Valence state mapping and quantitative electron spectroscopic imaging of exsolution in titanohematite by energy-filtered TEM     

U. Golla  A. Putnis 《Physics and Chemistry of Minerals》2001,28(2):119-129

 The microstructure of hematite-ilmenite exsolution intergrowth of a natural titanohematite crystal from a granulite has been investigated in a transmission electron microscope equipped with an energy filter. Special emphasis is on quantitative compositional mapping at the nanometre scale using electron spectroscopic imaging, as well as mapping the Fe³⁺ and Fe²⁺ valence distribution in the intergrowth. Quantitative point analyses by energy-dispersive X-ray analysis have been compared with results from electron energy-loss spectroscopy and element-distribution mapping. The results indicate that the coexisting compositions of the two phases (Ilm₈₈Hem₁₂ and Ilm₁₆Hem₈₄) are independent of the size of the exsolution. The application of quantitative mapping to determining diffusion profiles around precipitates is demonstrated. Received: 30 March 2000 / Accepted: 7 September 2000  相似文献   

Measurements of free radicals in the atmosphere by matrix isolation and electron paramagnetic resonance     

D. Mihelcic  D. H. Ehhalt  G. F. Kulessa  J. Klomfass  M. Trainer  U. Schmidt  H. Röhrs 《Pure and Applied Geophysics》1978,116(2-3):530-536

With some special adaptations the technique of matrix isolation followed by detection through electron paramagnetic resonance (EPR) can also be used for the measurement of atmospheric radical concentrations. A light weight cryogenic sampling device has been constructed. It uses condensation of atmospheric CO₂ or H₂O at 77 K for matrix formation and trapping of the radicals. The sampler has been flown on a balloon for stratospheric sampling. First data on stratospheric, HO₂ and NO₂ at 32 km altitude have been obtained on a flight on 8 August 1976 and will be reported.  相似文献   

The use of electron backscatter diffraction and orientation contrast imaging as tools for sulphide textural studies: example from the Greens Creek deposit (Alaska)     

Katja?Freitag  Alan?P.?BoyleEmail author  Eric?Nelson  Murray?Hitzman  James?Churchill  Magda?Lopez-Pedrosa 《Mineralium Deposita》2004,39(1):103-113

The Greens Creek polymetallic massive sulphide deposit is hosted in a typical polyphase deformed lower greenschist facies orogenic setting. The structure of the host rocks is well constrained, exhibiting a series of three superimposed ductile deformations followed by two brittle episodes. The ore is found both in fold hinges where early-formed depositional features are preserved and in fold limbs where primary features are typically strongly modified or obliterated. Samples from both settings have been investigated using electron backscatter diffraction (EBSD) coupled with forescatter orientation contrast (OC) imaging in order to observe the effects of deformation and lower greenschist facies metamorphism on pyrite. Results suggest that colloform pyrite may preserve information relevant to palaeoenvironment, that apparently simple textures are generally more complex, and that pyrite can deform plastically by dislocation glide and creep processes at lower temperatures and/or strain rates than generally accepted. This analysis indicates that EBSD and OC imaging provide powerful tools for observing textural relationships in pyrite that are not shown by more traditional methods. They should become routine tools for pyrite texture analysis.Editorial handling: D. Lentz  相似文献   

Point defects in crystalline zircon (zirconium silicate), ZrSiO<Subscript>4</Subscript>: electron paramagnetic resonance studies     

W. C.?TennantEmail author  R. F. C.?Claridge  C. J.?Walsby  N. S.?Lees 《Physics and Chemistry of Minerals》2004,31(4):203-223

This article outlines the present state of knowledge of paramagnetic defects in crystalline zircon as obtained mainly, but not exclusively, from electron paramagnetic resonance (EPR) studies in crystalline zircon (zirconium silicate, ZrSiO₄). The emphasis is on single-crystal studies where, in principle, unambiguous analysis is possible. Firstly, the crystallography of zircon is presented. Secondly, the relationships between available crystal-site symmetries and the symmetries of observed paramagnetic species in zircon, and how these observations lead to unambiguous assignments of point-group symmetries for particular paramagnetic species are detailed. Next, spin-Hamiltonian (SH) analysis is discussed with emphasis on the symmetry relationships that necessarily exist amongst the Laue classes of the crystal sites in zircon, the paramagnetic species occupying those sites and the SH itself. The final sections of the article then survey the results of EPR studies on zircon over the period 1960–2002.  相似文献   

