中国大陆科学钻探主孔100～2000米超高压变质岩中的钛矿化   总被引：14，自引：12，他引：14  

徐珏陈毓川  王登红余金杰李纯杰  傅旭杰陈振宇 《岩石学报》2004,20(1):119-126

中国大陆科学钻探工程100～2000m的岩心、矿心的观察、编录揭示主要有经济价值的舍钛相是金红石．其次是钛磁铁矿。主要含矿岩石是普通金红石榴辉岩和石英金红石榴辉岩，其次有多硅白云母金红石榴辉岩，蓝晶石金红石榴辉岩，金红石黑云绿帘纤闪石岩(退变的石榴辉石岩)和金红石-含钒钛磁铁矿榴辉岩。划分了四个矿化层位。金红石在矿层中的含量一般为2％～5％(体积)，多高达8％～10％。金红石的TiO2含量在95％(重量)以上，多产于石英榴辉岩、多硅白云母榴辉岩中。钛磁铁矿的TiO2含量在49％～55％(重量)，钛磁铁矿多见于黄铁矿-金红石-钛磁铁矿榴辉岩(546～608m岩性段)中，含钛磁铁矿5％～25％，石榴单辉橄榄岩(608～683m岩性段)，含钛磁铁矿达5％～10％和第三含矿层中局部黑云绿帘角闪岩夹层内，舍钛磁铁矿可达6％。30个榴辉岩和超铁镁质岩中8种主要造岩矿物148个点的电子探针分析结果揭示：榴辉岩可分为壳源和幔源两大类，钛磁铁矿富含V、Ni、Cr说明来自幔源，大部分金红石则来自壳源榴辉岩，它们的原岩是曾经居留地表的基性火成岩，在深俯冲的过程中经超高压变质成为含柯石英的榴辉岩。岩石薄片中金红石和柯石英的假像共存于同一石榴石或绿辉石晶粒中，也见金红石粒内有“柯石英”假象，这清楚说明金红石结晶于超高压的峰期变质阶段，在后继的变质地体隆升过程中，钛磁铁矿和金红石都有退变质成为钛铁矿和榍石的种种岩石记录，因此，退变质作用势必导致钛矿品位的降低。  相似文献   

新疆西南天山木扎尔特一带低压麻粒岩相变质作用P-T轨迹及其地质意义   总被引：11，自引：5，他引：11  

李强  张立飞 《岩石学报》2004,20(3):583-594

本文首次报道在新疆西南天山木扎尔特一带发现了二辉石麻粒岩和麻粒岩相变质的堇青石榴矽线石片麻岩。二辉石麻粒岩的矿物组合为单斜辉石-斜方辉石-黑云母-角闪石-斜长石-石英。堇青石榴矽线石片麻岩矿物组合为堇青石-矽线石-石榴石-黑云母-斜长石-石英。岩石学和矿物学特征表明它们是典型的低压麻粒岩相变质岩石，其变质作用经历了两期演化：a．峰期麻粒岩相变质，T=681～705℃，P=5．4～5．8kbar；b．峰后角闪岩相退变阶段，T：571～637℃．P=4．7～5．3kbar。其变质作用P-T轨迹具有逆时针近等压降温(IBC)的特点，代表该地区可能为塔里木板块向伊犁．中天山板块俯冲过程中，在陆壳一侧所产生的陆源岩浆弧区域，由于受到下部岩浆热源的影响，在拉伸环境下出现低压麻粒岩相变质。通过分析低压麻粒岩相岩石与其南部高压一超高压变质带的大地构造位置和年代关系，我们认为该地区的低压麻粒岩相变质岩石可能与其南部的西天山高压一超高压变质带组成了双变质带。  相似文献   

