以DDTC为螯合剂反相HPLC法分离测定铜钴镍汞     

赵芳石  李俊峰  郑荣华 《吉林大学学报(地球科学版)》1988,(2)

本文研究了用ODS柱对DDTC与Cu、Co、Ni、Hg四种重金属离子螯合物的分离测定方法。经过对流动相及其配比、波长、柱温、压力、流速等色谱条件进行的选择,对共存离子影响的分析,确定了最佳分离分析条件。以58:42(v:y)的乙醇水溶液作流动相在R.P.柱上分离,于254nm处检测。在0.0064～1.Oμg/ml(Cu),0.0064～1.0μg/ml(Co),0.0032～1.0μg/ml(Ni),0.010～1.0μg/ml(Hg)浓度范围内,线性关系良好。对含量在线性范围内的天然水样和人尿样进行了分析测定,回收率在97.0～109.0％之间,变异系数不超过5.6％,结果较好。  相似文献   

帕米尔及其邻近地区大震活动与环境因子的关系     

叶民权  白超英 《内陆地震》1990,4(1):13-20

本文讨论了太阳黑子活动,地球自转运动。大气降水和气压等环境因子与帕米尔及其邻近地区(新疆部分)大震活动的关系,进行了相关统计分析,在α=0.05置信水平的统计检验是显著的。认为,环境因子与大震活动存在着较好的相关关系,地震的孕育不仅是由于地壳内部应力的积累和调整,而且还有地球外部的地震环境因子的调制和触发作用。  相似文献   

绿泥石片岩和斜长角闪岩在高温高压下的物理力学性质及其应用   总被引：5，自引：1，他引：5       下载免费PDF全文

高平  刘若新 《地震地质》1994,16(1):83-88

在高温高压下绿泥石片岩和斜长角闪岩中含水矿物的脱水作用可以引起岩石物理力学性质的异常变化。在半封闭条件下，含水矿物的脱水温度有随压力增加而降低的趋势。脱水作用可能是华北地区壳内低速高导层（体）的形成原因之一。这一低速高导层（体）同时也是低强度的软弱层（体），有利于地震在其上覆脆性岩层中的孕育与发生  相似文献   

冀东高级变质岩石的流体包裹体研究   总被引：5，自引：5，他引：5  

刘树文 《岩石学报》1995,11(4):375-385

冀东高级变质的石榴石斜长片麻岩、含或不含石榴石的角闪二辉斜长片麻岩、紫苏花岗岩、斜长角门岩等岩石中的流体包裹体主要有４类，按形成的先后顺序依次为：（１）Ｈ２Ｏ和ＣＯ２两液相包裹体，ＣＯ２的部分均一温度是－１２℃，密度１．０４ｇ／ｃｍ３，Ｈ２Ｏ含量２１％～３９％（ｍｏｌｅ％），ＣＯ２含量５０％～７１％（ｍｏｌｅ％）；（２）ＣＯ２液相包裹体，冰点温度－５６℃～－６１℃，均一温度－７．４℃～－３５．１℃，ＣＯ２密度约为１．０５ｇ／ｃｍ３，ＣＯ２含量８２．１％～９８．４％（ｍｏｌｅ％），还有少量的ＣＨ４、Ｎ２和Ｈ２等组分；（３）Ｈ２Ｏ和ＣＯ２多相包裹体，ＣＯ２的部分均一温度７℃～２８℃，ＣＯ２密度为０．６４～０．９３ｇ／ｃｍ３，气相组分以ＣＯ２、ＣＨ４和ＣＯ为主，液相成分主要是Ｈ２Ｏ和ＣＯ２；（４）多世代盐水溶液包裹体，冰点温度－０．５℃～－２０℃，盐度０．８７％～２２．８％（ｗｔ％），盐水密度０．７～１．０５ｇ／ｃｍ３，均一温度在１５０℃～２００℃和约３００℃，存在两个峰值。不同世代的流体包裹体记录了等密度降温的Ｐ－Ｔ路径。包裹体反映的变质作用早期降温过程流体的Ｈ２Ｏ／Ｈ２Ｏ＋ＣＯ２（ｍｏｌｅ）比值降低，晚期升高  相似文献   

Interpretation of Holocene lake-level change from diatom assemblages in Lake Sidi Ali,Middle Atlas,Morocco   总被引：1，自引：0，他引：1  

P. A. Barker  N. Roberts  H. F. Lamb  S. van der Kaars  A. Benkaddour 《Journal of Paleolimnology》1994,12(3):223-234

While palaeohydrological changes in non-outlet lakes provide a key proxy indicator of past climatic fluctuations, for lake systems which have been chemically insensitive, it is necessary to use indicators of water depth rather than salinity to reconstruct their hydro- climatic histories. A study of diatoms in the modern sediments of Sidi Ali, a non-outlet lake in the Middle Atlas of Morocco, has shown a statistically significant correlation between water depth and the ratio of planktonic to littoral diatoms. This relationship is used to calibrate fossil diatom assemblages from a lake sediment core from the same lake to provide a quantitative index of water levels over the pastc. 6500 years. Palaeoecological evidence suggests that climatically induced hydrological variations have dominated the bulk of the mid-late Holocene lake sediment record, with significant human-induced catchment disturbance only occurring during the twentieth century. The pattern of water depth fluctuations suggests that the response time of the regional groundwater system to climatic forcing is <100 years.This is the third in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.  相似文献   

