A carbonate-hosted stratabound siliceous crust type (SCT) mineralization (base metal sulphides, barite, fluorite) occurs over large areas of Carnic Alps and Karawanken in the Eastern Alps. It concerns a pervasively silicified lithological unit, up to some tens of metres thick, which caps the unconformity landscapes developed on epicontinental Devonian–Dinantian carbonates. The SCT mineralization is directly overlaid by different transgressive siliciclastic sediments, which range from Lower Carboniferous to Lower Permian. The presence of fragments of the SCT mineralization in the transgressive siliciclastic sediment bounds its whole lithological evolution within a short stratigraphic interval of Lower Carboniferous age. Selected features of the regional and lithostratigraphic setting are discussed. The chemical characterisation is based on the statistical evaluation of compositional data of 581 selected samples. Three significant groups of elements have been distinguished: (1) the hydrological and metasomatically active elements (Si, Ba, F), which show a strong negative correlation amongst themselves and characterise the silica-saturated aqueous solutions; (2) the terrigenous elements (Al2O3, K2O, Fetot, TiO2, B, Be, Ce, La, Nb, V, Y, Zr), which suggest a continental margin environment for silica deposition; (3) the sulphide metals (Cu, Pb, Zn, Ni, Sb, As, Hg, Cd), which define the metalliferous signature of the SCT mineralization.Some consistent, but still debatable genetic aspects of the SCT mineralization are as follow: (1) silica may be supplied by illitization of clay-rich basinal sediments during their diagenesis. δ18O of microcrystalline quartz ranges from +18.5‰ and +24.6‰ and is very similar to δ18O of authigenic quartz deriving from diagenetic processes of illitization of clay-rich basinal sequences. (2) The diagenetic evolution of these sediments may trigger off the movement of silica-rich marine pore waters. δ34S of barite ranges from +15.5‰ to +19.3‰ with an average of +17.7‰ and are in good agreement with δ34S of sulphate in ocean waters of Upper Devonian–Lower Carboniferous age. (3) A convective hydrological system, connected with sinsedimentary transtensive tectonics, active in the Carnic Alps since the Frasnian, may be the transport mechanism of aqueous solutions. (4) A weak drop in pH in the dominant carbonate environment represents the conditions for silica precipitation.SCT mineralization, showing persistent, independent and distinct characters, occurs over large areas also in other sites of the Alpine belt and outside Italy and Austria. Therefore, it points to important markers for some sedimentary sequences as well as to a worldwide significant cyclic metallogenic event. It represents a new ore deposit-type within the carbonate-hosted mineralization. 相似文献
The VRANCEA99 seismic refraction experiment is part of an international and multidisciplinary project to study the intermediate depth earthquakes of the Eastern Carpathians in Romania. As part of the seismic experiment, a 300-km-long refraction profile was recorded between the cities of Bacau and Bucharest, traversing the Vrancea epicentral region in NNE–SSW direction.
The results deduced using forward and inverse ray trace modelling indicate a multi-layered crust. The sedimentary succession comprises two to four seismic layers of variable thickness and with velocities ranging from 2.0 to 5.8 km/s. The seismic basement coincides with a velocity step up to 5.9 km/s. Velocities in the upper crystalline crust are 5.9–6.2 km/s. An intra-crustal discontinuity at 18–31 km divides the crust into an upper and a lower layer. Velocities within the lower crust are 6.7–7.0 km/s. Strong wide-angle PmP reflections indicate the existence of a first-order Moho at a depth of 30 km near the southern end of the line and 41 km near the centre. Constraints on upper mantle seismic velocities (7.9 km/s) are provided by Pn arrival times from two shot points only. Within the upper mantle a low velocity zone is interpreted. Travel times of a PLP reflection define the bottom of this low velocity layer at a depth of 55 km. The velocity beneath this interface must be at least 8.5 km/s.
Geologic interpretation of the seismic data suggests that the Neogene tectonic convergence of the Eastern Carpathians resulted in thin-skinned shortening of the sedimentary cover and in thick-skinned shortening in the crystalline crust. On the autochthonous cover of the Moesian platform several blocks can be recognised which are characterised by different lithological compositions. This could indicate a pre-structuring of the platform at Mesozoic and/or Palaeozoic times with a probable active involvement of the Intramoesian and the Capidava–Ovidiu faults. Especially the Intramoesian fault is clearly recognisable on the refraction line. No clear indications of the important Trotus fault in the north of the profile could be found. In the central part of the seismic line a thinned lower crust and the low velocity zone in the uppermost mantle point to the possibility of crustal delamination and partial melting in the upper mantle. 相似文献
