Lawsonite eclogites preserve a record of very-low-temperature conditions in subduction zones. All occur at active margin settings, typically characterized by accretionary complexes lithologies and as tectonic blocks within serpentinite-matrix mélange. Peak lawsonite-eclogite facies mineral assemblages (garnet + omphacite + lawsonite + rutile) typically occur in prograde-zoned garnet porphyroblasts. Their matrix is commonly overprinted by higher-temperature epidote-bearing assemblages; greenschist- or amphibolite-facies conditions erase former lawsonite-eclogite relics. Various pseudomorphs after lawsonite occur, particularly in some blueschist/eclogite transitional facies rocks. Coesite-bearing lawsonite-eclogite xenoliths in kimberlitic pipes and lawsonite pseudomorphs in some relatively low-temperature ultrahigh-pressure eclogites are known. Using inclusion assemblages in garnet, lawsonite eclogites can be classified into two types: L-type, such as those from Guatemala and British Columbia, contain garnet porphyroblasts that grew only within the lawsonite stability field and E-type, such as from the Dominican Republic, record maximum temperature in the epidote-stability field.
Formation and preservation of lawsonite eclogites requires cold subduction to mantle depths and rapid exhumation. The earliest occurrences of lawsonite-eclogite facies mineral assemblages are Early Paleozoic in Spitsbergen and the New England fold belt of Australia; this suggests that since the Phanerozoic, secular cooling of Earth and subduction-zone thermal structures evolved the necessary high pressure/temperature conditions. Buoyancy of serpentinite and oblique convergence with a major strike-slip component may facilitate the exhumation of lawsonite eclogites from mantle depths. 相似文献
The Fe2+–Mg distribution coefficients between sapphirine and spinel:
were experimentally determined at pressures of 9–13 kbar and temperatures of 950–1150 °C using a natural ultrahigh-temperature (UHT) granulite with paragenesis of these minerals from the Napier Complex in East Antarctica [XMg = Mg / (Fe + Mg); XFe = Fe / (Fe + Mg)]. A new sapphirine–spinel geothermometer has been obtained as:
We applied the exchange thermometer to UHT or high-grade metamorphic rocks that were reported from various complexes in the world. If the KD values of 2.63–4.34 obtained from low-Cr mineral pairs such as XCrSpr < 0.016 and XCrSpl < 0.047 were substituted into the equation, their temperature conditions would be estimated as 806–1050 °C at 11 kbar. The XCr means Cr / (Al + Cr(+ Fe3+)). These temperatures are reasonable retrograde or near peak metamorphic condition. 相似文献
The Lesser Himalayan low- to medium-grade metamorphic rocks in central Nepal are rich in K-white micas occurring as porphyroclasts and in matrix defining S1 and S2. Porphyroclasts are usually zoned with celadonite-poor cores and celadonite-rich rims. The cores are the relics of igneous or high grade metamorphic muscovites, and the rims were re-equilibrated or overgrown under lower T metamorphic conditions. The matrix K-white micas defining S1, pre-dating the Main Central Thrust activity, are generally celadonite-rich. They show heterogeneous compositional zoning with celadonite-rich cores and celadonite-poor rims. They were recrystallized at lower T condition prior to the Main Central Thrust activity, most probably prior to the India–Asia collision (pre-Himalayan metamorphism). The matrix K-white micas along S2, synchronous to the Main Central Thrust activity (Neohimalayan metamorphism), are relatively celadonite-poor and were recrystallized under relatively higher T condition. K-white micas defining S1 also were partially re-equilibrated during the Neohimalayan metamorphism. The average compositions of recrystallized K-white micas defining both S1 and S2 become gradually poor in (Fe + Mg)- and Si-contents and rich in Al- and Ti-contents from south to north showing an increase of metamorphic grade from structurally lower to higher parts in the Lesser Himalaya. This shows that the metamorphism is inverted throughout the inner Lesser Himalaya. The tectono-metamorphic significance of the published K–Ar and 40Ar / 39Ar K-white micas ages from the Lesser Himalaya need re-evaluation in the context of observed intrasample compositional variation and zoning, and possible higher closure temperature (500 °C) for K–Ar system. 相似文献
