Petrogenesis and implications of jadeite‐bearing kyanite eclogite from the Sanbagawa belt (SW Japan)     

S. Endo  M. Tsuboi 《Journal of Metamorphic Geology》2013,31(6):647-661

Jadeite‐bearing kyanite eclogite has been discovered in the Iratsu body of the Sanbagawa belt, SW Japan. The jadeite + kyanite assemblage is stable at higher pressure–temperature (P–T) conditions or lower H₂O activity [a(H₂O)] than paragonite, although paragonite‐bearing eclogite is common in the Sanbagawa belt. The newly discovered eclogite is a massive metagabbro with the peak‐P assemblage garnet + omphacite + jadeite + kyanite + phengite + quartz + rutile. Impure jadeite is exclusively present as inclusions in garnet. The compositional gap between the coexisting omphacite (P2/n) and impure jadeite (C2/c) suggests relatively low metamorphic temperatures of 510–620 °C. Multi‐equilibrium thermobarometry for the assemblage garnet + omphacite + kyanite + phengite + quartz gives peak‐P conditions of ~2.5 GPa, 570 °C. Crystallization of jadeite in the metagabbro is attributed to Na‐ and Al‐rich effective bulk composition due to the persistence of relict Ca‐rich clinopyroxene at the peak‐P stage. By subtracting relict clinopyroxene from the whole‐rock composition, pseudosection modelling satisfactorily reproduces the observed jadeite‐bearing assemblage and mineral compositions at ~2.4–2.5 GPa, 570–610 °C and a(H₂O) >0.6. The relatively high pressure conditions derived from the jadeite‐bearing kyanite eclogite are further supported by high residual pressures of quartz inclusions in garnet. The maximum depth of exhumation in the Sanbagawa belt (~80 km) suggests decoupling of the slab–mantle wedge interface at this depth.  相似文献   

Sapphirine in SW Sweden: a record of Sveconorwegian (–Grenvillian) late-orogenic tectonic exhumation     

MÖller 《Journal of Metamorphic Geology》1999,17(1):127-141

In the Sveconorwegian granulite region of SW Sweden, sapphirine occurs in reaction coronas in Mg- and Al-rich kyanite eclogites which form parts of mafic complexes. Aluminous to peraluminous sapphirine forms symplectitic intergrowths with plagioclase±corundum±spinel after kyanite. Kyanite and omphacite were the main reactants in the formation of sapphirine. The sapphirine formed during decompression from the eclogite facies ( P >15  kbar) through the high- to medium-pressure granulite and upper amphibolite facies at c. 750  °C. Preserved growth zoning in garnet, frozen-in reaction textures, and chemical disequilibrium suggest a rapid tectonic exhumation. Ductile deformation in the surrounding gneisses and parts of the mafic complex is characterized by foliation development, WNW–ESE stretching and dynamic recrystallization under granulite to upper amphibolite facies conditions, simultaneous with the sapphirine formation. This decompression, high-grade re-equilibration and associated deformation took place during the exhumation of the Sveconorwegian eclogites, bracketed between 969±14 and 956±7  Ma. Probable tectonic causes are late-orogenic gravitational collapse and/or plate divergence following the Sveconorwegian–Grenvillian continent–continent collision. There are no indications of metastability of aluminous and peraluminous sapphirine in the decompressed kyanite eclogites; sapphirine is stable in amphibole-poor and amphibolitized varieties, including rocks that have undergone dynamic recrystallization. Close similarities between rocks from different parts of the world with respect to reaction textures suggests that sapphirine+plagioclase-forming reactions are a universal feature in high-temperature decompressed kyanite eclogites.  相似文献   

Petrological constraints on the formation conditions and retrograde P–T path of the Kotsu eclogite unit, central Shikoku     

M. Matsumoto  S. Wallis  M. Aoya  M. Enami  J. Kawano  Y. Seto  N. Shimobayashi 《Journal of Metamorphic Geology》2003,21(4):363-376

