安徽庐枞盆地酸性蚀变岩帽地质地球化学特征研究   总被引：5，自引：4，他引：1  

李旋旋  张乐骏  高昌生  谢杰  Noel C WHITE 《岩石学报》2017,33(11):3545-3558

酸性蚀变岩帽是浅成低温热液系统演化的产物,形成于酸性高氧化性流体的化学条件下;在高硫化型浅成低温热液金矿床中广泛发育,是该类矿床的显著识别特征。通过对酸性蚀变岩帽的野外地质特征、矿物共生组合和地球化学特征研究,能较好阐明浅成低温成矿热液系统的特征、性质、发生和发展演化及成矿作用过程。庐枞矿集区是长江中下游成矿带重要的矿集区之一,盆地内广泛发育以明矾石为特征蚀变矿物的酸性蚀变岩帽,面积超过30km~2,指示盆地内高硫化浅成低温热液系统的存在。目前为止,前期工作主要针对明矾石矿床地质特征和明矾石资源储量进行,该酸性蚀变岩帽的地质地球化学特征研究尚未开展。本次工作通过对酸性蚀变岩帽系统的野外采样、全岩地球化学分析和短波红外光谱测试分析技术(PNIRS测试)分析,确定其主要赋存在砖桥组火山岩中,组成矿物为石英、明矾石、高岭石、地开石,此外有少量绢云母、伊利石、珍珠陶土、叶蜡石、褐铁矿,极少数的叶腊石和黄钾铁矾等,在钻孔深部存在浸染状和半自形粒状黄铁矿。由于受到地表风化剥蚀和不同热热中心的影响,水平方向从矾山明矾石矿床向外围发育石英+明矾石带、石英+高岭石/地开石+明矾石带、石英+高岭石/地开石带、硅化带以及最外围的泥质带即高岭石±绢云母±伊利石带。根据酸性蚀变岩帽的矿物组合和主量元素特征,可将其分为三类:硅质蚀变岩、明矾石蚀变岩和粘土蚀变岩。硅质蚀变岩中SiO_2含量发生明显的富集作用,其余主量元素(K_2O、Na_2O、Al_2O_3、Fe_2O_3、P_2O5)含量显著降低;明矾石蚀变岩和粘土蚀变岩具有相似的地球化学特征,SiO_2、Al_2O_3、Fe_2O_3、P_2O_5元素含量范围变大,K_2O和Na_2O含量降低,且Na_2O降低更加明显;而钛为不活泼元素,在岩石发生蚀变过程中TiO_2含量变化很小。矾山地区的酸性蚀变岩帽的产状、蚀变类型、地球化学特征受构造和地层的双重控制。  相似文献   

A Review of Magnesium Isotope System in Rivers     

Dong Aiguo  Han Guilin 《地球科学进展》2017,32(8):800-809

In recent years, a series of important progresses have been made in the aspect of magnesium isotopes behavior in weathering processes. These progresses are not only favorable to understand the change of the magnesium isotopic compositions in rivers, but also establish the foundation to further reveal the magnesium isotope geochemical cycle. The magnesium in rivers is both magnesium sink for weathering and magnesium source for the ocean. The Mg isotopic compositions in rivers are dominated by the magnesium sources and Mg isotope fractionations processes. The sources of magnesium in rivers originate mainly from draining rocks, as well as less contribution from the eolian deposition, groundwater, plant debris, and precipitation. The Mg isotope fractionations in rivers are mainly related to precipitation and dissolution of carbonate minerals, silicate mineral hydrolysis, adsorption on mineral or colloidal matter surface, and plant uptake. Generally, the contribution of carbonate minerals dissolution or precipitation is equal to add or reduce magnesium from carbonate endmember, which has a remarkably negative δ²⁶Mg value. Based on the fact that most clay minerals are rich in ²⁶Mg during nature silicate mineral hydrolysis, then it is possible to infer that residual weathering products enrich in ²⁶Mg. However, there is no significant Mg isotope fractionation causing by the adsorption on mineral or colloidal matter surface during river water migration. For the plant uptake, the root prefers to have ²⁶Mg, leading the plant itself rich in heavier Mg isotopic composition. In addition, formation of secondary minerals in rivers could also reflect the changes of chemical parameters in rivers (such as major elements, CO₂ solubility, pH, etc.). Hence, Mg isotopic composition in rivers and associated isotope fractionations are not only the basis for the application of magnesium isotope to trace surface material cycle, but also have important significance for the further understanding the geochemical cycle of magnesium isotopes.  相似文献   

Depositional environment and geochemical characteristics of the Lower Carboniferous source rocks in the Marsel area,Chu-Sarysu Basin,Southern Kazakhstan     

