide a quick and reasonable verdict on the data quality of TIMS runs.  相似文献   

Precise and Accurate Doping of Nanoporous Silica Gel for the Synthesis of Trace Element Microanalytical Reference Materials          下载免费PDF全文

William O. Nachlas 《Geostandards and Geoanalytical Research》2016,40(4):505-516

This study presents an experimental procedure to fabricate high‐purity silica glass containing a selected element at a specified mass fraction. The procedure was used to prepare glasses doped with trace‐level mass fractions of Ti with the goal of improving analytical confidence when measuring trace elements in quartz. Systematic tests were performed to determine the ideal conditions and procedures for doping nanoporous silica gel with the highest efficiency of dopant recovery. Silica gel was cleaned in concentrated HCl, immersed in a non‐polar doping medium at a controlled pH and doped with precise quantities of ICP‐MS standard solution. Using liquids composed of longer chain molecules as the doping medium diminishes recovery, suggesting that large molecules could obstruct nanopores to inhibit capillary uptake of the dopant. A control experiment using crystalline quartz reinforced the effectiveness of nanoporous silica gel for doping with trace‐level precision. Layered aggregates of silica gel doped with different Ti mass fractions were hot‐pressed to create multi‐layered reference materials that were analysed with multiple techniques at a variety of spatial scales. Analyses at the intra‐grain scale (cathodoluminescence scanning electron microscopy, electron probe microanalysis), at the single grain scale (SIMS), at the sample layer scale (EPMA, laser ablation‐ICP‐MS) and at the bulk scale (ICP‐OES) demonstrated acceptable homogeneity at sample volumes characteristic of most microanalysis techniques and show that nanoporous silica gel holds promise as a highly retentive doping substrate for preparing reference materials for laser‐, electron‐ and ion‐beam microanalysis.  相似文献   

Episodic Cenozoic tectonism and the development of the NW European ‘passive’ continental margin     

D. Praeg  M.S. Stoker  P.M. Shannon  S. Ceramicola  B. Hjelstuen  J.S. Laberg  A. Mathiesen 《Marine and Petroleum Geology》2005,22(9-10):1007

The North Atlantic margins are archetypally passive, yet they have experienced post-rift vertical movements of up to kilometre scale. The Cenozoic history of such movements along the NW European margin, from Ireland to mid-Norway, is examined by integrating published analyses of uplift and subsidence with higher resolution tectono-stratigraphic indicators of relative movements (including results from the STRATAGEM project). Three episodes of epeirogenic movement are identified, in the early, mid- and late Cenozoic, distinct from at least one phase of compressive tectonism. Two forms of epeirogenic movement are recognised, referred to as tilting (coeval subsidence and uplift, rotations <1° over distances of 100s of Kilometres) and sagging (strongly differential subsidence, rotations up to 4° over distances <100 km). Each epeirogenic episode involved relatively rapid (<10 Ma) km-scale tectonic movements that drove major changes in patterns of sedimentation to find expression in regional unconformity-bounded stratigraphic units. Early Cenozoic tilting (late Paleocene to early Eocene, c. 60–50 Ma) caused the basinward progradation of shelf-slope wedges from elongate uplifts along the inner continental margin and from offshore highs. Mid-Cenozoic sagging (late Eocene to early Oligocene, c. 35–25 Ma) ended wedge progradation and caused the onset of contourite deposition in deep-water basins. Late Cenozoic tilting (early Pliocene to present, <4±0.5 Ma) again caused the basinward progradation of shelf-slope wedges, from uplifts along the inner margin (including broad dome-like features) and from offshore highs. The early, mid- and late Cenozoic epeirogenic episodes coincided with Atlantic plate reorganisations, but the observed km-scale tectonic movements are too large to be accounted for as flexural deflections due to intra-plate stress variations. Mantle–lithosphere interactions are implied, but the succession of epeirogenic episodes, of differing form, are difficult to reconcile with the various syn-to post-rift mechanisms of permanent and/or transient movements proposed in the hypothetical context of a plume beneath Iceland. The epeirogenic movements can be explained as dynamic topographic responses to changing forms of small-scale convective flow in the upper mantle: tilting as coeval upwelling and downwelling above an edge-driven convection cell, sagging as a loss of dynamic support above a former upwelling. The inferred Cenozoic succession of epeirogenic tilting, sagging and tilting is proposed to record the episodic evolution of upper mantle convection during ocean opening, a process that may also be the underlying cause of plate reorganisations. The postulated episodes of flow reorganisation in the NE Atlantic region have testable implications for epeirogenic movements along the adjacent oceanic spreading ridge and conjugate continental margin, as well as on other Atlantic-type ‘passive’ margins.  相似文献   

