青海祁漫塔格地区虎头崖矿床Ⅵ矿带花岗岩的成岩时代、地球化学特征和成因     

姚磊  吕志成  于晓飞  庞振山  蔡煜琦  刘鹏  刘长城  王凤兰 《吉林大学学报(地球科学版)》2015,45(3):743-758

利用LA-ICP-MS锆石U-Pb法,测得与成矿有关的青海祁漫塔格地区虎头崖矿床Ⅵ矿带花岗岩的成岩年龄为(233.6±1.8) Ma(MSWD=1.2,n=17)。地球化学特征显示:花岗岩属高钾钙碱性、弱过铝质花岗岩;样品的稀土元素组成以总体右倾,轻、重稀土分异明显和具明显的负铕异常为特征;微量元素具有富集Rb、Th、U、La、Nd等大离子亲石元素,亏损Ba、Sr、Nb、P、Ti等元素的特点。Sr-Nd同位素组成特征显示,花岗岩的源区可能是富集岩石圈地幔。初步研究认为,虎头崖矿床Ⅵ矿带花岗岩可能形成于中、晚三叠世碰撞后碰撞的构造背景下。  相似文献   

内蒙古白乃庙铜-金-钼矿床成矿机制——来自流体包裹体和He-Ar同位素的证据   总被引：1，自引：0，他引：1  

周振华  车合伟  欧阳荷根  马星华 《地质学报》2017,91(3):542-560

白乃庙铜-金-钼矿是华北板块北缘中段一个重要矿床,其矿化特征既显示斑岩型蚀变特征,同时又表现出明显的后期造山作用改造的特点。本次研究通过系统的流体包裹体显微测温、激光拉曼和气液相色谱分析揭示其成矿流体为中—低温、中低盐度的CO_2(CO)-H_2O-CH_4(C_2H_2+C_2H_4)-NaCl-CaCl_2体系,流体混合作用和CO_2逃逸为成矿主要因素。富还原性流体的存在可能促使气相流体携带大量的Cu、Au等成矿元素迁移至较远点的白乃庙群地层,沿着片理或裂隙沉淀成矿。对不同成矿阶段矿石中黄铁矿的He-Ar同位素组成测试结果显示白乃庙矿床黄铁矿流体包裹体的~3He/~4He比值在0.06~0.71Ra之间,~(40)Ar/~(36)Ar比值为375.5~1436.3,指示成矿体系由不同性质和组成的两个端元流体混合而成,即混入了类似于MORB型地幔端元的高温高盐度流体和富含地壳放射成因氦但具有空气氩同位素组成特征的低温大气降水。白乃庙矿床属受后期造山作用改造的斑岩型铜-金-钼矿床,形成于古亚洲洋板块持续向南俯冲背景。  相似文献   