Strong magnetic linear dichroism in Fe <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript> and O <Emphasis Type="Italic">K</Emphasis> electron energy-loss near-edge spectra of antiferromagnetic hematite α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>     

P. A.?van AkenEmail author  S.?Lauterbach 《Physics and Chemistry of Minerals》2003,30(8):469-477

We report strong magnetic linear dichroism (MLD) at the Fe L₂₃ and O K edges of the antiferromagnetic compound hematite -Fe₂ O₃ in high-resolution orientation- and temperature-dependent electron energy-loss spectroscopy (EELS). Large intensity differences of corresponding spectral features are observed when the Fe L₂₃ and O K edges are measured with momentum transfer either parallel or perpendicular to the magnetization. The resultant difference spectra for the Fe L₂₃ edges is consistent with the MLD observed in X-ray absorption spectroscopy. For the first time we have observed MLD at the O K edge, where the magnetic origin of this dichroism is demonstrated by temperature-dependent investigations across the Morin transition temperature T_M= 263 K, at which the Fe electron spins, i.e. the magnetic moments, rotate by 90°. The O K edge MLD is interpreted in terms of superexchange between the spins of the Fe 3d and O 2p electrons through overlapping Fe 3d and O 2p orbitals. The experiments were performed in a transmission electron microscope (TEM), yielding information about the anisotropic electronic structure at nanoscale spatial resolution when operated with a focused electron probe. The effects of MLD at the Fe L₂₃ edges on the determination of Fe³⁺/Fe in hematite at submicrometre scale using different independent quantification methods are discussed.  相似文献   

Electron microprobe dating of monazite substantiates ages of major geological events in the southern Brazilian shield   总被引：1，自引：0，他引：1  

Hugo Tickyj  Lo A. Hartmann  Marcos A. Z. Vasconcellos  Ruy P. Philipp  Marcus V. D. Remus 《Journal of South American Earth Sciences》2004,16(8):84

To obtain the chemical Th^*–Pb isochron ages and surface maps of monazite crystals in igneous and metamorphic rocks from the southern Brazilian Shield, we employ Th–U-total Pb dating by an electron probe microanalyzer. The ages of two Trans-Amazonian metamorphic events are given by a felsic, garnet-bearing granulite from the Santa Maria Chico granulitic complex. The age of the first event, at approximately 2.35 Ga, was obtained by surface mapping in a grain included in garnet. The dating of the second event, 1899±43 Ma, is in agreement with previous data obtained in zircon crystals with sensitive high-resolution ion microprobe. Other determinations belong to the Brasiliano cycle. In the São Gabriel block, an age of 643±129 Ma was obtained on monazite from a staurolite-garnet schist of the Cambaizinho Formation, whereas a staurolite-bearing schist from the Passo Feio complex yielded a 510±68 Ma age. Several units in the Dom Feliciano belt were dated, including the biotite-sillimanite gneisses of the Várzea do Capivarita complex (552±90 Ma), the sillimanite-garnet gneisses of Camboriú complex (565±77 Ma), the Três Figueiras granite (558±57 Ma), and the Plaza Itapema granite (545±55 Ma). The ages presented in this study, obtained through monazite chemical dating, are confirmed through comparison with previous data regarding zircon crystals from the same geological units.  相似文献   

Temperature–time paths from phosphate accessory phase paragenesis in the Honey Brook Upland and associated cover sequence, SE Pennsylvania, USA     

