兖州矿区煤中某些微量元素的赋存状态研究   总被引：6，自引：8，他引：6  

刘桂建  杨萍玥  彭子成  王桂梁  曹增会 《地球化学》2002,31(1):85-90

微量元素的赋存状态决定其在煤的加工利用过程中释放的难易程度和毒性，弄清其在煤中的赋存状态，对准确评价元素的工艺性能、环境影响、作为副产品的可能性以及在地质意义上都是十分重要的。分析了微量元素在煤中的有机亲合性，采用数理统计方法，求得了微量元素与煤中有机显微组分、三态硫、灰分之间的相关性，并在浮沉实验的基础上，分析了微量元素的存在状态，通过研究向知，Ge、Ga、U、V、Cu、Th、Pb和Zn主要以无机态存在于煤中，F和Cl可能以有机态存在为主，As无机态和有机态存在的机率相似。  相似文献   

Crustal structure of the Ruby Mountains and southern Carlin Trend region, Nevada, from magnetotelluric data     

Philip E. Wannamaker  William M. Doerner 《Ore Geology Reviews》2002,21(3-4)

We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings reside in three east–west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass, and Secret Pass latitudes). One short cross-line was also taken to assess an east–west structure to the north of the northern profile. Model resistivity cross-sections were derived from the MT data using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity–thickness product) from east to west. These increases are attributed to graphitization caused by Elko–Sevier era compressional shear deformation and possibly by intrusive heating. The resistive crystalline central massifs adjoin the host stratigraphy across crustal-scale, steeply dipping fault zones. The zones provide pathways to the lower crust for heterogeneous, upper crustal induced, electric current flow. Resistive core complex crust appears steeply bounded under the middle of the neighboring grabens and not to deepen at a shallow angle to arbitrary distances to the west. The numerous crustal breaks imaged with MT may contribute to the low effective elastic thickness (T_e) estimated regionally for the Great Basin and exemplify the mid-crustal, steeply dipping slip zones in which major earthquakes nucleate. An east–west oriented conductor in the crystalline upper crust spans the East Humboldt Range and northern Ruby Mountains. The conductor may be related to nearby graphitic metasediments, with possible alteration by middle Tertiary magmatism. Lower crustal resistivity everywhere under the profiles is low and appears quasi one-dimensional. It is consistent with a low rock porosity (<1 vol.%) containing hypersaline brines and possible water-undersaturated crustal melts, residual to the mostly Miocene regional extension. The resistivity expression of the southern Carlin Trend (CT) in the Pinon Range is not a simple lineament but rather a family of structures attributed to Eocene intrusion, stratal deformation, and alteration/graphitization. Substantial reactivation or overprinting by core complex uplift or Basin–Range extensional events seems likely. We concur with others that the Carlin Trend may result in part from overlap of the large Eocene Northeast Nevada Volcanic Field with Precambrian–Paleozoic deep-water clastic source rocks thickening abruptly to the west of the Pinon Range, and projecting to the north–northwest.  相似文献   

New Mexico structural zone—an analogue of the Colorado mineral belt     

P. K. Sims  H. J. Stein  C. A. Finn   《Ore Geology Reviews》2002,21(3-4)

Updated aeromagnetic maps of New Mexico together with current knowledge of the basement geology in the northern part of the state (Sangre de Cristo and Sandia–Manzano Mountains)—where basement rocks were exposed in Precambrian-cored uplifts—indicate that the northeast-trending Proterozoic shear zones that controlled localization of ore deposits in the Colorado mineral belt extend laterally into New Mexico. The shear zones in New Mexico coincide spatially with known epigenetic precious- and base-metal ore deposits; thus, the mineralized belts in the two states share a common inherited basement tectonic setting. Reactivation of the basement structures in Late Cretaceous–Eocene and Mid-Tertiary times provided zones of weakness for emplacement of magmas and conduits for ore-forming solutions. Ore deposits in the Colorado mineral belt are of both Late Cretaceous–Eocene and Mid-Tertiary age; those in New Mexico are predominantly Mid-Tertiary in age, but include Late Cretaceous porphyry-copper deposits in southwestern New Mexico.The mineralized belt in New Mexico, named the New Mexico structural zone, is 250-km wide. The northwest boundary is the Jemez subzone (or the approximately equivalent Globe belt), and the southeastern boundary was approximately marked by the Santa Rita belt. Three groups (subzones) of mineral deposits characterize the structural zone: (1) Mid-Tertiary porphyry molybdenite and alkaline-precious-metal deposits, in the northeast segment of the Jemez zone; (2) Mid-Tertiary epithermal precious-metal deposits in the Tijeras (intermediate) zone; and (3) Late Cretaceous porphyry-copper deposits in the Santa Rita zone. The structural zone was inferred to extend from New Mexico into adjacent Arizona. The structural zone provides favorable sites for exploration, particularly those parts of the Jemez subzone covered by Neogene volcanic and sedimentary rocks.  相似文献   

