不同成矿阶段流体包裹体气相成分的四极质谱测定   总被引：14，自引：10，他引：14  

朱和平王莉娟  刘建明 《岩石学报》2003,19(2):314-318

四极质谱法测定的爆裂温度曲线，可区分出不同成矿阶段群体包裹体温度区间，并分别测定其气相组成。代表不同成矿阶段的包裹体气相组成有明显差异。本研究表明用四极质谱法测定同一样品中不同成矿阶段的包裹体气相组分是可行的，拓宽了成矿流体研究的思路，为研究多期次成矿流体的来源、演化和解译矿床成因提供了新的方法、手段。  相似文献   

Pollution history of the savannah river estuary and comparisons with Baltic Sea pollution history     

C. Alexander  R. Smith  B. Loganathan  J. Ertel  H.L. Windom  R.F. Lee   《Limnologica》1999,29(3):267

The sediment record, as revealed in sediment cores, can be used to reconstruct the history of contaminant input into estuaries. The basic assumptions are that contaminant inputs equilibrate relatively rapidly with sediment inputs and that the sediment column represents a continuous sequence of sediment and associated contaminant accumulation. With radiochemical chronologies, it is possible to date sediments over a period corresponding to about five half-lives (100 years for ²¹⁰Pb). In our study we reconstruct the pollution history of the Savannah Estuary, which is a typical estuary in the South Atlantic Bight. A series of cores were taken in the estuary, followed by the analysis of the cores for a variety of organic and inorganic contaminants. Ages were assigned to different depth intervals by the use of two radiotracers, ²¹⁰Pb and ¹³⁷Cs. The major pesticides found were an isomer of DDT and dieldrin. The peak in their concentrations (1967) correlated with peak use of these pesticides before their use was banned. Between 1959 and 1962, there was more input of anthropogenic PAHs than before and after this period. The metals which showed significant changes in the cores include mercury, lead and chromium. Chromium reached a maximum during the late 1950s, followed by a decrease in the late 1960s. This chromium peak coincided with the initial operation of a titanium dioxide pigment plant in the Savannah Estuary. An interesting aspect of the study, which has been noted by many pollution history studies, was the decrease in the concentration of anthropogenic chemicals during the past two decades, suggesting that pollution controls have been effective, even while industrial and population growth was taking place.Similar studies have been carried out to reconstruct the historical record of contamination in the Baltic Sea. Concentrations of metals were found to increase after 1880 (industrial revolution in northern Europe). PCBs peaked in concentration in the late 1960s and the early 1970s, while DDT peaked in the 1960s. The Baltic experienced a major input of nutrients (N and P) after 1965 resulting from heavy use of fertilizers in this region.  相似文献   

Contaminated ground and contaminated estuary sediment illustrated by two case histories   总被引：1，自引：0，他引：1  

F. G. Bell  P. Lindsay  N. Hytiris 《Environmental Geology》1997,32(3):191-202

 Contaminated ground forms a problem in all of the industrialized countries of the world. Contaminated ground may give rise to hazards and that implies a degree of risk which also involves a problem of definition. The investigation of a site which is suspected of being contaminated differs somewhat from a routine site investigation. Sampling of soil, groundwater and gas-producing material may be required. Various precautions may be necessary to do this and personnel may have to wear protective clothing. The first case history considered involves a site investigation for a relief sewer in Glasgow. As the site investigation progressed it ran into made-ground which contained chemical waste. The presence of this waste meant that the nature of the investigation changed and much more stringent safety precautions had to be taken. It also meant that the initial location of the sewer tunnel had to be repositioned at greater depth in uncontaminated sandstone rather than in the superficial deposits above. The other case history considers the contamination of sediments in the Forth Estuary. When trace metals are released into the water column they can be transferred rapidly to the sediment phase by adsorption onto suspended particulate matter, followed by sedimentation. Intertidal flats may be considered as important trace metal sinks since they accumulate large amounts of suspended matter. Hence, in polluted estuaries the deposition of suspended particles on intertidal flats may thus cause severe contamination. The Forth Estuary has unique contamination for British estuaries; it is experiencing significant Hg pollution. In addition, due to the presence of a nuclear submarine base in the Forth Estuary, ⁶⁰Co is detectable in the intertidal sediments. Temporal and spatial contamination patterns were analysed in relation to historical and present pollution point sources. The effect of fluvial and marine sediment mixing on trace metals and other processes controlling contaminant levels is reviewed. Preliminary results on quantifying sediment accretion rates using Caesium levels are discussed. Received: 9 August 1996 · Accepted: 17 December 1996  相似文献   

Nutrient,heavy metal and organic pollutant composition of suspended and bed sediments in the Rhone River     