《Marine and Petroleum Geology》2017

There are two sets of carbonate source rocks in the Lower Carboniferous layers in Marsel: the Visean (C₁v) and Serpukhovian (C₁sr). However, their geochemical and geological characteristics have not been studied systematically. To assess the source rocks and reveal the hydrocarbon generation potential, the depositional paleoenvironment and distribution of C₁v and C₁sr source rocks were studied using total organic carbon (TOC) content, Rock-Eval pyrolysis and vitrinite reflectance (Ro) data, stable carbon isotope data, gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS) analysis data. The data were then compared with well logging data to understand the distribution of high-quality source rocks. The data were also incorporated into basin models to reveal the burial and thermal histories and timing of hydrocarbon generation. The results illustrated that the average residual TOC contents of C₁v and C₁sr were 0.79% and 0.5%, respectively, which were higher than the threshold of effective carbonate source rocks. Dominated by type-III kerogen, the C₁v and C₁sr source rocks tended to be gas-bearing. The two source rocks were generally mature to highly mature; the average Ro was 1.51% and 1.23% in C₁v and C₁sr, respectively. The source rocks were deposited in strongly reducing to weakly oxidizing marine–terrigenous environments, with most organic material originating from higher terrigenous plants and a few aquatic organisms. During the Permian, the deep burial depth and high heat flow caused a quick and high maturation of the source rocks, which were subsequently uplifted and eroded, stopping the generation and expulsion of hydrocarbons in the C₁v and C₁sr source rocks. The initial TOC fitted by the △logR method was recovered, and it suggests that high-quality source rocks (TOC ≥ 1%) are mainly distributed in the northern and central local structural belt.  相似文献   

庞西垌地区地球化学异常圈定方法讨论          下载免费PDF全文

王琨  周永章  高乐 《江苏地质》2012,36(1):64-69

庞西垌地区位于钦杭成矿带南段,是主要的贵金属、有色金属成矿区。区内构造复杂,岩浆活动频繁。基于庞西垌地区水系沉积物测量数据,以Au、Ag元素含量为例,分别利用传统统计学方法、趋势面法和分形方法计算其异常下限值,并圈定地球化学异常。通过对3种方法计算过程及应用效果的对比,分析了3种方法应用于本研究区的效果,进而揭示了复杂地质背景下,最适用于圈定地球化学异常的方法。  相似文献   

江南造山带深部边界及成矿制约：来自综合地球物理的认识          下载免费PDF全文

严加永  吕庆田  张永谦  刘卫强  王栩  陈昌昕  徐峣  刘家豪 《岩石学报》2022,38(2):544-558

江南造山带位于组成华南大陆的扬子地块和华夏地块之间，是揭示华南陆块演化及其动力学过程、探索该地区大规模岩浆多金属成矿作用的关键窗口。前人在构造学、岩石学和矿床学等方面取得了诸多进展，但仍对江南造山带的深部结构认识不明，导致对其定义、边界范围、形成时代及演化过程等方面长期存在争议，故亟需开展综合地球物理探测工作，为解决上述争议问题提供约束。鉴于后期构造运动对上地壳大幅改造的影响，致使对于江南造山带的深部边界存在不同认识，本文以重力数据和航磁数据为主、辅以大地电磁测深结果、并与水系沉积物地球化学资料相结合，厘定江南造山带的深部边界。综合重磁多尺度边缘检测、深部电性结构及75种元素水系沉积物地球化学数据聚类分析结果，推测钦杭结合带可能为江南造山带东南侧深部边界，并推断了江南造山带北部可能的深部边界和周缘的断裂构造。基于上述结果和认识，分析了区域构造对金、铜矿床的控制作用，认为江南造山带深部边界及深部断裂扮演了成矿系统中“导矿通道”的角色，从深大断裂形成之初就提供了铜、金等幔源成分为主的矿物质，在合适位置就位成矿；后期复杂的构造运动，使得局部位置再次活化，成矿物质重新富集迁移，在次级断裂等有利...  相似文献   

A Fissure-Controlled Acidic Volcanic Centre (Ordovician) at Yr Arddu,North Wales     

M. F. Howells  S. D. G. Campbell  A. J. Reedman  S. P. Tunnicliff 《Geological Journal》1987,22(2):133-149

The Yr Arddu Tuffs (Ordovician) are a sequence of predominantly welded acid ash-flow tuffs in the outlier centred on Yr Arddu (North Wales). The tuffs accumulated above a NNE-trending fracture, the Yr Arddu Fracture, which had previously influenced sedimentation. The heterogeneity of the tuffs and their restricted development suggest that they represent proximal accumulations from small or suppressed (boiling-over) eruption columns. The eruptions and emplacement developed, at least in the initial stages, in a submarine environment. Lithological, geochemical and palaeontological evidence indicates that the tuffs represent the earliest eruptive phase of the Lower Rhyolitic Tuff Formation. They were later intruded by comagmatic rhyolite domes, whose alignment reflects the continued influence of the early fracture.  相似文献   

中国大陆科学钻探工程主孔榴辉岩原岩研究及其成因指示          下载免费PDF全文

叶景艳  胡建  汤倩 《江苏地质》2013,37(1):1-16

榴辉岩是造山带中最为常见的高级变质岩石,无论是自身还是其原岩均蕴含着丰富的地球动力学信息。以中国大陆科学钻探工程主孔0～2000m范围内揭露的榴辉岩为对象,按其与围岩接触关系,划分为与片麻岩类共生的榴辉岩、与超基性岩毗邻的榴辉岩以及与超基性岩共生的榴辉岩3种类型。据此对比分析了此3类榴辉岩的地球化学组成的差异,提出了这些岩石的原岩可能是由单一岩浆房岩浆经堆晶及分离结晶作用演化而来的基性—超基性杂岩体,物质来源主要为富集地幔物质的部分熔融,其构造环境应位于洋壳对大陆俯冲的消减带,但并非岛弧环境,应是弧后拉张岩浆作用的产物。  相似文献   

江苏基础地质工作程度概述   总被引：1，自引：0，他引：1  

钱凤仪 《江苏地质》1997,21(1):1-6

江苏基础地质工作开展较早，研究程度较高，从区域地质调查，地球物理勘探，地球化学勘探三方面对江苏的基础地质工作情况进行了概述。  相似文献