随县-西安剖面地壳结构的初步研究   总被引：3，自引：0，他引：3       下载免费PDF全文

丁韫玉  曹家敏  黄长林  蒋国芳 《地球物理学报》1987,30(1):31-38

本文对随县-西安测线的地震测深资料进行了初步分析,讨论了该剖面地壳内主要界面的震相特征。通过对观测走时的分层反演及综合反演,得到三层的地壳模型。地壳的平均速度为6.33km/s,厚度约34km,上地幔顶部的速度为8.10km/s。下地壳是由高速及低速层交替构成,高速层的速度为7.39km/s。构制了主要界面的剖面起伏图,并进行了讨论。  相似文献   

Y—Ba—Cu—O系高Tc超导材料的电子衍射分析     

吴秀玲  赵文霞 《地球科学》1989,14(4):407-412

  相似文献   

关于我国高技术开发区建设与布局的几个问题   总被引：5，自引：0，他引：5  

陈汉欣 《地理学报》1989,44(4):400-406

本文简要阐述了高技术对推动国民经济发展的重要作用，指出了我国建立高技术开发区的必要性，可能性及其战略思想，并提出了分三个层次布局的建设方案。  相似文献   

Thermal diffusivity of garnets at high temperature     

Anne M. Hofmeister 《Physics and Chemistry of Minerals》2006,33(1):45-62

Thermal diffusivity (D) of garnets with diverse chemical compositions was measured using the laser-flash technique, which is accurate (±2%) and isolates the lattice component from direct radiative transfer. Temperatures ranged from ~290 to ~1,600 K (unless limited by melting). Seven synthetic (e.g., YAG, GGG) and 15 natural garnets with two types of ionic substitution [Ca₃(Fe,Al)₂Si₃O₁₂ and (Mg,Fe,Ca)₃Al₂Si₃O₁₂] and varying amounts of OH^- were examined. Cation substitution or hydroxyl incorporation lowers D from end-member values. Thermal diffusivity is constant once the temperature (T) exceeds a critical value (T _sat) of ~1,100 to 1,500 K. From ~290 K to T _sat, the measurements are best represented by 1/D=A+BT+CT ² where A, B, and C are constants. These constants vary little among diverse chemical compositions, suggesting that the oxygen sublattice controls heat transport. Higher order terms are needed only when T _sat is low, such as Ant Hill garnet wherein 1/D=0.049403+0.0032299T−2.3992T ²×10⁻⁶+6.0168T ³×10⁻¹⁰(1/D in s/mm²; T in K). The mean free path (λ, computed from D and sound velocities) is slightly larger than the lattice parameter above T _sat, in accord with phonon–phonon interactions requiring non-localized modes. At most temperatures, λ is nm-sized. Large values of λ are obtained by extrapolation to a few Kelvins, suggesting that boundary scattering can only be important at extremely cold temperatures. The observed behavior with T and chemical composition is consistent with the damped harmonic oscillator model. Phonon transport is best represented by inverse thermal diffusivity wherein 1/D goes as T ⁿ where n is between 1 and 3 up to ~200 K, depends on a quadratic or cubic polynomial at moderate T, but is constant above T _sat. The predicted and observed temperature response of 1/D mimics the well-known form for heat capacity, in that acoustic modes control heat transport near cryogenic temperatures, optic phonons dominate above ambient temperature, and a limit analogous to that of Dulong and Petit is reached at very high temperature, due to full population of discrete phonon states.  相似文献   

Seismic imaging of the transitional crust across the northeastern margin of the South China Sea   总被引：23，自引：0，他引：23  

Tan K. Wang  Ming-Kai Chen  Chao-Shing Lee  Kanyuan Xia 《Tectonophysics》2006,412(3-4):237-254

Crustal structure across the passive continental margin of the northeastern South China Sea (SCS) is presented based on a deep seismic survey cooperated between Taiwan and China in August 2001. Reflection data collected from a 48-hydrophone streamer and the vertical component of refraction/reflection data recorded at 11 ocean-bottom seismometers along a NW–SE profile are integrated to image the upper (1.6–2.4 km/s), lower (2.5–2.9 km/s), and compacted (3–4.5 km/s) sediment, the upper (4.5–5.5 km/s), middle (5.5–6.5 km/s) and lower (6.5–7.5 km/s) crystalline crust successively. The velocity model shows that the thickness (0.5–3 km) and the basement of the compacted sediment are strongly varied due to intrusion of the magma and igneous rocks after seafloor spreading of the SCS. Furthermore, several volcanoes and igneous rocks in the upper/middle crust (7–10 km thick) and a high velocity layer (0–5 km thick) in the lower crust of the model are identified as the ocean–continent transition (OCT) below the lower slope in the northeastern margin of the SCS. A thin continent NW of the OCT and a thick oceanic crust SE of the OCT in the continental margin of the northeastern SCS are also imaged, but these transitional crusts cannot be classified as the OCT due to their crustal thickness and the limited amount of the volcano, the magma and the high velocity layer. The extended continent, next to the gravity low and a sag zone extended from the SW Taiwan Basin, may have resulted from subduction of the Eurasian Plate beneath the Manila Trench whereas the thick oceanic crust may have been due to the excess volcanism and the late magmatic underplating in the oceanic crust after seafloor spreading of the SCS.  相似文献