大别山太湖地区榴辉岩峰期变质条件与构造意义   总被引：3，自引：6，他引：3  

石永红  王清晨 《岩石学报》2004,20(3):609-620

大别山太湖地区曾被作为“冷”、“热”榴辉岩带的交界处所在，我们对大别山太湖地区的进行了1：10000地质填图，并详细研究了该地区榴辉岩的岩相学和矿物成分变化，以及KD值、峰期变质P-T条件。研究表明榴辉岩自南向北可分为三类：①朱家冲型榴辉岩；②大坝型榴辉岩；③金河桥型榴辉岩。其中朱家冲型榴辉岩和金河桥型榴辉岩显示出明显的温度、压力差异，它们形成的P-T条件分别为：P=2．14GPa、T=563℃和P=3．76GPa、T=791℃。大坝型榴辉岩的峰期变质P-T条件差别较大，在柯石英-石英相变线附近徘徊，变质环境相当于高压一超高压过渡环境。朱家冲型榴辉岩与大坝型榴辉岩分别对应于前人所划分的“冷”、“热”榴辉岩，并且两者在峰期，变质温、压条件上是连续变化的，没有明显的温、压间断。因此，我们认为本区所谓的“冷”、“热”榴辉岩带界线是不存在的。  相似文献   

红透山矿床变质岩系褶皱构造特征浅析   总被引：1，自引：0，他引：1  

王锡华  李伟 《矿产与地质》2004,18(3):245-248

红透山式铜-锌矿床形成于太古代克拉通裂谷槽盆中海底火山喷发-沉积环境。因此，矿床的空间展布严格受特定的含矿岩系所控制。槽盆构造中的岩层褶皱构造最发育，矿床赋存在具多期褶皱构造叠加的大型同倾向形褶皱内，褶皱的层间虚脱是控矿有利构造空间，可以借此预测矿体侧伏方向及赋存部位。  相似文献   

Mantle Xenoliths from the Southeastern Slave Craton: Evidence for Chemical Zonation in a Thick, Cold Lithosphere   总被引：7，自引：3，他引：7  

KOPYLOVA  M. G.; CARO  G. 《Journal of Petrology》2004,45(5):1045-1067

We present the first data on the petrology of the mantle lithosphereof the Southeastern (SE) Slave craton, Canada. These are basedon petrographic, mineralogical and geochemical studies of mantlexenoliths in Pipe 5034 of the Cambrian Gahcho Kué kimberlitecluster. Major types of mantle xenoliths include altered eclogite,coarse garnet or spinel peridotite, and deformed garnet peridotite.The peridotites belong to the low-temperature suite and formedat T=600–1300°C and P= 25–80 kbar in a thick(at least 220–250 km), cool lithosphere. The SE Slavemantle is cooler than the mantle of other Archaean cratons andthat below other terranes of the Slave craton. The thick lithosphereand the relatively cool thermal regime provide favourable conditionsfor formation and preservation of diamonds beneath the SE Slaveterrane. Similar to average Archaean mantle worldwide, the SESlave peridotite is depleted in magmaphile major elements andcontains olivine with forsterite content of 91–93·5.With respect to olivine composition and mode, all terranes ofthe Slave mantle show broadly similar compositions and are relativelyorthopyroxene-poor compared with those of the Kaapvaal and Siberiancratons. The SE Slave spinel peridotite is poorer in Al, Caand Fe, and richer in Mg than deeper garnet peridotite. Thegreater chemical depletion of the shallow upper mantle is typicalof all terranes of the Slave craton and may be common for thesubcontinental lithospheric peridotitic mantle in general. Peridotiticxenoliths of the SE Slave craton were impregnated by kimberliticfluids that caused late-stage recrystallization of primary clinopyroxene,spinel, olivine and spinel-facies orthopyroxene, and formationof interstitial clinopyroxene. This kimberlite-related recrystallizationdepleted primary pyroxenes and spinel in Al. The kimberliticfluid was oxidizing, Ti-, Fe- and K-rich, and Na-poor, and introducedserpentine, chlorite, phlogopite and spinel into peridotitesat P < 35 kbar. KEY WORDS: kimberlite xenolith; lithosphere; mantle terrane; chemical zoning; thermobarometry; Slave craton  相似文献   

A Sequence of Pan-African and Hercynian Events Recorded in Zircons from an Orthogneiss from the Hercynian Belt of Western Central Iberia--an Ion Microprobe U-Pb Study   总被引：1，自引：0，他引：1  