北阿尔金白尖山地区花岗闪长岩锆石U-Pb定年、Hf同位素组成及其地质意义   总被引：2，自引：0，他引：2  

刘锦宏  刘良  盖永升  康磊  杨文强  廖小莹  杨敏 《地质学报》2017,91(5):1022-1038

白尖山花岗闪长岩位于北阿尔金红柳沟-拉配泉蛇绿混杂岩带东段,呈大套岩株状产出于拉配泉岩群之中。该花岗闪长岩具有较低的SiO_2含量(62.58%～65.05%),富CaO(4.02%～4.98%),铝饱和指数A/CNK1.0(0.89～0.98),富集K、Rb、Ba,亏损Nb、Ta、Zr、Ti,属于准铝质钙碱性岩石系列,具I型花岗岩的特征;其稀土元素∑REE=90.2～137.8μg/g,具有轻重稀土元素分馏明显,轻稀土元素相对富集的特点,具弱的Eu负异常(δEu_N=0.84～0.92)。该岩石变化范围较大的锆石Hf同位素组成(ε_(Hf)(t)=-2.96～7.99)可能与源区物质不充分的岩浆混染有关,结合地球化学特征及其与实验岩石学资料的对比,其形成应为洋壳俯冲时板片脱水诱发下地壳基性岩石部分熔融产生的初始岩浆结晶作用的产物,同时在岩浆侵位过程中还受到上地壳物质(杂砂岩等)的混染。锆石U-Pb年龄为475.2±2.0Ma,结合锆石CL图像具有岩浆环带特征和Th/U值(0.30～0.75),推断该年龄为花岗闪长岩的形成年龄。综合区域地质背景,本次研究的白尖山花岗闪长岩应为红柳沟-拉配泉蛇绿混杂岩带东部地区早古生代洋壳俯冲岛弧岩浆活动的组成部分,与西部红柳沟地区(恰什坎萨依及巴什考供盆地北缘)的花岗闪长岩和石英闪长岩共同构成北阿尔金早古生代洋壳俯冲产生的岛弧岩浆岩带。此外,由西到东红柳沟-拉配泉蛇绿混杂岩带的南北两侧均发育早古生代与洋壳俯冲有关的花岗质岩石,表明整个北阿尔金洋俯冲时期可能具有双向性。  相似文献   

南大巴山前陆冲断褶皱带断裂流体地球化学特征及构造保存研究     

周业鑫  丁俊  余谦  王剑  熊国庆  门玉澎  熊小辉  邓奇 《地质学报》2017,91(6):1169-1180

南大巴山前陆构造带位于城口断裂与铁溪-巫溪断裂之间,为研究该构造带断裂对烃类运移及构造对页岩气保存的影响,本文对该构造带内断裂流体的碳氧同位素和流体包裹体进行了测试分析。测试结果显示,研究区断裂流体碳氧同位素整体较围岩更为分散,δ~(13)C_(PDB)介于-2.9‰~3.9‰之间,属正常海相碳酸盐层的碳同位素值,坪坝断裂附近δ~(13)C_(PDB)呈明显亏损,具外来流体混合的特征。流体包裹体为含烃的气液二相盐水包裹体,气相成分为CH_4,液相为H_2O。包裹体均一温度以城口断裂附近最高,主要为311~336℃,频率峰值温度为328℃;往南叠瓦带流体均一温度主要位于183~269℃之间,峰值为230℃,断褶带峰值为213℃,滑脱褶皱带为170℃,整体表现为向盆内方向降低。盐度主要为4.43%~8.6%NaCl。研究表明,城口断裂作为大巴山构造带南北分界的主干断裂,古流体的形成温度和热演化程度最高,且从盆地向北至城口断裂,各构造带流体的热演化程度、成岩温度、古流体压力均逐渐升高,说明随着构造活动的增强,构造带中的流体更为活跃,持续时间更长,导致流体形成的深度和温度变化较大。构造带内的流体总体上形成于封闭体系,在主构造应力的驱动下,盆地深部含烃流体沿断裂向浅部运移,并与浅部地层流体发生混合,运移通道整体处于封闭状态;而构造带内的一些次级断裂,因其形成的时间以及向下延伸的深度不足以触及下古生界烃源岩层,因此其对流体封闭性的影响有限。  相似文献   