Variation in element release rate from different mineral size fractions from the B horizon of a granitic podzol     

Mark E. Hodson 《Chemical Geology》2002,190(1-4):91-112

Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10⁻¹⁴ mol/m²/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10⁻¹⁴ mol/m²/s) and sheet silicates (100×10⁻¹⁴ mol/m²/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10⁻¹⁴ mol/m²/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.  相似文献   

矿产资源资产与市场优化配置     

郑锡泉 《江苏地质》2003,27(4):242-245

将土地资产的理论与经验引进矿产资源管理，探讨建立和完善社会主义矿产资源市场经济制造，指出实现矿产资源性资产的市场机制是资源优化配置的一种十分重要的手段。它能够通过各级政府规划或者指导对资源的形势研究，预测其供求、价格和竞争之间的相互作用和影响。推动资源的科学利用与有效保护，合理流动与分配，提高资源利用率，从而促进社会经济的可持续发展。探讨和创建矿产资源性资产与产权管理的新机制，其实质是采矿权人根据国家法律，按统一的技术规定、规程、标准和要求，对其占用的资源储量进行定期或不定期的检测，编制相应的动态报表、年度报告和统计报表。国家根据矿种类型，通过省市县建立不同层次的矿产资源储量数据库进行产权管理。政府的监督管理主要由矿产资源储量登记与统计及核查机制组成。  相似文献   

基于GIS技术的矿产资源信息系统   总被引：8，自引：3，他引：8  

蔡洪春  张春明  姜绍飞  陈为公  寇大明 《地质与资源》2003,12(2):111-114

地质资料基本上可以分为空间数据和属性数据两大类.它们是地学数据不可分割的两方面,客观上要求统一进行管理.采用地理信息系统技术,可以彻底解决两种类型数据统一管理问题.结合正在开展的辽宁省矿产资源勘查、开发与利用规划工作,论述了建立基于GIS技术的辽宁矿产资源信息系统实现数据可视化和空间模型分析的思路和实现方法.它为今后矿产资源管理工作实现全面科学化管理提供了现代化手段,也为制定行业发展规划以及进行生产决策提供了支持,进而促进地质找矿和矿产开发的工作部署朝思维可视化及思路多样化的方向发展.  相似文献   

青海东昆仑肯德可克金-有色金属矿床矿物特征研究   总被引：4，自引：0，他引：4  

王力  孙丰月  陈国华  李碧乐  迟效国 《世界地质》2003,22(1):50-56

肯德可克贵金属-有色金属矿床有多种元素达到工业要求，矿物组成复杂，本文在详细的光、薄片鉴定和电子探针分析的基础上，分析研究了该矿床的矿物组成特征，并根据成矿地质特征、矿物组合特点和矿物间的穿插关系，划分了成矿期次，进而确定该矿床为-多期成矿作用叠加的叠生型金-有色金属矿床。  相似文献   

中国金银矿产资源现状成矿环境及开发前景   总被引：5，自引：0，他引：5  

朱桂田 《矿产与地质》1997,(6):368-373

中国金银矿产具有类型齐全的共同特点，其资源和开发前景表现为金矿优于银矿。金矿成矿环境有利，成矿时代及资源分布广泛。但是，储量在１００吨以上的超大型矿床不多，富矿少，资源利用程度高，且浪费严重，存在重开发、轻勘查等问题。银矿虽然是世界上资源丰富的国家之一，但仍然是我国资源保证程度较低的矿种之一，也存在特大型矿床少、探明储量不足的问题。  相似文献   