ZECK  H. P.; WINGATE  M. T. D.; POOLEY  G. D.; UGIDOS  J. M. 《Journal of Petrology》2004,45(8):1613-1629

Sensitive high-resolution ion microprobe U–Pb dating showsthat a biotite orthogneiss from the Hercynian belt of westerncentral Iberia contains 1000–300 Ma zircon. Older, 1000–570Ma ages within this range represent inherited, detrital materialamong which four age components may be recognized:  相似文献   

Transformation of garnet epidote amphibolite to eclogite, western Dabie Mountains, China   总被引：8，自引：0，他引：8  

J. Liu  K. Ye 《Journal of Metamorphic Geology》2004,22(5):383-394

Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H₂O, and Amp + Ab = Omp ± Czo + Qtz + H₂O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H₂O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite.  相似文献   

Grain coarsening in contact metamorphic carbonates: effects of second-phase particles, fluid flow and thermal perturbations   总被引：3，自引：0，他引：3  

A. Berger  M. Herwegh 《Journal of Metamorphic Geology》2004,22(5):459-474

Under contact metamorphic conditions, carbonate rocks in the direct vicinity of the Adamello pluton reflect a temperature‐induced grain coarsening. Despite this large‐scale trend, a considerable grain size scatter occurs on the outcrop‐scale indicating local influence of second‐order effects such as thermal perturbations, fluid flow and second‐phase particles. Second‐phase particles, whose sizes range from nano‐ to the micron‐scale, induce the most pronounced data scatter resulting in grain sizes too small by up to a factor of 10, compared with theoretical grain growth in a pure system. Such values are restricted to relatively impure samples consisting of up to 10 vol.% micron‐scale second‐phase particles, or to samples containing a large number of nano‐scale particles. The obtained data set suggests that the second phases induce a temperature‐controlled reduction on calcite grain growth. The mean calcite grain size can therefore be expressed in the form D = C₂ e^Q*/RT(d_p/f_p)^m*, where C₂ is a constant, Q* is an activation energy, T the temperature and m* the exponent of the ratio d_p/f_p, i.e. of the average size of the second phases divided by their volume fraction. However, more data are needed to obtain reliable values for C₂ and Q*. Besides variations in the average grain size, the presence of second‐phase particles generates crystal size distribution (CSD) shapes characterized by lognormal distributions, which differ from the Gaussian‐type distributions of the pure samples. In contrast, fluid‐enhanced grain growth does not change the shape of the CSDs, but due to enhanced transport properties, the average grain sizes increase by a factor of 2 and the variance of the distribution increases. Stable δ¹⁸O and δ¹³C isotope ratios in fluid‐affected zones only deviate slightly from the host rock values, suggesting low fluid/rock ratios. Grain growth modelling indicates that the fluid‐induced grain size variations can develop within several ka. As inferred from a combination of thermal and grain growth modelling, dykes with widths of up to 1 m have only a restricted influence on grain size deviations smaller than a factor of 1.1. To summarize, considerable grain size variations of up to one order of magnitude can locally result from second‐order effects. Such effects require special attention when comparing experimentally derived grain growth kinetics with field studies.  相似文献   

Retrograded textures and associated mass transfer: evidence for aqueous fluid action during exhumation of the Qinglongshan eclogite, Southern Sulu ultrahigh pressure metamorphic terrane, eastern China   总被引：6，自引：0，他引：6  