西藏多龙矿集区地堡铜(金)矿床年代学、流体包裹体、地球化学特征及其成因类型研究   总被引：3，自引：0，他引：3  

乔东海  赵元艺  汪傲  李玉彬  郭硕  李小赛  王松 《地质学报》2017,91(7):1542-1564

多龙矿集区位于班公湖-怒江成矿带西段北侧、羌塘地块南缘,是我国近年来发现的最大斑岩-浅成低温热液型Cu(Au)矿集区。地堡是多龙矿集区最西南边缘的矿床,资源潜力巨大,有望达到超大型规模,但研究程度薄弱。本次工作对地堡Cu(Au)矿开展了锆石U-Pb测年、流体包裹体、地球化学等方面的研究,为推动资源勘查和矿集区成矿规律的总结提供理论依据。含矿斑岩锆石206 Pb/238 U平均加权年龄为111.2±0.4Ma(MSWD=0.67),与矿集区成矿岩浆活动时限一致,是矿集区重要组成部分。石英脉流体包裹体显示矿床主成矿期成矿流体温度集中于140~382℃,主要集中在240~280℃。成岩阶段石英斑晶中Ⅰ型包裹体盐度范围为0.2%~20.7%NaCleqv.,含盐子晶包裹体盐度为33.6%NaCleqv.和43.9%NaCleqv.;成矿阶段不含石膏石英脉Ⅰ型包裹体盐度范围为0.2%~20.8%NaCleqv.,黄铁矿石英脉Ⅰ型包裹体盐度范围为1.1%~11.1%NaCleqv.,石膏中Ⅰ型包裹体盐度范围为0.5%~9.3%NaCleqv.。对钻孔DNZK6428样品进行主微量元素测试并进行因子分析计算,结果表明F1、F2、F3代表成岩阶段,因子主成分为Y-Ho-Er-Tm-Yb-Dy-Lu-Tb-Eu-Gd-Sm-La-Ce-Pr-Nd-SiO_2-Al_2O_3-CaO等,F4和F5代表铜金矿化阶段,因子主成分为Sn-Sb-Ba-Fe_2O_3-Sr-|SiO_2|-Ni-Cu-U-In-Cd-Au-Zn。黄铁矿δ34SV-CDT值总体较为集中,呈"双峰塔式"分布,变化范围为-7.8‰~4.1‰,均值为-4.23‰,为深源岩浆硫,硫的来源接近地幔硫。矿床粒状黄铁矿Co/Ni比值为0.207~10.775,平均值4.39,脉状黄铁矿Co/Ni比值为0.353~23.155,平均值3.802,均为热液成因。矿相学与岩相学研究结果显示矿床具明矾石和硫砷铜矿典型高硫化浅成低温热液矿床的矿物组合,地堡Cu(Au)矿为高硫型浅成低温热液矿床。  相似文献   

青海牛鼻子梁镍矿勘查区闪长岩U-Pb年代学、地球化学及Hf同位素研究   总被引：2，自引：0，他引：2  

李睿华  孙丰月  李良  白宜娜  王飞  姜和芳  禹禄 《地质学报》2017,91(10):2273-2284

本文对牛鼻子梁镁铁质-超镁铁质杂岩体中产出的闪长岩进行了详细的U-Pb年代学、岩石地球化学和Hf同位素分析,以便对岩石的成因及南祁连造山带对柴达木盆地的俯冲效应予以研究。闪长岩中锆石LAICP-MS U-Pb定年结果表明,闪长岩的形成时代为361±3 Ma(MSWD=0.049),即晚泥盆世。岩石地球化学方面,SiO_2含量为53.44%~58.27%,Na_2O+K_2O为4.80%~6.39%,K_2O/Na_2O比值为0.33~0.97,显示出富钠的特征,岩石由钙碱性序列向高钾钙碱性序列过渡。微量元素原地地幔标准化蛛网图上显示相对富集大离子亲石元素(Rb、K)及轻稀土,相对亏损高场强元素(Ta、Nb、Zr),同时Th含量介于2.03×10~(-6)~6.57×10~(-6)之间,Th/Ta比值为2.73~12.82之间,显示为壳幔混染作用的产物,另外据闪长岩中发现的辉长岩包体也表明了壳幔岩浆的混合。闪长岩Hf同位素显示,岩石的ε_(Hf)(t)值和二阶段模式年龄(TDM2)分别介于±6.41~±9.36和714~878Ma之间。上述结果表明,岩体的原始岩浆是一种幔源物质为主,混合新生陆壳部分熔融的产物。综合区域岩石构造背景的研究,认为牛鼻子梁闪长岩岩体形成于南祁连向柴达木板块俯冲碰撞后伸展的环境。  相似文献   

Primary diagenetic copper carbonate at the Malbunka copper deposit,Amadeus Basin,Northern Territory,Australia     