The scaling of the meridional overturning with the meridional temperature gradient in idealised general circulation models     

M.A. Lucas  J.J. Hirschi  J. Marotzke 《Ocean Modelling》2006,13(3-4):306-318

The scaling law linking the strength of the meridional overturning to the surface meridional temperature gradient is re-examined in two ocean general circulation models at coarse resolution in an idealised single-hemisphere setting. Two sets of results are presented, where the surface meridional temperature gradient is decreased either by increasing the northernmost temperature and keeping the equator temperature fixed, or by decreasing the equator temperature and keeping the northernmost temperature fixed. The maximum of the meridional overturning first increases and then decreases when the northernmost temperature is gradually increased, whereas the maximum overturning decreases monotonically when the equator temperature is decreased. No scaling law can be derived when the northernmost temperature is increased, whereas a 2/3 power law is found when the temperature is decreased at the equator. The behaviour of the overturning is strongly influenced by the vigour and, particularly, the spatial patterns of convection, which vary substantially between the two sets and which control the horizontal and vertical density gradients at high latitudes.  相似文献   

Estimation by photogrammetry of the glacier recession on the Cotopaxi Volcano (Ecuador) between 1956 and 1997 / Estimation par photogrammétrie de la récession glaciaire sur le Volcan Cotopaxi (Equateur) entre 1956 et 1997     

《水文科学杂志》2013,58(6)

Abstract

Aerial photographs of the Cotopaxi Volcano ice cap dating from 1956 to 1997 were used to quantify the evolution of the surface area. Results were obtained using precise stereoscopic methods that give the most accurate information. In addition four specific glacier tongues were investigated in detail to measure the ice mass lost between 1976 and 1997. Surprisingly, the bedrock morphology is shown to be very irregular and this explains a large extent of the variability found in the ice losses. The results show that glaciers stagnated from 1956 to 1976 and lost about 30% of their surface area between 1976 and 1997. Slope exposure did not seem to have any significant effect since all the glaciers of the volcano retreated in the same proportion. In accordance with specific measurements performed on the nearby Antizana 15 Glacier, it is suggested that the strong recession observed after 1976 was associated with increasing melting conditions which have occurred repeatedly during the intense/long-duration warm ENSO phases.  相似文献   

Trends in frequency of precipitation extremes in the Yangtze River basin,China: 1960–2003 / Tendances d'évolution de la fréquence des précipitations extrêmes entre 1960 et 2003 dans le bassin versant du Fleuve Yangtze (Chine)     

《水文科学杂志》2013,58(3)

Abstract

The spatial distribution and trends in the frequency of precipitation extremes over the last 44 years (1960–2003), especially since 1990, have been analysed using daily precipitation data from 147 stations in the Yangtze River basin. The research results are as follows: (1) The 15 mm precipitation isohyet approximately divides the precipitation extremes (corresponding to the 95th percentile) of the stations in the middle and lower Yangtze reaches (higher) from those of the upper Yangtze reaches (lower). Also the starting time of the precipitation extremes in the middle and lower Yangtze reaches is earlier than of those in the upper Yangtze reaches. Precipitation extremes are concentrated mostly in June in the middle and lower Yangtze reaches, and July in the upper Yangtze reaches. (2) During the period 1960–2003, the first two decades had fewer precipitation extremes than the last two decades. There have been significant increasing trends and step changes in frequency of annual total precipitation extremes and precipitation extremes with a 1–5 day gap in the middle and lower Yangtze reaches. Precipitation extremes occur more frequently in shorter periods, separated by a few days. Precipitation extremes are also becoming more concentrated in the month with the highest frequency of extremes (June) in the middle and lower Yangtze reaches. In the upper Yangtze reaches, there is an upward tendency of extreme events in June. Increasing precipitation extremes in June for both the middle and lower, and the upper Yangtze reaches will increase the probability of flooding if the observed trends of the last 40 years continue into the future.  相似文献   

