闪锌矿铷-锶同位素等时线讨论   总被引：3，自引：0，他引：3  

杨向荣  彭建堂  胡瑞忠 《地质论评》2009,55(3)

通过对闪锌矿铷-锶同位素等时线形成机制的讨论,若为同源、同期、待测同位素封闭的体系,因混合形成的直线为等时线具有定年意义,但若非同源、非同期或非封闭的体系亦可因混合形成直线,但该直线为无年代学意义的混合线.作为铷-锶同位素定年矿物,闪锌矿可能仪充当"容器"的角色,因此利用闪锌矿进行定年时,必须进行细致的物相研究.闪锌矿中的碳酸盐、硅酸盐等矿物微粒可能对铷-锶定年产生极大的影响,如不能对其进行成因鉴别或配合其他同化素定年方法加以系统研究,闪锌矿铷-锶法直线拟合结果很难反映成矿时间.  相似文献   

内蒙古东北部得耳布尔铅锌银矿床闪锌矿Rb-Sr年龄及地质意义     

赵岩  吕骏超  张德宝  周永恒  邵军  王冰 《矿床地质》2017,36(4):893-904

得耳布尔铅锌银矿床产出于内蒙古东北部额尔古纳地块中部,得尔布干断裂西北侧。矿石呈角砾状、团块状产出,尤以闪锌矿粗大集合体与方铅矿伴生为特征。本次研究在对矿石开展矿相学研究基础上,选取成矿早阶段未遭受构造活动影响的8件闪锌矿样品进行Rb-Sr同位素分析,结果显示,8件样品~(87)Rb/~(86)Sr和~(87)Sr/~(86)Sr同位素比值分别在0.0824~8.957和0.712 902~0.730 753之间,二者之间具线性关系,8件样品构成等时线年龄为(144±13)Ma,剔除2件偏离等时线较远样品数据后,获得等时线年龄为(141.6±1.9)Ma(MSWD=1.8)。矿床形成于早白垩世,与额尔古纳地块内其他铅锌银矿床时代基本一致。额尔古纳地块中生代成矿作用直接受控于蒙古-鄂霍茨克造山过程,造山带后碰撞阶段局部拉伸环境引发晚侏罗世—早白垩世浅成岩浆侵入活动,得耳布尔铅锌银矿床的形成与之相关。  相似文献   

Chalcopyrite Intergrowths in sphalerite in the Meixian Lead—Zine Deposit,Fujian Province and their Metallogenic Significance   总被引：2，自引：0，他引：2  

顾连兴  周兵等 《中国地球化学学报》1998,17(4):311-319

Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains,intergrown chalcopyrite also occurs as rods,myrmekites and lamellae aligned along cleavages and twin boundaries of the host sphalerite.The majority of the intergrowths could have been formed by replacement of sphalerite by chalcopyrite,albeit part of them may have resulted from exsolution,Not only copper,but also iron were introduced into the sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody,Zn and Pb were dissolved and Cu was precipitated,resulting in zonal refining of the sulphide ores,The remobilized zinc and lead were precipitated at favourable sites with changed physico-chemical conditions .This is a possible mechanism for the formation of copper-poor zinc and lead ores above or lateral to the copper orebodies in some of the massive sulphide deposits reworked and overprinted by late-stage granites and their hydrothermal fluids.  相似文献   

Relationship between chemical composition and magnetic susceptibility in sediment cores from Central Indian Ocean Basin     

J. N. Pattan  G. Parthiban  V. K. Banakar  A. Tomer  M. Kulkarni 《Journal of Earth System Science》2008,117(2):113-119

Three sediment cores in a north-south transect (3°N to 13°S) from different sediment types of the Central Indian Ocean Basin (CIOB) are studied to understand the possible relationship between magnetic susceptibility (χ) and Al, Fe, Ti and Mn concentrations. The calcareous ooze core exhibit lowest χ (12.32 × 10⁻⁷ m³ kg⁻¹), Al (2.84%), Fe (1.63%) and Ti (0.14%), terrigenous clay core with moderate χ (29.93 × 10⁻⁷ m³ kg⁻¹) but highest Al (6.84%), Fe (5.20%) and Ti (0.44%), and siliceous ooze core with highest χ (38.06 × 10⁻⁷ m³ kg⁻¹) but moderate Al (4.49%), Fe (2.80%) and Ti (0.19%) contents. The distribution of χ and detrital proxy elements (Al, Fe, and Ti) are identical in both calcareous and siliceous ooze. Interestingly, in terrigenous core, the behaviour of χ is identical to only Ti content but not with Al and Fe suggesting possibility of Al and Fe having a non-detrital source. The occurrence of phillipsite in terrigenous clay is evident by the Al-K scatter plot where trend line intersects K axis at more than 50% of total K suggesting excess K in the form of phillipsite. Therefore, the presence of phillipsite might be responsible for negative correlation between χ and Al (r = −0.52). In siliceous ooze the strong positive correlations among χ, Al_exc and Fe_exc suggest the presence of authigenic Fe-rich smectite. High Mn content (0.5%) probably in the form of manganese micronodules is also contributing to χ in both calcareous and siliceous ooze but not in the terrigenous core where mean Mn content (0.1%) is similar to crustal abundance. Thus, χ systematically records the terrigenous variation in both the biogenic sediments but in terrigenous clay it indirectly suggests the presence of authigenic minerals.  相似文献   