The Achankovil Zone of southern India, a NW–SE trending lineament of 8–10 km in width and > 100 km length, is a kinematically debated crustal feature, considered to mark the boundary between the Madurai Granulite Block in the north and the Trivandrum Granulite Block in the south. Both these crustal blocks show evidence for ultrahigh-temperature metamorphism during the Pan-African orogeny, although the exhumation styles are markedly different. The Achankovil Zone is characterized by discontinuous strands of cordierite-bearing gneiss with an assemblage of cordierite + garnet + quartz + plagioclase + spinel + ilmenite + magnetite ± orthopyroxene ± biotite ± K-feldspar ± sillimanite. The lithology preserves several peak and post-peak metamorphic assemblages including: (1) orthopyroxene + garnet, (2) perthite and/or anti-perthite, (3) cordierite ± orthopyroxene corona around garnet, and (4) cordierite + quartz symplectite after garnet. We estimate the peak metamorphic conditions of these rocks using orthopyroxene-bearing geothermobarometers and feldspar solvus which yield 8.5–9.5 kbar and 940–1040 °C, the highest P–T conditions so far recorded from the Achankovil Zone. The retrograde conditions were obtained from cordierite-bearing geothermobarometers at 3.5–4.5 kbar and 720 ± 60 °C. From orthopyroxene chemistry, we record a multistage exhumation history for these rocks, which is closely comparable with those reported in recent studies from the Madurai Granulite Block, but different from those documented from the Trivandrum Granulite Block. An evaluation of the petrologic and geochronologic data, together with the nature of exhumation paths leads us to propose that the Achankovil Zone is probably the southern flank of the Madurai Granulite Block, and not a unit of the Trivandrum Granulite Block as presently believed. Post-tectonic alkali granites that form an array of “suturing plutons” along the margin of the Madurai Granulite Block and within the Achankovil Zone, but are absent in the Trivandrum Granulite Block, suggest that the boundary between the Madurai Granulite Block and the Trivandrum Granulite Block might lie along the Tenmalai shear zone at the southern extremity of the Achankovil Zone. 相似文献
Granulite-facies rocks are intermittently exposed in a roughly E–W trending belt that extends for approximately 2000 km across the North China Craton, from the Helanshan, Qianlishan, Wulashan–Daqingshan, Guyang and Jining Complexes in the Western Block, through the Huai'an, Hengshan, Xuanhua and Chengde Complexes in the Trans-North China Orogen, to the Jianping (Western Liaoning), Eastern Hebei, Northern Liaoning and Southern Jilin Complexes in the Eastern Block. The belt is generally referred to as the North China Granulite-Facies Belt, previously interpreted as the lowest part of an obliquely exposed crust of the North China Craton. Recent data indicate that the North China Granulite-Facies Belt is not a single terrane. Instead, it represents components of three separate terranes: the Eastern and Western Blocks and Trans-North China Orogen. Each of these units records different metamorphic histories and reflect the complex tectonic evolution of the NCC during the late Archean and Paleoproterozoic. Mafic granulites in the Eastern Block and the Yinshan Terrane (Western Block) underwent medium-pressure granulite-facies metamorphism at about 2.5 Ga, with anticlockwise P–T paths involving near isobaric cooling following peak metamorphism, reflecting an origin related to intrusion and underplating of mantle-derived magmas. Pelitic granulites in the Khondalite Belt (Western Block) underwent medium-pressure granulite-facies metamorphism at about 2.0–1.9 Ga, with clockwise P–T paths, which record the Paleoproterozoic amalgamation of the Yinshan and Ordos Terranes to form the Western Block. Mafic and pelitic granulites in the Trans-North China Orogen experienced high- to medium-pressure granulite-facies metamorphism at 1.85 Ga, with clockwise P–T paths involving nearly isothermal decompression following peak metamorphism, which are in accord with the final collision between the Eastern and Western Blocks to form the North China Craton at 1.8 Ga. The NCGB cannot therefore represent a separate unique terrane; instead it reflects the amalgamation of three separate granulite terranes that evolved independently and at different times. 相似文献