汝城地区晚中生代火山岩地球化学特征及其对源区属性的指示   总被引：4，自引：0，他引：4  

李超文  王岳军  郭锋  彭头平  喻晓彬 《大地构造与成矿学》2002,26(4):354-362

湘东南汝城地区发育一套由基性玄武岩和中酸性安山质-英安质岩石组成的火山岩建造,属于低钾拉斑系列,该火山岩系中两个玄武岩的K-Ar年龄分别为124.5±2.5Ma和127.6±1.9Ma,属晚侏罗—早白垩世产物。在主、微量元素上两者成分存在明显差异。其中安山质-英安质岩石具有高MgO特征,属高MgO岩石,LILE富集、Nb-Ta、Sr-P亏损强烈,(La/Yb)N=6.7～7.9,Eu*/Eu=0.74～0.85,具岛弧型微量元素配分型式,87Sr/86Sr(t)=0.71079～0.71118,εNd(t)=-7.64～-8.16,与adakites高Mg岩石有着明显的差别,可能是富集岩石圈地幔熔融后直接分异的产物;玄武岩LILE富集,Nb-Ta富集,(La/Yb)cn=4.0～4.3,Eu*/Eu=1.00～1.16,具OIB型微量元素配分型式,87Sr/86Sr(t)=0.70812～0.70832,εNd(t)=0.48～1.03,其源区具二元混合趋势,其源区可能是富集型岩石圈地幔端员与亏损的软流圈地幔端员的混合产物。汝城地区晚中生代玄武岩和高Mg安山质-英安质岩石源区属性的限定及其相互的空间依存关系表明该区晚中生代时有着较薄的岩石圈厚度,处于岩石圈伸展减薄的大地构造背景。  相似文献   

Viscosity of albite melt at high pressure and high temperature     

A. Suzuki  E. Ohtani  K. Funakoshi  H. Terasaki  T. Kubo 《Physics and Chemistry of Minerals》2002,29(3):159-165

 The viscosity of albite (NaAlSi₃O₈) melt was measured at high pressure by the in situ falling-sphere method using a high-resolution X-ray CCD camera and a large-volume multianvil apparatus installed at SPring-8. This system enabled us to conduct in situ viscosity measurements more accurately than that using the conventional technique at pressures of up to several gigapascals and viscosity in the order of 10⁰ Pa s. The viscosity of albite melt is 5.8 Pa s at 2.6 GPa and 2.2 Pa s at 5.3 GPa and 1973 K. Experiments at 1873 and 1973 K show that the decrease in viscosity continues to 5.3 GPa. The activation energy for viscosity is estimated to be 316(8) kJ mol⁻¹ at 3.3 GPa. Molecular dynamics simulations suggest that a gradual decrease in viscosity of albite melt at high pressure may be explained by structural changes such as an increase in the coordination number of aluminum in the melt. Received: 6 January 2001 / Accepted: 27 August 2001  相似文献   

In situ X-ray observations of the decomposition of brucite and the graphite–diamond conversion in aqueous fluid at high pressure and temperature     

T. Okada  W. Utsumi  H. Kaneko  M. Yamakata  O. Shimomura 《Physics and Chemistry of Minerals》2002,29(7):439-445

 An experimental technique to make real-time observations at high pressure and temperature of the diamond-forming process in candidate material of mantle fluids as a catalyst has been established for the first time. In situ X-ray diffraction experiments using synchrotron radiation have been performed upon a mixture of brucite [Mg(OH)₂] and graphite as starting material. Brucite decomposes into periclase (MgO) and H₂O at 3.6 GPa and 1050 °C while no periclase is formed after the decomposition of brucite at 6.2 GPa and 1150 °C, indicating that the solubility of the MgO component in H₂O greatly increases with increasing pressure. The conversion of graphite to diamond in aqueous fluid has been observed at 7.7 GPa and 1835 °C. Time-dependent X-ray diffraction profiles for this transformation have been successfully obtained. Received: 17 July 2001 / Accepted: 18 February 2002  相似文献   

The preservation of high-pressure rocks during exhumation: metagranites and metapelites     

Alexander Proyer 《Lithos》2003,70(3-4):183-194

Metagranites in the NKFMASH system require external hydration during prograde high-pressure metamorphism in order to equilibrate to ambient HP conditions by producing more siliceous muscovite. Any lack of external fluid or the disappearance of biotite stops re-equilibration and thus prevents recording of high-pressure conditions. The same hydration reactions cause dehydration during exhumation. Orthogneiss from shear zones or adjacent to metapelites and metabasites will take up external fluid during subduction and record the highest P–T conditions, but will also be the first to dehydrate upon exhumation, now hydrating other lithologies and probably refuelling shearzones.