云南会泽铅锌矿床闪锌矿化学成分特征及其指示意义     

张茂富  周宗桂  熊索菲  宫勇军  陈国林  李行 《岩石矿物学杂志》2016,35(1):111-123

在详细的野外调研及岩相学研究基础上,通过电子探针分析(EMPA)和电感耦合等离子体质谱分析(ICPMS),系统研究云南会泽铅锌矿不同成矿阶段闪锌矿化学成分特征,探讨Zn、Fe、Cd、Ge、In、Ag的富集规律及其指示意义。研究表明,该矿床的热液成矿作用可划分为4个阶段,依次为细粒黄铁矿阶段、多金属硫化物阶段、黄铁矿-方铅矿阶段和碳酸盐阶段,其中闪锌矿的形成可划分为两个阶段,从早到晚颜色由黑色变为红色。早阶段闪锌矿富Fe,贫Ge、In、Ag、Zn和Cd;晚阶段闪锌矿富Ge、In、Ag、Zn和Cd,相对贫Fe。闪锌矿中Cd、Ge等有用组分均已达到工业综合利用要求,主要替代Fe进入闪锌矿晶格。闪锌矿中Fe S含量从早到晚呈降低趋势,估算早期成矿温度为170~262℃,晚期成矿温度低于203℃,结合Zn/Cd含量比值变化范围,认为该矿床属于中温热液矿床,其成矿温度由早至晚逐渐降低。空间上,Zn、Fe含量及Zn/Cd值均指示矿床形成时热液由深部向浅部流动。将该矿床闪锌矿中In、Cd、Ga、Ge、Zn/Cd、Ga/In、Ge/In等特征元素及其比值与典型铅锌矿进行对比,显示会泽铅锌矿与MVT型铅锌矿床类似。  相似文献   

闪锌矿铷 锶同位素等时线讨论     

杨向荣  彭建堂  胡瑞忠 《地质论评》2009,55(3):370-374

通过对闪锌矿铷锶同位素等时线形成机制的讨论,若为同源、同期、待测同位素封闭的体系,因混合形成的直线为等时线具有定年意义,但若非同源、非同期或非封闭的体系亦可因混合形成直线,但该直线为无年代学意义的混合线。作为铷锶同位素定年矿物,闪锌矿可能仅充当“容器”的角色,因此利用闪锌矿进行定年时,必须进行细致的物相研究。闪锌矿中的碳酸盐、硅酸盐等矿物微粒可能对铷锶定年产生极大的影响,如不能对其进行成因鉴别或配合其他同位素定年方法加以系统研究,闪锌矿铷锶法直线拟合结果很难反映成矿时间。  相似文献   

闪锌矿LA-ICP-MS微量元素组成对西藏纳如松多铅锌矿床成矿作用的制约     

龚雪婧  杨竹森  庄亮亮  马旺 《矿床地质》2019,38(6):1365-1378

西藏纳如松多铅锌矿床是冈底斯北侧Pb-Zn-Ag-Mo成矿带中规模最大且最为典型的与斑岩系统相关的铅锌矿床,发育有多种矿化样式。本次研究选取该矿床隐爆角砾岩型矿体中的闪锌矿开展LA-ICP-MS微量元素组成研究,发现其中Fe含量不高,不属于高温铁闪锌矿,以富集Cd、Mn、Co,而贫In、Ga、Ge、Se、Te为特征。闪锌矿In/Ga值、In/Ge值及Zn/Cd值指示纳如松多隐爆角砾岩型铅锌矿体形成于中低温环境,且属于热液型矿床的范畴。闪锌矿原位微量元素特征指示纳如松多铅锌矿床的形成主要受到来自于岩浆热液作用的影响和控制,成矿物质主要来自于深部斑岩岩浆系统。  相似文献   

湖南几个大型银矿床银的分配和矿物学特征     

李正勤 《矿物学报》1991,11(2):148-154

湖南几个大型银矿床的特征是:银在矿石中主要以银的硫化矿及其类似化合物形式存在;银矿物的主要载体是方铅矿、闪锌矿和硫铁矿;银矿物主要是Cu、Sb、As的银黝铜矿系复硫盐类,粒度极细微。  相似文献   

Sphalerite geobarometry in metamorphic terranes: an appraisal with implications for metamorphic pressure in the Otago Schist     

R. A. JAMIESON  DAVID CRAW 《Journal of Metamorphic Geology》1987,5(1):87-99

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Short-range order of Fe2+ in sphalerite by 57Fe Mössbauer spectroscopy and magnetic susceptibility     

F. Di Benedetto  G. B. Andreozzi  G. P. Bernardini  M. Borgheresi  A. Caneschi  C. Cipriani  D. Gatteschi  M. Romanelli 《Physics and Chemistry of Minerals》2005,32(5-6):339-348

An extensive study of natural and synthetic Fe-bearing sphalerites (Fe-content ranging from 0.005 afu to 0.250 afu) has been carried out through the combined investigations of the temperature dependence of the magnetic susceptibility and of the ⁵⁷Fe Mössbauer spectroscopic features. Magnetic susceptibility measurements evidence, in the low temperature regime, the presence of clustered Fe even in the most diluted samples, whereas all the Mössbauer spectra are described in terms of variable proportions of three components, namely one single and two doublets absorption, centred at the same isomer shift, relative to Fe ions and to different Fe clusters, respectively. The comparison of all the experimental results points out a self-affinity of Fe ions in sphalerite favoured by the superexchange interaction, which stabilises the formation of clusters even in diluted samples and may be related to both macroscopic inhomogeneous distribution and crystal zoning.  相似文献