《Ore Geology Reviews》2017

The Malbunka copper deposit, located about 220 km west of Alice Springs, in the Northern Territory of Australia, may be a rare example of primary formation of copper carbonate mineralization. This deposit consists of unusual azurite disks up to 25 cm diameter, and lesser amounts of secondary azurite crystals and malachite. Carbon isotope values of the copper carbonate minerals are consistent with formation from groundwater-dissolved inorganic carbon. Oxygen isotope thermometry formation temperature estimates are 5–16 °C above ambient temperatures, suggesting the copper carbonates formed at a depth between 0.3 and 1.6 km in the Amadeus Basin. Azurite fluid inclusion waters are rich in boron, chlorine, and other elements suggestive of dilute oil basin formation fluids. In addition, presence of euhedral tourmaline with strong chemical zonation suggest that this was a low temperature diagenetic setting. The strong correlation of structures associated with hydraulic fracturing and rich copper carbonate mineralization suggest a strongly compartmentalized overpressure environment. It is proposed that copper carbonates of the Malbunka deposit formed when deep, copper-rich formation fluids were released upward by overpressure-induced failure of basin sediments, permitting mixing with carbonate-rich fluids above. This work bears directly upon exploration for a new type of primary copper deposit, through understanding of the conditions of genesis.  相似文献   

Metallogenic age and hydrothermal evolution of the Jidetun Mo deposit in central Jilin Province,northeast China: Evidence from fluid inclusions,isotope systematics,and geochronology     

《Ore Geology Reviews》2017

The Jidetun deposit is a large porphyry Mo deposit that is located in central Jilin Province, northeast China. The Mo mineralization occurs mainly at the edge of porphyritic granodiorite, as well as the adjacent monzogranite. Field investigations, cross-cutting relationships, and mineral paragenetic associations indicate four stages of hydrothermal activity. To determine the relationships between mineralization and associated magmatism, and better understand the metallogenic processes in ore district, we have undertaken a series of studies incluiding molybdenite Re–Os and zircon U–Pb geochronology, fluid inclusions microthermometry, and C–H–O–S–Pb isotope compositions. The molybdenite Re–Os dating yielded a well-defined isochron age of 168.9 ± 1.9 Ma (MSWD = 0.34) that is similar to the weighted mean ²⁰⁶Pb/²³⁸U age of 173.5 ± 1.5 Ma (MSWD = 1.8) obtained from zircons from the porphyritic granodiorite. The results lead to the conclusion that Mo mineralization, occurred in the Middle Jurassic (168.9 ± 1.9 Ma), was spatially, temporally, and genetically related to the porphyritic granodiorite (173.5 ± 1.5 Ma) rather than the older monzogranite (180.1 ± 0.6 Ma). Fluid inclusion and stable (C–H–O) isotope data indicate that the initial H₂O–NaCl fluids of mineralization stage I were of high-temperature and high-salinity affinity and exsolved from the granodiorite magma as a result of cooling and fractional crystallization. The fluids then evolved during mineralization stage II into immiscible H₂O–CO₂–NaCl fluids that facilitated the transport of metals (Mo, Cu, and Fe) and their separation from the ore-bearing magmas due to the influx of abundant external CO₂ and heated meteoric water. Subsequently, during mineralization stage III and IV, increase of pH in residual ore-forming fluids on account of CO₂ escape, and continuous decrease of ore-forming temperatures caused by the large accession of the meteoric water into the fluid system, reduced solubility and stability of metal clathrates, thus facilitating the deposition of polymetallic sulfides.  相似文献   

A comparison of Jiaojia- and Linglong-type gold deposit ore-forming fluids: Do they differ?     