A largely undocumented region of eclogite associated with a thick blueschist unit occurs in the Kotsu area of the Sanbagawa belt. The composition of coexisting garnet and omphacite suggests that the Kotsu eclogite formed at peak temperatures of around 600 °C synchronous with a penetrative deformation (D1). There are local significant differences in oxygen fugacity of the eclogite reflected in mineral chemistries. The peak pressure is constrained to lie between 14 and 25 kbar by microstructural evidence for the stability of paragonite throughout the history recorded by the eclogite, and the composition of omphacite in associated eclogite facies pelitic schist. Application of garnet‐phengite‐omphacite geobarometry gives metamorphic pressures around 20 kbar. Retrograde metamorphism associated with penetrative deformation (D2) is in the greenschist facies. The composition of syn‐D2 amphibole in hematite‐bearing basic schist and the nature of the calcium carbonate phase suggest that the retrograde P–T path was not associated with a significant increase or decrease in the ratio of P–T conditions following the peak of metamorphism. This P–T path contrasts with the open clockwise path derived from eclogite of the Besshi area. The development of distinct P–T paths in different parts of the Sanbagawa belt shows the shape of the P–T path is not primarily controlled by tectonic setting, but by internal factors such as geometry of metamorphic units and exhumation rates.  相似文献   

Rutile to Titanite Transformation in Eclogites and its Geochemical Consequences: An Example from the Sumdo Eclogite, Tibet     

ZHAO Linghao  ZENG Lingsen  GAO Li’e  HU Mingyue  SUN Dongyang  ZHANG Lifei 《《地质学报》英文版》2023,97(1):122-133

The formation of titanite coronae after rutile is common in retrograde high-to ultrahigh-pressure meta-mafic rocks, which provides a good opportunity to address the geochemical behavior of HFSE in crustal environments. In the Sumdo eclogite, titanite occurs either as a corona around rutile grains or as semi-continuous veins cross-cutting the major foliation, whereas rutile grains occur either as inclusions in garnet or omphacite or as a relict core surrounded by titanite. Textural relationships ...  相似文献   

Abiotic Methane Reservoirs in the Western Tianshan HP–UHP Metamorphic Belt,China     

ZHANG Lijuan  ZHANG Lifei  LI Xiaowei  WANG Xiao 《《地质学报》英文版》2023,97(1):337-349

Natural gas, consisting primarily of methane(CH₄), has become a major source of clean energy in modern society in many parts of the globe. Recent experimental observations and discoveries of deep-sourced abiotic CH₄ in cold subduction zones indicate the important ability of cold subducted slabs to generate natural gas reservoirs. However, most CH₄ flux and reservoirs remain unknown and their potential is overlooked in global carbon flux estimations. Massive abiot...  相似文献   

Was the Panzhihua Large Fe-Ti Oxide Deposit,SW China,Formed by Silicate Immiscibility?     

DING Xiangli  CHEN Xuanhu  SHAO Zhaogang 《《地质学报》英文版》2023,97(5):1451-1461

The Panzhihua mafic intrusion, which hosts a world-class Fe-Ti-V ore deposit, is in the western Emeishan region, SW China. The formation age(～260 Ma), and Sr and Nd isotopes indicate that the Panzhihua intrusion is part of the Emeishan large igneous province and has little crustal contamination. To assess ore genesis of the Panzhihua Fe-Ti-V ore deposit, two different models have been provided to explain the formation, namely silicate immiscibility and normal fractional crystallization. Silicate...  相似文献   

Does continental crust transform during eclogite facies metamorphism?   总被引：1，自引：0，他引：1       下载免费PDF全文