Buoyancy-driven perturbations in a rapidly rotating,electrically conducting fluid: part II – dynamo action     

Arnaud Chulliat  Hisayoshi Shimizu  David E. Loper 《地球物理与天体物理流体动力学》2013,107(6):471-487

The helicity, electromotive force and α-effect produced in a homogeneous, rapidly rotating, electrically conducting fluid by an isolated source of buoyancy at small Elsasser number are calculated, visualized and analyzed. Due to physical symmetries of the system, the integrals of helicity and electromotive force over all space are zero. However, each has a significant non-zero value when integrated over the cross section of the Taylor column. The local α-effect is found to be significantly anisotropic; it is strongest when the applied magnetic field is toroidal and the resulting EMF is parallel to the applied field.  相似文献   

Convection in a rotating,laterally heated annulus transition to lower symmetry     

E. R. Lewis  E. L. Koschmieder 《地球物理与天体物理流体动力学》2013,107(1-2):37-47

Abstract

The radial temperature differences at which the transition from lower symmetry to the wave regime and the transition from the wave regime to lower symmetry occur have been measured for rotation rates ≦2rad/sec. It was found that the temperature differences at which the transitions occur differ for a fixed rotation rate, depending on whether the radial temperature difference is either increased or decreased with time. There is hysteresis in the transition at lower symmetry.  相似文献   

An experimental investigation of convection in a rotating sphere subject to time varying thermal boundary conditions     

J. A. Chamberlain  C. R. Carrigan 《地球物理与天体物理流体动力学》2013,107(1-4):303-327

Abstract

A series of experiments has been undertaken to investigate the onset of convection in a rapidly rotating fluid filled sphere. The boundary is subjected to a time varying temperature allowing the simulation of radial temperature profiles associated with internal heating. The system is similar to that treated theoretically by Roberts (1968), Busse (1970) and Soward (1977). It is found that Busse's modification of Roberts' linear analysis, taking into account velocity perturbations which are antisymmetric about the equatorial plane, provides a good estimate of the temperature gradient required to initiate convection. As observed in the experiments of Carrigan and Busse (1983) and predicted by linear theory, convection appears in the form of rolls or columns, aligned parallel to the rotation axis. As in earlier experiments, observed azimuthal wavenumbers are consistently smaller than predicted which we postulate to be a consequence of nonlinear effects. Owing to the presence of a centrifugally driven thermal wind, the predicted azimuthal drift of the rolls has not been observed.  相似文献   

Convection in a rotating magnetic system and taylor's constraint part II,numerical results     

P. H. Skinner  A. M. Soward 《地球物理与天体物理流体动力学》2013,107(1-4):335-356

Abstract

Results are presented of a numerical study of marginal convection of electrically conducting fluid, permeated by a strong azimuthal magnetic field, contained in a circular cylinder rotating rapidly about its vertical axis of symmetry. To this basic state is added a geostrophic flow U_G (s), constant on geostrophic cylinders radius s. Its magnitude is fixed by requiring that the Lorentz forces induced by the convecting mode satisfy Taylor's condition. The nonlinear mathematical problem describing the system was developed in an earlier paper (Skinner and Soward, 1988) and the predictions made there are confirmed here. In particular, for small values of the Roberts number q which measures the ratio of the thermal to magnetic diffusivities, two distinct regions can be recognised within the fluid with the outer region moving rapidly compared to the inner. Otherwise, conditions for the onset of instability via the Taylor state (U_G 0) do not differ significantly from those appropriate to the static (U_G = 0) basic state. The possible disruption of the Taylor states by shear flow instabilities is discussed briefly.  相似文献