S. Santiago  R. L. Thomas  G. Larbaigt  C. Corvi  D. Rossel  J. Tarradellas  D. J. Gregor  L. McCarthy  J. P. Vernet 《Aquatic Sciences - Research Across Boundaries》1994,56(3):220-242

The environmental quality of the Rhone River (Switzerland-France) has been assessed with a geochemical survey of the pollutants bound to suspended sediments. Ten samples were collected between Lake Geneva and the Mediterranean Sea in Nobember 1989 by continuous flow centrifugation and analysed for grain size distribution, carbonate, organic C, N, forms of particulate P, trace metals, and organic compounds (chlorobenzenes, organochlorine pesticides, PCBs, and PAHs). Four bed sediment samples were also studied for comparative purposes. The suspended solids provide lower variance by parameter than the bed sediments and are clearly most suitable for synoptic monitoring.The Upper Rhone River carries a glacial derived sediment with a low nutrient content, the stretch from Geneva to Lyon provides a sediment dominated by carbonate, and in the Lower Rhone the organic matter and phosphorus are relatively increased, mainly due to wastewater effluents and to an industrial P source. High concentrations of metals and organic micropollutants downstream of Lyon indicate a multiple contamination in the Lower Rhone, whereas more specific inputs are located downstream of Geneva and Arles.The comparison with data from other polluted major systems, the Rhine, the Niagara and the Detroit rivers, shows on overall similarity confirming that the Rhone quality is degraded downstream of Lyon. The levels of particular concern are for Hg, DDT metabolites which reveal a recent release in the basin, PCBs with a likely high chlorine content, and PAHs.The statistical evaluation of the compositional variables indicates a limited number of well defined associations, suggesting that the contamination of the suspended sediments results from the combination of numerous and intermittent point and diffuse sources in the Rhone River basin.  相似文献   

钨的气态迁移与岩浆-热液成矿作用:实验研究及其成矿学意义   总被引：1，自引：0，他引：1       下载免费PDF全文

张生  陈根文 《地质科学》2015,(3):898-910

低密度的水热蒸气和超临界似气流体广泛存在于中地壳至地球表面的各种地质环境中, 是成矿金属搬运和富集的重要介质。火山喷气凝结水、火山结壳和升华物、矿床的流体包裹体气相中均存在具有地质意义的W含量或含钨矿物, 表明W同样可在含水气相中溶解和迁移。本文在350 ℃~400 ℃和压力为60~200 bar的实验条件下, 测定了WO₃-H₂O体系中W在水蒸气和似气流体中的溶解度, 考察了水蒸气压力对W溶解度的影响。结果显示, W在水蒸气中的逸度(或含量)远高于依据无水体系中固体WO₃挥发性数据计算的蒸气压力, 证明气态溶质W与溶剂水蒸气之间存在促进W溶解的水合作用。经热力学方法分析, 认为可能形成了WO₃·nH₂O(g)形式的水合气体物种, 其水合数n在350 ℃、370 ℃和400 ℃时分别为1.4、1.6和2.9。因此WO₃·3H₂O(g)或H₂WO₄·2H₂O(g)及H₆WO₆(g)在温压较高的岩浆-热液或气成-热液成矿环境中(如斑岩系统)对W的气态迁移和浓集可能具有重要作用, 而在温压较低的水热蒸气条件下, W的迁移形式可能以水合数较小的WO₃·H₂O(g)(或H₂WO₄)和WO₃·2H₂O(g)(或H₂WO₄·H₂O)物种为主, 其含量或比例随水蒸气的压力而改变。某些斑岩型和脉型钨(钼)矿床常存在富气体包裹体, 伴随酸性岩浆结晶出溶的以低盐度含水蒸气占优势的岩浆流体对斑岩系统中W、Mo在高温阶段的气态迁移和矿质在花岗岩体顶部和上覆岩层的聚集具有重要意义, 之后蒸气冷凝可产生高盐度的含矿卤水或与渗流地下水混合形成低-中等盐度的成矿流体, 流体的减压沸腾(相分离)和对围岩的交代蚀变导致W、Mo等金属在不同阶段和构造-岩性部位沉淀富集。  相似文献   

Contributing to marine pollution by washing your face: Microplastics in facial cleansers   总被引：6，自引：0，他引：6  

Lisa S. Fendall 《Marine pollution bulletin》2009,58(8):1225-9179

Plastics pollution in the ocean is an area of growing concern, with research efforts focusing on both the macroplastic (>5 mm) and microplastic (<5 mm) fractions. In the 1990s it was recognized that a minor source of microplastic pollution was derived from liquid hand-cleansers that would have been rarely used by the average consumer. In 2009, however, the average consumer is likely to be using microplastic-containing products on a daily basis, as the majority of facial cleansers now contain polyethylene microplastics which are not captured by wastewater plants and will enter the oceans. Four microplastic-containing facial cleansers available in New Zealand supermarkets were used to quantify the size of the polythelene fragments. Three-quarters of the brands had a modal size of <100 microns and could be immediately ingested by planktonic organisms at the base of the food chain. Over time the microplastics will be subject to UV-degradation and absorb hydrophobic materials such as PCBs, making them smaller and more toxic in the long-term. Marine scientists need to educate the public to the dangers of using products that pose an immediate and long-term threat to the health of the oceans and the food we eat.  相似文献   