T. N. Yang 《Journal of Metamorphic Geology》2004,22(7):653-669

The Qinglongshan eclogites in the Southern Sulu ultrahigh pressure metamorphic (UHPM) terrane show very different retrograded textures from their counterparts in the Northern Sulu terrane, implying a different thermal history. Scanning electron and optical microscope observations indicate that the peak assemblage of the Qinglongshan eclogite is anhydrous, composed of Grt + OmpI + Rt + (Ky + coesite). These primary minerals were replaced by second and third stage minerals, resulting in symplectite pseudomorphs or coronas. The following relationships are inferred: OmpI → OmpII + Ab + Fe‐oxide symplectite (type I) and Rt → Rt + Ilm intergrowth; and, Ky → Pg, OmpII (+Pl) → Amp (+Pl) symplectite (type II), and Grt → Prg (+Fe‐oxide). Mineral chemistry and mass‐balance demonstrate that the pseudomorphed textures were developed by metasomatism involving dissolution and precipitation intensified by fluids along grain boundaries. The formation of symplectite type I produced Fe, Mg and Na but consumed Ca and Si. The Mg and Fe diffused to garnet where exchange of (Mg, Fe) with Ca of the garnet resulted in compositional zonation with decreased Ca towards the edge of garnet grains where Ca was consumed during symplectite formation. The replacement of kyanite by paragonite consumed the extra Na. In the later stage, fluid infiltration partially transformed symplectite type I to type II, and narrow rims of pargasite resorbed garnet from their boundaries. Mass balance suggests that the transformation and resorption would have been coupled during fluid infiltration. In the latest stage, epidote and quartz were precipitated at very late stage as a result of fluid activity along microfractures. Tentative P–T conditions based on mineral reactions and thermocalc software suggest that the retrograded eclogite did not record the granulite facies retrograde evolution characteristic of eclogites from the Northern Sulu terrane. The difference in retrograde evolution between the Southern and Northern Sulu eclogites suggests a different exhumation history.  相似文献   

Late-Stage Ductile Deformation in Xiongdian-Suhe HP Metamorphic Unit, North-Western Dabie Shan, Central China     

SuoShutian ZhongZengqiu ZhouHanwen YouZhendong 《中国地质大学学报(英文版)》2004,15(3):262-274

New structural and petrological data unveil a very complicated ductile deformation history of the Xiongdian-Suhe HP metamorphic unit, north-western Dabie Shun, central China. The finegrained symplectic amphibolite-facies assemblage and coronal structure enveloping eclogite-facies garnet,omphacite and phengite etc., representing strain-free decompression and retrogressive metamorphism,are considered as the main criteria to distinguish between the early-stage deformation under HP metamorphic conditions related to the continental deep subduction and collision, and the late-stage deformation under amphibolite to greenschist-facies conditions occurred in the post-eclogite exhumation processes.Two late-stages of widely developed, sequential ductile deformations D3 and D4, are recognized on the basis of penetrative fabrics and mineral aggregates in the Xiongdian-Suhe HP metamorphic unit, which shows clear, regionally, consistent overprinting relationships. D3 fabrics are best preserved in the Suhe tract of low post-D3 deformation intensity and characterized by steeply dipping layered mylonitic amphibolites associated with doubly vergent folds. They are attributed to a phase of tectonism linked to the initial exhumation of the HP rocks and involved crustal shortening with the development of upright structures and the widespread emplacement of garnet-bearing granites and felsic dikes. D4 structures are attributed to the main episode of ductile extension (D^24) with a gently dipping foliation to the north and common intrafolial, recumbent folds in the Xiongdian tract, followed by normal sense top-to-the northductile shearing (D^24) along an important tectonic boundary, the so-called Majiawa-Hexiwan fault (MHF), the westward continuation of the Balifan-Mozitan-Xiaotian fault (BMXF) of the northern Dabie Shan. It is indicated that the two stages of ductile deformation observed in the Xiongdian-Suhe HP metamorphic unit, reflecting the post-eclogite compressional or extrusion wedge formation, the subhorizontal ductile extension and crustal thinning as well as the top-to-the north shearing along the high-angle ductile shear zones responsible for exhumation of the HP unit as a coherent slab, are consistent with those recognized in the Dabie-Sulu UHP and HP metamorphic belts, suggesting that they were closely associated in time and space. The Xiongdian-Suhe HP metamorphic unit thus forms part of the Triassic(250-230 Ma) collision orogenic belt, and can not connect with the South Altun-North Qaidam-North Qinline UHP metamorphic belt formed durin~ the Early Paleozoic (500-400Ma).  相似文献