《Ore Geology Reviews》2017

The Jiaodong peninsula contains the most important concentration of gold deposits in China, which can be divided into Jiaojia-type and Linglong-type deposits based on mineralization style. The former is characterized by disseminated- and stockwork-style mineralization hosted in first-order regional faults, with relatively larger tonnages and lower gold grades. The latter is characterized by massive auriferous quartz veins commonly hosted in subsidiary second- or third-order faults, with smaller tonnage but higher grade orebodies. Despite these differences, both groups of deposits have the same alteration assemblages, mineral paragenesis, element concentrations, and ore-forming ages.The mainly Jiaojia-type Luoshan gold deposit and the mainly Linglong-type Fushan gold deposit are characterized by H-O-S-Pb isotope data that indicate the ore-forming fluids have a dominantly metamorphic source. The fluids were derived during the Yanshanian orogenic event, and were most likely associated with dehydration and decarbonization processes near the top of the subducting paleo-Pacific plate. The Linglong-type ores have relatively lighter calculated δ¹⁸O compositions (−3.9 to −2.3‰) than the Jiaojia-type ores (0.3–8.0‰), possibly because of a greater degree of mixing with meteoric water. Petrographic, cathodoluminescence, microthermometric, and laser Raman spectroscopic analyses of fluid-inclusion assemblages in quartz from the two types of ores indicate fluids were similar, in both cases characterized by medium–high homogenization temperatures (211–393 °C), significant CO₂ (∼15% mol), minor CH₄ (⩽18% in the carbonic phase), and low salinity (⩽11.2 wt% NaCl eq.). The Linglong-type ores, however, have a wider range of CO₂ and CH₄ concentration and salinity than the Jiaojia-type ores. Fluid immiscibility, occurred in main ore stage of both ore types, with the trapping conditions of 77–185 MPa and 284–328 °C, although the unmixing is more intense and widespread in the Linglong-type ores. Both fluid-wallrock interaction and fluid immiscibility are important gold-deposition processes in the two types, but immiscibility is more important in the Linglong-type ores and that has led to the typical higher gold grade.In general, there is little geochemical differences between the ore-forming fluids for Jiaojia- and Linglong-type gold deposits. Both Jiaojia- and Linglong-type ores can exist in a single deposit and form in the same metallogenic event. The Linglong-type ores developed as more massive veins, because of their location in zones of more extensive extension and they lack significant post-ore cataclastic deformation.  相似文献   

Early Cretaceous porphyry copper mineralization in Northeast China: the Changfagou example     

Yong Zhang  Shu–Wen Xing  Chao Li  Shi–Fu Liang  Zheng–Tao Yu  Xiao–Hui Du 《International Geology Review》2017,59(2):185-203

The Changfagou Cu deposit is a newly discovered porphyry deposit located in the southern Jilin Province of Northeastern China, on the northeastern margin of the North China Craton. To better understand the formation of the Cu deposit, we report the zircon U–Pb and molybdenite Re–Os dating, and Sr-, Nd-, and Hf- isotopic data of the granite porphyry. LA-ICP-MS dating of zircon grains from two mineral zones in the granite porphyry yield ages of 115.7 ± 0.8 and 115.3 ± 0.6 Ma, which is interpreted as the emplacement age of the granite porphyry. The molybdenite Re–Os model ages of 112.5 to 113.8 Ma, an isochron age of 113.3 ± 1.3 Ma, and a weighted mean model age of 113.0 ± 0.7 Ma, which represents the age of the Cu mineralization quite well. The Changfagou granite porphyry samples lack amphibole and muscovite, and are compositionally characterized by high SiO₂, high Na₂O+K₂O, and low P₂O₅, enriched in some Rb, Th, U, and Pb, and depleted in Nb, Ta, Ti, P, and Eu. Mineralogical and geochemical features suggest that the Changfagou granite porphyry samples are slightly peraluminous and are of highly fractionated I-type granitoids. The granitic rocks also have relatively high (⁸⁷Sr/⁸⁶Sr)_i (0.71199 to 0. 71422), and both low εNd(t) (?14.56 to ?13.19) and εHf(t) values (?14.916 to ?8.644), which suggest that Changfagou granite porphyry are derived from mixed sources of crustal and mantle, and diagenesis and mineralization were possibly related to the switch in subduction direction of the Palaeo-Pacific Plate in the late phase of Early Cretaceous.  相似文献