Genesis and distribution of mineral waters as a consequence of recent lithospheric dynamics: the Rhenish Massif,Central Europe     

Franz May  Stephan Hoernes  Horst J. Neugebauer 《International Journal of Earth Sciences》1996,85(4):782-799

Three major, interdependent processes control the genesis and distribution of mineral and thermal waters in the Rhenish Massif, Central Europe: (a) Magmatic processes in the upper mantle provide most of the CO₂ to produce bicarbonate waters in shallow aquifers. (b) Extension of the brittle upper crust enables the ascent of sodium chloride waters. (c) Uplift and erosion shape the massif's relief, which determines the extent of flow systems and the distribution of thermal springs. The chemistry of mineral waters further depends on the aquifers' mineral composition. A comprehensive set of hydrological, chemical, tectonic and geophysical data on the Rhenish Massif has been compiled. It was used to classify the mineral waters and to map the spatial distribution of water properties. The composition of cuttings from several representative wells producing different water types shows that the hydrothermal alteration of the aquifer rocks consists mainly of kaolinization of chlorite and dissolution of feldspar. Numerical transport simulations favour two modes of groundwater flow: topography-driven flow and the pressure-driven ascent of basement brines along active faults. Thermal convection is less important.  相似文献   

Metamorphic evolution of oceanic gabbros: recrystallization from subsolidus to hydrothermal conditions in the MARK area (ODP Leg 153)     

L. Gaggero  L. Cortesogno 《Lithos》1997,40(2-4):105-131

The 117.38 m of gabbroic core drilled during the Ocean Drilling Program (ODP) Leg 153 at Sites 921 to 924 in the Mid-Atlantic Ridge (MAR) between 23 °N and the Kane Fracture Zone, exhibits a remarkable primary compositional heterogeneity, such as magmatic layering, intrusive contacts and late magmatic veining, which express a succession of magmatic events. Textural indicators suggest that the cooling of the crystal mush occurred in a dynamic environment, with infiltration of progressively evolved liquids. Magmatic features include random shape fabric and magmatic lamination; the subsequent deformational overprint occurred in subsolidus conditions. The ductile deformation, generally concentrated in discrete domains of the gabbro, is associated with continuous re-equilibration of the metamorphic assemblages of (1) olivine + clinopyroxene + orthopyroxene + plagioclase + ilmenite + Ti-magnetite, (2) olivine + clinopyroxene + plagioclase + ilmenite + Ti-magnetite + red hornblende. At lower temperatures brittle deformation prevails and subsequent fractures control the development of metamorphic assemblages: (3) clinopyroxene + plagioclase + red brown hornblende + Ti-magnetite + magnetite (?) + ilmenite, (4) plagioclase + brown hornblende + Ti-magnetite + magnetite + hematite + titanite ± Ti-oxide, (5) plagioclase + green hornblende + magnetite + titanite, (6) plagioclase + actinolite + chlorite + titanite + magnetite, (7) albite + actinolite + chlorite + prehnite ± epidote ± titanite and (8) albite + prehnite + chlorite ± smectite. Assemblages 1 to 8 express increasing water/rock ratios and decreasing degrees of recrystallization.

During the ductile phase, red hornblende is stable and its abundance increases with deformation intensity, possibly as an effect of the introduction of hydrous fluids. During the brittle phase, water diffusion controls the development of the fracture-filling mineral assemblages and re-equilibration of the adjacent rock; temperatures decrease further, as demonstrated by mineral zoning and incompletely re-equilibrated assemblages. The lowest temperatures correspond to the development of hydrothermal assemblages.

Compared with oceanic gabbros from fast-spreading transform environments, high-temperature ductile phases (granulite and amphibolite) are well developed, whereas brittle phases are widespread, as microcracks, prevalent on fracturing associated with discrete veins.  相似文献