Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China     

Qi Wang  Xizhun Zhuo  Guojun Chen  Xiaoyan Li 《中国地球化学学报》2008,27(3):249-256

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.  相似文献   

Helium-argon isotopic tracing for the Pb-Zn-Ag polymetallic ore deposits in the central-south segment of the Da Hinggan Ling Range     

Baode Wang  Shuyin Niu  Aiqun Sun  Huabin Hu  Yaming Liu  Lijun Guo  Shuo Wang 《中国地球化学学报》2008,27(3):235-241

In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures.  相似文献   

Petroleum Migration Direction of the Silurian Paleo-pools in the Tarim Basin, Northwest China   总被引：1，自引：0，他引：1  

LIU Luofu  ZHAO Ye  HUO Hong  CHEN Lixin  CHEN Yuanzhuang  ZHAO Suping  LI Chao  LI Shuangwen  GUO Yongqiang  LI Yan 《《地质学报》英文版》2008,82(1):174-183

The results obtained in this paper indicate that carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has a high concentration and complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in studying petroleum migration of paleo-pool. During the basin＇s first-stage of oil-gas pool formation in the Silurian in Tazhong and Tabei areas of Tarim Basin （at the end of Silurian period） and the second-stage in the Awati area （in Permian）, the petroleum experienced a long-distance migration. During the formation of the Silurian paleo-pools in Tazhong Uplift at the end of Silurian, the petroleum mainly came from the lower and middle Cambrian source rocks in the Manjiaer sag. The petroleum migrated towards the southwest-south entering the Silurian reservoir beds in Tazhong first. Then, it further migrated within Silurian from northwest to southeast along the highs of the Structural Belts to the region of the Silurian pinchout boundary in Tazhong. In Tabei Uplift, during the first-stage of pool formation, the petroleum was also from the lower and middle Cambrian source rocks in the Manjiaer sag. It migrated northwest entering the Silurian reservoir beds in the Tabei Uplift firstly, and then the migration continued in the same direction within the Silurian reservoirs and finally the petroleum was trapped in higher positions. During the second-stage pool formation in the Silurian beds in the areas around Awati sag, the petroleum mainly came from the lower-middle Cambrian source rocks in the Awati sag. The petroleum migrated from the generation center to Silurian reservoirs in all directions around the sag through major paths, and the petroleum was finally trapped in higher locations.  相似文献   

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events     

FENG Chengyou  ZHANG Dequan  LI Daxin  SHE Hongquan  DONG Yingjun 《《地质学报》英文版》2008,82(4):826-837

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.  相似文献   

胶东地区晚中生代岩浆活动及对大地构造的制约   总被引：16，自引：1，他引：15  

邱连贵  任凤楼  曹忠祥  张岳桥 《大地构造与成矿学》2008,32(1):117-123

应用近十几年来胶东地区及其周边岩浆岩体的同位素测年资料,结合几个岩体的新的SHRIMP测年数据(牙山岩体117.7Ma,院格庄岩体113.4Ma,正长斑岩脉115.7Ma),系统研究了该区晚中生代以来的岩浆活动规律,结果表明,该区可分为4个岩浆活动期;(1)晚侏罗世构造-岩浆热事件(150~160Ma),以玲珑-滦家河型岩体为代表,是在区域挤压构造应力作用下侵入的,属同构造或同造山时期的岩浆作用。(2)早白垩世早期构造-岩浆热事件(135~125Ma),以郭家岭岩体为典型,该时期的岩浆活动均具有双峰式岩浆作用特征,反映了伸展动力学背景。(3)早白垩世中晚期构造-岩浆热事件(125~105Ma),以崂山花岗岩为特征,该阶段对应于中国东部岩石圈大规模的减薄时期,是大陆裂谷作用的高峰期。(4)晚白垩世-古新世基性-超基性火山作用。本文还探讨了岩浆活动的地球动力学因素及其对大地构造的制约。  相似文献   

