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81.
The UV spectra of mixture solutions consisting of tyrosine,tryptophane,phenylalanine,cystine,histidineand 3,4-dihydroxyl phenylalanine have been measured.The numbers,identities and concentrations of theamino acids in the mixtures have been determined successfully using target factor analysis.The effectsof the wavelength range and the selected sampling interval on the results are discussed.Twenty-fivesynthetic mixture samples have been analysed successfully.The average recoveries are 98·9 for Tyr,96·5for Trp,105·6 for Phe,98·1 for Cys,98·9 for His and 106·4 for Di-phe.The results obtained are ingood agreement with those obtained by the Kalman filter method. 相似文献
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Yanjun ZHANG Fenglong ZHANG Full QI Fuquan NI 《东北亚地学研究》2006,9(2):199-203
In view of the situation of excavation of open coal mine for the underground water disaster,we should carry out simulation studies for the numerical value of the water lowering project and improve the accuracy and the level of the water lowering project.On the basis of the hydrological geological conditions of certain open mine digging,a more reasonable seepage numerical model was built according to MODFLOW.It was simulated in advance that the process of the confined water level descending with the time,and combining with the actual observations to test the correctness of the model.The calculation showed that the results coincided well with the results of actual measurement.Based on this,different water lowering numerical simulations were built for the open coal mine digging.It could be simulated and forecast that the changes of the groundwater level in drainage process within and outside the mine pit,and it was quantitatively assessed that the possible water lowering result of the opencast water drainage process,which provide an important basis for the actual water lowering project and the possible project disposal. 相似文献
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Jacques Laskar 《Celestial Mechanics and Dynamical Astronomy》1993,56(1-2):191-196
Frequency analysis is a new method for analyzing the stability of orbits in a conservative dynamical system. It was first devised in order to study the stability of the solar system (Laskar, Icarus, 88, 1990). It is a powerful method for analyzing weakly chaotic motion in hamiltonian systems or symplectic maps. For regular motions, it yields an analytical representation of the solutions. In cases of 2 degrees of freedom system with monotonous torsion, precise numerical criterions for the destruction of KAM tori can be found. For a 4D symplectic map, plotting the frequency map in the frequency plane provides a clear representation of the global dynamics and describes the actual Arnold web of the system. 相似文献
88.
Large scale geomechanical simulations are being increasingly used to model the compaction of stress dependent reservoirs, predict the long term integrity of under‐ground radioactive waste disposals, and analyse the viability of hot‐dry rock geothermal sites. These large scale simulations require the definition of homogenous mechanical properties for each geomechanical cell whereas the rock properties are expected to vary at a smaller scale. Therefore, this paper proposes a new methodology that makes possible to define the equivalent mechanical properties of the geomechanical cells using the fine scale information given in the geological model. This methodology is implemented on a synthetic reservoir case and two upscaling procedures providing the effective elastic properties of the Hooke's law are tested. The first upscaling procedure is an analytical method for perfectly stratified rock mass, whereas the second procedure computes lower and upper bounds of the equivalent properties with no assumption on the small scale heterogeneity distribution. Both procedures are applied to one geomechanical cell extracted from the reservoir structure. The results show that the analytical and numerical upscaling procedures provide accurate estimations of the effective parameters. Furthermore, a large scale simulation using the homogenized properties of each geomechanical cell calculated with the analytical method demonstrates that the overall behaviour of the reservoir structure is well reproduced for two different loading cases. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
89.
This paper presents a numerical model for predicting the dynamic response of rock mass subjected to large‐scale underground explosion. The model is calibrated against data obtained from large‐scale field tests. The Hugoniot equation of state for rock mass is adopted to calculate the pressure as a function of mass density. A piecewise linear Drucker–Prager strength criterion including the strain rate effect is employed to model the rock mass behaviour subjected to blast loading. A double scalar damage model accounting for both the compression and tension damage is introduced to simulate the damage zone around the charge chamber caused by blast loading. The model is incorporated into Autodyn3D through its user subroutines. The numerical model is then used to predict the dynamic response of rock mass, in terms of the peak particle velocity (PPV) and peak particle acceleration (PPA) attenuation laws, the damage zone, the particle velocity time histories and their frequency contents for large‐scale underground explosion tests. The computed results are found in good agreement with the field measured data; hence, the proposed model is proven to be adequate for simulating the dynamic response of rock mass subjected to large‐scale underground explosion. Extended numerical analyses indicate that, apart from the charge loading density, the stress wave intensity is also affected, but to a lesser extent, by the charge weight and the charge chamber geometry for large‐scale underground explosions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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