The accumulating volumes of data collected within environmental monitoring programs facilitate the use of exploratory statistical methods of data analysis as a supplement to traditional methods of characterizing lake water quality. When principal component analysis and multidimensional scaling are applied to a matrix containing approximately 24000 samples of lake water quality variables pH, alkalinity, conductivity, hardness, color, Secchi depth and total phosphorus concentration, it is found that the total matrix variance can be approximately reproduced in an orthogonal two-dimensional base with transformations of hardness and color as best principal component representatives. This base is suggested as an empirical lake classification standard where the variance structure of subset lake populations (such as single lakes) can be referenced to the water quality standard of the generic population. Since the principal axes of the base exclusively contain inorganic and organic related variables respectively, the combined inorganic/organic characteristics of the lake can be expressed with the hardness and color variables alone. With the data matrix being large enough to produce high significance levels, and with variable ranges wide enough to represent a majority of dimictic, glacial/boreal lakes, the analysis results should be valid in many lakes throughout the world. 相似文献
A previous analysis [Improta, L., G. Di Giulio, and A. Rovelli (2005). Variations of local seismic response in Benevento (Southern Italy) using earthquakes and ambient noise recordings, J. Seism. 9, 191–210.] of small magnitude earthquakes recorded at 12 sites within the city of Benevento has stressed the significant role played by near-surface geology in causing variability of the ground motion. In this paper, we extend the study of the seismic response from 12 sites to the entire urban area. Based on inferences from the comparison at the 12 sites between earthquake and ambient vibration results, we have collected ambient noise at about 100 sites within the city, intensifying measurements across the main shallow geological variations. We use borehole data to interpret ambient noise H/V spectral ratios in terms of near-surface geology comparing H/V curves to theoretical transfer functions of 1D models along five well-constrained profiles.
On the basis of geological, geotechnical, and seismic data, we identify three main typologies of seismic response in the city. Each type of response is associated to zones sharing common soil conditions and similar soil classes according to building codes for seismic design. Moreover, we find that the spatial variation of the seismic response in the ancient town area is consistent with the damage pattern produced by a very destructive, well-documented historical earthquake that struck the city in 1688, causing MCS intensity of IX–X in Benevento.
Finally, we use ground motions recorded during the experiment by Improta et al. [Improta, L., G. Di Giulio, and A. Rovelli (2005). Variations of local seismic response in Benevento (Southern Italy) using earthquakes and ambient noise recordings, J. Seism. 9, 191–210.] to generate synthetic seismograms of moderate to strong (Mw 5.7, Molise 2002 and Ms 6.9, 1980 Irpinia) earthquakes. We calibrate the random summation technique by Ordaz et al. [Ordaz, M., J. Arboleda, and S.K. Singh (1995). A scheme of random summation of an Empirical Green's Function to estimate ground motions for future large earthquakes, Bull. Seism. Soc. Am. 85, 1635–1647.] using recordings of these earthquakes available in Benevento. After a satisfactory fit between observed and synthetic seismograms, we compute response spectra at different sites and speculate on effects of the geology class at large level of shaking, including soil nonlinearity. We find that large discrepancies from design spectra prescribed by seismic codes can occur for a wide sector of Benevento, especially for periods < 0.5 s. 相似文献
The order-disorder phase transitions in NaNO3 and CaCO3 are simulated by molecular dynamics. The simulations are based on the potentials calculated from the Gordon–Kim modified
electron gas formalism extended to molecular ions. We successfully reproduced the transition temperature Tc and the abnormally large c axis thermal expansion observed in experiment. The phase transitions in NaNO3 and CaCO3 were found to be initiated by ±60 and ±180° reorientation of the NO3 and CO3 ions about the c axis. The orientations of NO3 and CO3 ions are continuous with six preferred calcite-type orientations above the phase-transition temperature.
Received: 30 January 2001 / Accepted: 11 May 2001 相似文献
Hydrogen incorporation is critical for explaining defect energies, structure parameters and other physical characteristics of minerals and understanding mantle dynamics. This work analyzed the hydrogen complex defects in jadeite by the plane-wave pseudo-potential method based on density functional theory, and optimized the atomic positions and lattice constants in all configurations(different defective systems). Incorporation mechanisms considered for hydrogen(H) in jadeite include:(1) hydrogen incorporating with the O2 site oxygen and coexisting with M2 vacancy;(2) one H atom combined with an Al atom replacing Si in tetrahedron;(3) 4H atoms directly replacing Si in tetrahedron and(4) 3H atoms replacing Al on the M1 site. The four incorporation mechanisms mentioned above form the corresponding V_(Na)-H_i, Al_(Si)-H_i, V_(Si)-4H_i and V_(Al)-3H_i point defects. The molecular dynamics simulation to the ideal, V_(Na)-H_i, Al_(Si)-H_i, V_(Si)-4H_i and V_(Al)-3H_i point defects under the P-T conditions of 900 K, 2 GPa, the V_(Na)-H_i and Al_(Si)-H_i point defects under different pressures at T = 900 K, and Al_(Si)-H_i point defects under different temperatures at P = 3 GPa was performed to examine the preferential mode of hydrogen incorporation in jadeite by means of first-principles calculations. The calculations show that the averaged O–H bond-length in the hydrogen point defects system decreased in the order of Al_(Si)-H_i, V_(Na)-H_i, V_(Si)-4H_i and V_(Al)-3H_i. V_(Na)-H_i complex defects result in a contraction of the jadeite volume and the presence of Al_(Si)-H_i, V_(Si)-4H_i and V_(Al)-3H_i defects could increase the supercell volume, which is the most obvious in the V_(Al)-3H_i defects. The energy of formation of Al_(Si)-H_i and V_(Al)-3H_i complex defects was much lower than that of other defect systems. The V_(Al)-3H_i defects system has the lowest energy and the shortest O–H bond-length, suggesting that this system is the most favorable. The analytical results of vacancy formation energy, O–H bondlength, and the stability of the hydrogen defects in jadeite have suggested that the preferred hydration incorporation mode in jadeite is V_(Al)-3H_i complex defect. 相似文献
Estimation of prospect outcome probabilities in numerical form should be a central objective for petroleum geologists. Most numerical estimates of outcome probabilities represent subjective guesses. While the effectiveness of subjective procedures is difficult to gauge, several postmortem analyses suggest that subjective procedures are ineffective. Objective procedures for estimating outcome probabilities should yield much improved estimates. Objective procedures require that geological, geophysical and production data be organized so that geological and geophysical characteristics of prospects interpreted before they were drilled can be compared systematically with outcomes of prospects after they have been drilled. An example application that involves well data and an example application that involves seismic data demonstrate that objective procedures are simple in principle, but require organization of information in a form suitable for computation of frequencies, on which objective estimates of probabilities can be based. 相似文献