川西坳陷中段天然气碳同位素特征及其成因类型   总被引：3，自引：1，他引：2  

王玲辉  沈忠民  赵虎 《物探化探计算技术》2008,30(4):326-330

川西坳陷中段天然气的组份以烃类气体为主,占气体总体积的98.1%～99.7%;非烃气体以CO,2和N2为主,其含量分别占气体的0.12%～1.32%和0.25%～1.54%;烃类气体中以甲烷占绝对优势,平均含量为95.83%;重烃含量较低,平均为3.21%;干燥系数(C1/C,1-5>)平均为0.97,整体上属典型的干气.川西坳陷中段的所有样品δ13C,2都大于-25.8‰,属于典型的煤型气范畴,天然气的δ13C,1δ'13C,2δ13C,3,呈明显的正序排列,显示出天然气为典型的有机成因.甲烷碳同位素组成,反映了其母质演化程度已处于成熟～高成熟阶段,且以高成熟阶段为主.  相似文献   

内蒙古兴安盟杜尔基岩体特征研究          下载免费PDF全文

丛利民  李国志 《甘肃地质》2008,(3):74-79

内蒙古兴安盟杜尔基岩体位于大兴安岭中南段,岩性主要为中—细粒二长花岗（斑）岩、中—粗粒二长花岗岩、细粒二长花岗岩。岩石化学分析结果属于碱性岩系列,具有高硅、高钾、富碱、过铝、贫铁、镁、钙特征。稀土元素总量平均值为112．43μg／g,球粒陨石标准化曲线整体平缓右倾,具有Eu负异常;微量元素蛛网图解表现为“W”型形态．具有明显的Sr、Ba、Ti负异常,反映了强烈的分离结晶作用存在。4个样品K-Ar全岩法测年结果为100．15-120．29Ma,说明岩体形成于早白垩世。反映杜尔基地区在早自垩世可能处于相对稳定的拉张环境。  相似文献   

河南桐柏围山城层控金银成矿带同位素地球化学   总被引：8，自引：2，他引：6  

张静  陈衍景  陈华勇  张冠  杨艳 《地学前缘》2008,15(4):108-124

河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

内蒙古敖包吐萤石矿床地质和地球化学特征   总被引：2，自引：0，他引：2  

许东青  聂凤军  江思宏  张万益  云飞  杨才  张天俊  吕旭光  林日亮 《地球学报》2008,29(4):440-450

笔者总结了敖包吐萤石矿床的地质特征,并通过萤石的稀土元素的地球化学和Nd同位素研究,探讨了该矿床的成矿作用和成矿物质来源。敖包吐萤石矿床产出于下二叠统大石寨组火山—沉积岩与燕山中期花岗岩的接触带,为单一萤石矿床。萤石矿石的稀土元素的含量(∑REE)变化范围为(8.04～30.04)×10-6,平均为19.42×10-6;轻重稀土LREE/HREE值0.24～0.65,平均0.52;LaN/YbN为0.07～0.62,平均0.26;δEu为0.42～0.90,平均0.60,具Eu负异常和明显重稀土富集的特征。岩矿石的Nd同位素研究表明,萤石矿石的εNd(t)都表现为很大的负值,以成矿主期年龄138Ma计算的εNd(138Ma)为-7.30～-30.55,具有古陆壳的演化特征,暗示其成矿的物质来源主要是壳源物质。在Moller的Tb/La-Tb/Ca成因判别图解中,敖包吐矿床的萤石的结晶作用表现为重新活化的趋势,反映流体具有混源的特征,既有热液成因,又有沉积成因。二叠世的海相火山活动通过海底喷气和喷流的作用形成了初始矿源层,而燕山中期花岗岩浆的侵位与结晶分异,又对初始矿源层的活化和富集提供了流体和热能的来源。成矿流体在经历了长期的演化后在大石寨组的构造薄弱破碎的的部位沉淀析出,形成敖包吐萤石矿床。  相似文献