膨润土研究现状及其作为PRB反应介质的探讨     

杨维  杨军锋  王立东  王虎  郭毓 《地质与资源》2007,16(2):155-160

在阐述膨润土的矿物学特性、类型及其改性方法（包括酸活化、焙烧、无机盐,有机铵盐）的基础上,探讨了其在废水处理、垃圾填埋场和土壤改良中的应用现状,并以膨润土作为反应介质,COD（化学需氧量）、Cr⁶⁺和NH₄⁺为靶污染物,进行垃圾渗滤液对地下水污染的渗透反应格栅（PRB）实验研究,结果表明：pH值和DO（垃圾渗滤液中的溶解氧）对靶污染物的去除效果有一定的影响,且反应介质对COD、Cr⁶⁺和NH₄⁺的去除率分别为53%、51%和53%,此结果说明了以膨润土作为PRB的反应介质是可行的.  相似文献   

Natural and Enhanced Concentrations of Trace Metals in Sediments of Cleveland Bay, Great Barrier Reef Lagoon, Australia   总被引：1，自引：0，他引：1  

G.B Doherty  G.J Brunskill  M.J Ridd 《Marine pollution bulletin》2000,41(7-12):337-344

Natural variation in concentrations of Cd, Co, Cu, Ni, Pb, and Zn in sediments of Cleveland Bay can be modelled by linear regression by using the concentration of Al recovered by strong acid digestion as an independent variable. Samples that exceed the upper 95% prediction interval of regression models are classified as enhanced. Enhancement of trace metals occurs in the intertidal zone and near-shore sediments of western Cleveland Bay, in sites that are characterized by high accumulation rates of fine grained terrigenous sediment. There is a strong positive relationship between increasing enhancement of Cu and Pb and the recovery of these metals by weak HCl digestion, which suggests that for these metals the modelled enhancement is environmentally meaningful. In contrast, at least 60%, and generally greater than 80% of Cd is recovered by weak HCl digestion irrespective of modelled enhancement, and suggests that the statistically modelled enhancement of Cd may be more meaningful than weak HCl soluble concentrations.  相似文献   

Method for Flux‐Chamber Measurement of Ammonia Volatilization From Putting Greens Foliarly‐Fertilized by Urea     

《洁净——土壤、空气、水》2017,45(9)

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Characteristics of gaseous pollutants near a main traffic line in Beijing and its influencing factors   总被引：5，自引：0，他引：5  

Jianhua Chen  Wei Wang  Jianyu Zhang  Hongjie Liu  Lihong Ren  Xiaoyu Liu  Wenjie Zhang  Xuan Wang 《Atmospheric Research》2009,94(3):470-480

Automobile exhaust emissions are becoming increasingly serious with the drastic increase of the number of vehicles in Beijing. In order to investigate the air pollution level and characteristics in the areas near the main traffic lines in Beijing and to identify the contributions from traffic and other sources, gaseous pollutants including NOx, CO, O₃, SO₂, and meteorological parameters have been monitored at a monitoring site and a contrasting site in winter and summer in 2006. The volumes of vehicles on Beiyuan Road were recorded. The average concentrations of NO, NO₂, NOx, CO, O₃, and SO₂ at the monitoring site were 0.148 mg/m³, 0.107 mg/m³, 0.333 mg/m³, 5.110 mg/m³, 0.006 mg/m³, and 0.157 mg/m³, respectively during the sampling period in winter and 0.021 mg/m³, 0.068 mg/m³, 0.101 mg/m³, 4.170 mg/m³, 0.083 mg/m³, and 0.056 mg/m³, respectively in summer. The high concentrations of CO and O₃ reflect the influence of vehicles emission near the traffic lines evidently. The higher concentrations of CO, NO and O₃ in summer may indicate that the characteristics of traffic pollution were more pronounced in summer. Results of regression analysis showed that in winter the concentrations of SO₂ and CO were significantly positively correlated with the emission of heating boilers at night and negatively correlated with wind speed in daytime. The concentrations of NO and NOx were negatively correlated with wind speed, positively correlated with emission of heating boilers in daytime and positively correlated with traffic density at nighttime. The concentrations of NO₂ were positively correlated with the emission of heating boilers in daytime and traffic density at nighttime. In summer, the air quality at the monitoring site and the contrasting site was mainly influenced by the traffic emissions.  相似文献