Joseph M. Pyle 《Lithos》2006,88(1-4):201-232

Analysis of monazite-bearing lithologies from the Precambrian Honey Brook Upland (HBU) and overlying metasedimentary Paleozoic Chester Valley Sequence (CVS) (SE PA, USA) reveals overprinting of primary major and accessory phase parageneses by texturally and compositionally disparate secondary accessory phase parageneses. Two-pyroxene temperatures of 915–945 °C for reconstituted pyroxene reflect emplacement temperatures of felsic plutonic rocks (opdalite, charnockite) prior to Mesoproterozoic metamorphism. Monazite in metavolcanic felsic gneiss yields three age domains at 1009 ± 4 Ma (2 s.e.), 965 ± 6, and 876 ± 10 Ma. The first two domains record metamorphism of the HBU after anorthosite intrusion; peak monazite–xenotime temperatures for the monazite core domain are 700 °C, and high Th/U values in the second (overgrowth) age domain likely reflect a second high-T monazite growth episode. Formation of cummingtonite coronas on orthopyroxene in opdalite constrains maximum 1010 Ma metamorphic temperatures in the “granulite-facies” terrane to 730–740 °C. Evidence of increased Cl fluid activity in the 965 Ma metamorphism includes higher Cl content of matrix apatite relative to garnet-included apatite (metavolcanics), and Cl-bearing K-hornblende succeeding cummingtonite in coronal overgrowths (opdalite). Extreme monazite Th/U values (75–250) in the rim domain suggest growth during low-T hydrothermal alteration. In the opdalite, secondary singe-grain monazite and monazite + xenotime metasomites in apatite yield ages of 714 ± 24 and 586 ± 88 Ma, temperatures of 325–425 °C, and are interpreted to reflect thermal disturbances associated with late Proterozoic plutonic and volcanic activity in the Upland. This thermal disturbance may be recorded by Rb–Sr age of 567 Ma for biotite from a HBU gneiss. Monazite age domains in metaquartzite (378 ± 28, 272 ± 44 Ma) suggest that low-grade metamorphism (260–320 °C, Mnz–Xno thermometry) of the CVS is not a result of Taconian orogenesis.  相似文献   

Electron temperatures during rapid subauroral ion drift events     

R. J. Moffett  A. E. Ennis  G. J. Bailey  R. A. Heelis  L. H. Brace 《Annales Geophysicae》1998,16(4):450-459

Examples of data from DE-2 satellite instruments are presented. These illustrate the behaviour of plasma parameters in the F-region and adjacent topside ionosphere during rapid sub-auroral ion drift (SAID) events. In particular, a variety of behaviours of the electron temperature (T_e) is demonstrated, both within and equatorward of the SAID region. The Sheffield University plasmasphere-ionosphere model (SUPIM) is used to perform calculations in which a model SAID is applied to a plasma flux tube. The model results indicate that strongly elevated ion temperature (a recognised signature of SAID events) is on occasion sufficient to raise T_e to observed values by ion-electron heat transfer. On other occasions, an additional heat source is required. It is suggested that such a source for the electron gas may be due to interaction between the ring current and the plasmasphere at high altitudes. The magnitude of the downward heat flux is consistent with that necessary to produce sub-auroral red arcs. The resulting strongly heated electron gas causes vibrational excitation of molecular nitrogen in the thermosphere.  相似文献   

山东蓝宝石中包裹体的研究   总被引：4，自引：1，他引：4  

王萍  李国昌 《矿产与地质》1996,10(4):251-255

山东蓝宝石中含有不同类型的包裹体，其中固态包裹体主要有镁铁尖晶石、普通辉石、钾长石、铌铁金红石和磁铁矿等。山东蓝宝石以及大部分固态包裹体中皆含有稀有元素铌或钽。  相似文献   

Debris from the basal ice of the Agassiz ice cap,Ellesmere Island,arctic Canada     

A. M. D. Gemmell  M. J. Sharp  D. E. Sugden 《地球表面变化过程与地形》1986,11(2):123-130

This article describes the characteristics of debris obtained from the basal ice in a borehole in the Agassiz ice cap, Ellesmere Island, Northwest Territories by the Canadian Polar Continental Shelf Project in 1979. The debris appears to have been incorporated by basal freezing at a time when the base of the glacier upstream was near the pressure melting point and some 19°C warmer than at the present site. Such an occurrence may be explained by a different flow regime, by a thicker ice sheet, by the influence of irregular bedrock topography on basal ice conditions at some stage in the past, or by a combination of these factors.  相似文献