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101.
102.
Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO
4
2–
: 84.2, NO
3
–
: 28.1, Cl–: 86.3, NH
4
+
: 45.5, Ca2+: 63.3, Mg2+: 27.0, K+: 3.4, Na+: 69.0 µ eq l–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO
4
2–
/NO
3
–
exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl– and Na+, ex-SO
4
2+
and ex-Ca2+, NO
3
–
and ex-Ca2+, and NH
4
+
and ex-SO
4
2–
, respectively. However, no correlation between Cl– and Na+ with Ca2+ was observed. The relationship of H+ with (ex-SO
4
2–
+ NO
3
–
) - (ex-Ca2+ + NH
4
+
) indicated positive correlation. 相似文献
103.
矿山地理信息系统中的空间和时间四维数据模型 总被引:8,自引:2,他引:8
现有的许多地理信息系统(GISs)一般都没有考虑时间这一维数据。本文依据矿山的特点和需求,提出了能满足空间和时间要求的GIS的概念。针对传统数据模型所存在的缺点,以及根据处理历史数据所具有的特点,提出了一种用于矿业开发的空间和时间综合四维数据模型。这种模型通过采用四维空间线性编码技术,可大大减少数据存贮所需的辅助操作。为了适应综合四维数据处理的需要,笔者研究出了一种新的拓扑结构——四维空间和时间因素的拓扑关系。 相似文献
104.
A series of novel long-chain 3,4-dialkylthiophenes (C36–C54) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment. 相似文献
105.
在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。 相似文献
106.
This paper deals with the influence of different humic substances (HS) on the enzyme activity (EA) of the proteolytic enzyme pronase E. The EA was determined by analyzing the concentration of the amino acid valine hydrolyzed from caseine. For amino acid analysis, a flourescence detector was used after precolumn derivatization and HPLC-separation of the hydrolysis products. The data show that the presence of HS has no adverse effects on amino acid analysis. Based on this result, a decrease of EA was observed in the presence of HS acting as enzyme inhibitors. Clear inhibition effects could be seen for different fulvic acids (HO3 FA, FBR FA and FBR 1.0 FA) at concentrations of 150 mg/L. In case of FBI-2 FA, higher concentrations were necessary to decrease the EA significantly. At an inhibitor concentration of 1500 mg/L the EA was mostly found to be less than 50%. The standard deviations of the results don't allow a differentiation between the HS of different origin and treatment. Specifying HS according to their influence on EA has to remain uncertain. As shown in a kinetic study of the hydrolysis of L-Leucine-2-naphthylamide-hydrochloride, the inhibitor HO3 FA decreases the maximum velocity of the reaction but has no effect on the Michaelis constant. These results indicate that this HS acts as a noncompetitive inhibitor. 相似文献
107.
The Eocene Maoming oil shale from Guangdong Province occurs as a laterally uniform stratigraphic section, typically 20–25 m thick, from which the aliphatic hydrocarbon constituents of six representative samples were investigated using GC and C-GC-MS. The sediments evaluated included the basal lignite, a vitrinite lens from the overlying claystone, and four intervals from the massive oil shale bed. As expected, the lignite and vitrinite differ markedly from the oil shales. The lignite is dominated by bacterial hopanoids and components of higher plant origin, including C29 steroids and triterpenoids such as oleanenes. Visually, the oil shale samples show corroded and degraded phytoclasts, spores, wispy particles of fluorescent organic material attributable to dinoflagellates and, especially in the uppermost sample, colonial algal bodies. The distributions of biological markers in the oil shales show many features in common, notably a dominance of dinoflagellate-derived 4-methylsteroids, and a significant proportion of higher-plant derived n-alkanes with marked odd-over-even carbon number predominance. Overall, they exhibit several features that resemble characteristics of the Messel shale. The hydrocarbons of the lowest shale horizon suggest that there may have been a gradual transition between deposition of the original peat and the subsequent oil shales. The aliphatic hydrocarbons of the uppermost shale are dominated by a number of C31 and C33 botryococcane homologues and other unusual branched alkanes possibly derived from green algae. All of the samples are immature. Overall, molecular and microscopic examination of the stratigraphic succession of the Maoming oil shale suggests a shallow, lacustrine environment within which peats were deposited. This lake subsequently deepened to support abundant algal populations, especially dinoflagellates, culminating in a dominance of botryococcoid algae. 相似文献
108.
北部湾盆地不同凹陷原油生物标志物分布与组成特征 总被引:7,自引:1,他引:7
通过对取自北部湾盆地不同凹陷典型原油样品中各类生物标志物的分布与组成特征的系统分析,发现盆地北部的涠西南凹陷和乌石凹陷所产原油具有姥植比低和奥利烷与各类重排构型生物标志物含量低,而C26+长链三环萜烷系列和C304 甲基甾烷含量高的特点,且其三环萜烷系列呈现以C23为主峰的正态分布,指示了该类原油的烃源岩沉积时水体较深,还原性相对较强,且原始生烃母质以藻类为主;而南部福山凹陷和迈陈凹陷所产的原油则具有姥植比高和奥利烷与各类重排构型生物标志物含量高的特征,而C26+长链三环萜烷系列和C304 甲基甾烷含量低,且其三环萜烷系列呈现C19—C26阶梯状依次降低,表明这类原油的烃源岩沉积时水体较浅,还原性相对较弱,且原始生烃母质中被子植物来源的陆源有机质贡献较大。由此表明北部湾盆地南北不同凹陷第三纪的沉积特征和有机质生源构成存在显著差异。 相似文献
109.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Physics and Chemistry of Minerals》2007,34(2):121-127
A multi-anvil device was used to synthesize 24 mg of pure γ-Fe2SiO4 crystals at 8.5 GPa and 1,273 K. The low-temperature heat capacity (C
p) of γ-Fe2SiO4 was measured between 5 and 303 K using the heat capacity option of a physical properties measurement system. The measured
heat capacity data show a broad λ-transition at 11.8 K. The difference in the C
p between fayalite and γ-Fe2SiO4 is reduced as the temperature increases in the range of 50–300 K. The gap in C
p data between 300 and 350 K of γ-Fe2SiO4 is an impediment to calculation of a precise C
p equation above 298 K that can be used for phase equilibrium calculations at high temperatures and high pressures. The C
p and entropy of γ-Fe2SiO4 at standard temperature and pressure (S°298) are 131.1 ± 0.6 and 140.2 ± 0.4 J mol−1 K−1, respectively. The Gibbs free energy at standard pressure and temperature (ΔG°
f,298) is calculated to be −1,369.3 ± 2.7 J mol−1 based on the new entropy data. The phase boundary for the fayalite–γ-Fe2SiO4 transition at 298 K based on current thermodynamic data is located at 2.4 ± 0.6 GPa with a slope of 25.4 bars/K, consistent
with extrapolated results of previous experimental studies. 相似文献
110.
通过对青藏高原崇测冰帽一支18.70m冰芯中Cl^-、SO4^2-离子含量变化的分析表明,20世纪90年来Cl^-、SO4^2-离子含量在波动中呈下降趋势,两种离子的周期性波动变化相似,20世纪晚期比早期和中期的波动幅度小,总体上离子含量逐渐减少与温度在波动中上升相一致,但每一次温度的升高与离子含量的下降并非一一对应。陆源物质和青藏高原上的盐湖是冰芯中Cl^-、SO4^2-离子的主要贡献者。揭示了研究地区大气成分和环境变化与气候变化的关系及亚洲粉尘在全球环境变化中的源区地位。 相似文献