D. J. Young  A. R. C. Kylander‐Clark 《Journal of Metamorphic Geology》2015,33(4):331-357

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.  相似文献   

拉萨地块松多榴辉岩的变质演化过程:NCKMnFMASHTO体系中的相平衡关系   总被引：2，自引：0，他引：2       下载免费PDF全文

黄杰  田作林张 聪杨经绥陈 梅 《中国地质》2015,(5):1559-1571

拉萨地块松多榴辉岩主要矿物组合为石榴子石、绿辉石、角闪石、多硅白云母、绿帘石、金红石。石榴子石环带不明显,核部成分均一,从核部到边部,镁铝榴石和钙铝榴石含量降低,可能分别记录了榴辉岩峰期及退变质过程信息。绿辉石显示微弱的成分环带,硬玉含量从核部到边部略有升高,部分绿辉石边部发育韭闪石退变质边,反映了在减压过程中外来流体进入体系的过程。多硅白云母具有高的Si含量(3.5~3.6),其中石榴石包体中的多硅白云母相对基质中的白云母有更高的Si值。本文利用Thermocalc变质相平衡模拟软件,结合详细岩相学观察,在NCKMn FMASHTO体系下,模拟松多含多硅白云母榴辉岩的变质演化过程。其中,榴辉岩峰期矿物组合为g+o+law+phn+ru,石榴石核部最大镁铝榴石值和石榴子石包体中多硅白云母最大Si值确定的榴辉岩峰期温压条件约为620℃,32×105Pa,榴辉岩经历了近等温降压的退变质过程。相平衡模拟结果表明拉萨地块松多榴辉岩经历了超高压变质作用过程,并经历了相对快速的折返过程到中部地壳层次。  相似文献   

Constraining the P–T path of a MORB-type eclogite using pseudosections, garnet zoning and garnet-clinopyroxene thermometry: an example from the Bohemian Massif     

P. &#;TÍPSKÁ  R. POWELL 《Journal of Metamorphic Geology》2005,23(8):725-743

A mid‐ocean ridge basalt (MORB)‐type eclogite from the Moldanubian domain in the Bohemian Massif retains evidence of its prograde path in the form of inclusions of hornblende, plagioclase, clinopyroxene, titanite, ilmenite and rutile preserved in zoned garnet. Prograde zoning involves a flat grossular core followed by a grossular spike and decrease at the rim, whereas Fe/(Fe + Mg) is also flat in the core and then decreases at the rim. In a pseudosection for H₂O‐saturated conditions, garnet with such a zoning grows along an isothermal burial path at c. 750 °C from 10 kbar in the assemblage plagioclase‐hornblende‐diopsidic clinopyroxene‐quartz, then in hornblende‐diopsidic clinopyroxene‐quartz, and ends its growth at 17–18 kbar. From this point, there is no pseudosection‐based information on further increase in pressure or temperature. Then, with garnet‐clinopyroxene thermometry, the focus is on the dependence on, and the uncertainties stemming from the unknown Fe³⁺ content in clinopyroxene. Assuming no Fe³⁺ in the clinopyroxene gives a serious and unwarranted upward bias to calculated temperatures. A Fe³⁺‐contributed uncertainty of ±40 °C combined with a calibration and other uncertainties gives a peak temperature of 760 ± 90 °C at 18 kbar, consistent with no further heating following burial to eclogite facies conditions. Further pseudosection modelling suggests that decompression to c. 12 kbar occurred essentially isothermally from the metamorphic peak under H₂O‐undersaturated conditions (c. 1.3 mol.% H₂O) that allowed the preservation of the majority of garnet with symplectitic as well as relict clinopyroxene. The modelling also shows that a MORB‐type eclogite decompressed to c. 8 kbar ends as an amphibolite if it is H₂O saturated, but if it is H₂O‐undersaturated it contains assemblages with orthopyroxene. Increasing H₂O undersaturation causes an earlier transition to SiO₂ undersaturation on decompression, leading to the appearance of spinel‐bearing assemblages. Granulite facies‐looking overprints of eclogites may develop at amphibolite facies conditions.  相似文献   

北秦岭官坡地区柯石英榴辉岩变质作用的P－T－t轨迹     

Zhao Donglin 《地球科学与环境学报》1997,(2)

根据矿物包裹和替代关系以及共生组合规律，北秦岭官坡地区柯石英榴辉岩的变质作用演化可划分为５个阶段，即前榴辉岩相的绿帘角闪岩相、榴辉岩相、后榴辉岩相的角闪岩相、绿帘角闪岩相和绿片岩相。Ｓｍ－Ｎｄ同位素定年显示，北秦岭柯石英榴辉岩于４００±１６Ｍａ沿朱夏断裂被推覆上升，Ｐ－Ｔ－ｔ轨迹的地球动力学成因可能与扬子和华北陆块间的俯冲－碰撞作用有关。  相似文献