The (de)hydration behavior of Ca-bearing metagranitoids is similar to that in the Ca-free system. However, the anorthite component of plagioclase decomposes with increasing pressure to form either (clino)zoisite or a grossular-rich garnet. Both reactions are fluid-consuming. If H₂O is supplied from an external source, the garnet-bearing assemblage can record P–T conditions up to very high pressures, but dehydrates again during heating and/or decompression to form a more Fe-rich garnet and Al-rich mica(s). The garnet compositions observed in natural HP-metagranites are mostly too Fe-rich to be formed in the presence of an H₂O-rich fluid.

N(C)KFMASH metapelites generally have a more complex mineralogy and succession of mineral assemblages along a P–T path. The H₂O contained in hydrous silicates like chlorite and chloritoid is only partly released, but partly transferred to other minerals like paragonite, glaucophane or phengite during subduction and further dehydration during exhumation is common. The mineral assemblage preserved by the rock may then record P–T conditions way below those of the actual pressure and temperature peak of the path. Contouring of the P–T pseudosection of a specific metapelite composition with mode isopleths for H₂O shows which P–T conditions along a given path are the ones most likely recorded by the rock.  相似文献   

藏南定结淡色花岗岩--基底隆升降压熔融成因的地质证据   总被引：6，自引：0，他引：6  

张金阳  廖群安 《西北地质》2004,37(2):7-12

西藏南部定结地区高喜马拉雅结晶基底中淡色花岗岩体紧靠藏南拆离断层内部产出．野外地质和岩相学特征显示其为S型、分两期侵入的淡色花岗岩体——早期的黑云母淡色花岗岩和晚期的白云母淡色花岗岩。基底副变质岩中广泛分布淡色花岗岩脉体．在基底副变质岩中的淡色花岗岩脉体中发现紫苏辉石暗色麻粒岩残留体，这表明本区高喜马拉雅淡色花岗岩源岩为基底副变质岩，且基底副变质岩是在基底快速隆升降压的条件下发生缺水熔融生成的淡色花岗岩岩浆。  相似文献   

高精度电磁频谱法在滇东煤层气勘探中的应用   总被引：2，自引：0，他引：2  

周仁安  桂宝林  王朝栋  郭自任 《云南地质》2004,23(4):515-520

使用高精度电磁频谱探测方法,对滇东恩洪、老厂地区的煤层气作实地探测。取得煤系地层中的地球物理响应。由此建立煤层、围岩的岩性与物性的关系,进而利用大地电磁频谱探测技术了解煤层的埋深、厚度。使煤层气的勘探工作有了新的科学勘探技术方法。  相似文献   

Ab initio elasticity of FeS2 pyrite from 0 to 135 GPa     

Y. Le Page  J. R. Rodgers 《Physics and Chemistry of Minerals》2005,32(8-9):564-567

Polynomial expressions for the elastic tensor coefficients, the bulk, the shear and Young’s moduli, the speed of sound for longitudinal and transverse waves, the equation of state and the x coordinate of the sulfur atom in pyrite are reported based on ab initio calculations in the range of 0–135 GPa. Comparison with published experimental data indicates good agreement for the equation of state and for values at 0 GPa as well as reasonable agreement for first derivatives. All modeling and interpretation was performed with Materials Toolkit v.2.0 and all ab initio computations with VASP.  相似文献   

Effects of defect and pressure on the thermal expansivity of Fe x O     

Jianzhong Zhang  Yusheng Zhao 《Physics and Chemistry of Minerals》2005,32(4):241-247

Pressure–volume–temperature measurements have been carried out using synchrotron X-ray diffraction for wüstite at static pressures of 1.9, 2.6, and 5.4 GPa. Our results revealed that the composition change of wüstite and, hence, rearrangements of defect structures are primarily caused by the magnetite (Fe₃O₄) exsolution at temperatures of 523–723 K. Based on the isobaric volume–temperature data collected during cooling, the contribution of compositional variations to the unit-cell volumes of wüstite in the ranges of 300–673 K and 723–1073 K is negligibly small, within the experimental uncertainties. These observations suggest that the measured volume changes in the range of 300–673 K and 723–1,073 K can be attributed to the metal–oxygen bond expansion. Owing to the magnetite exsolution, thermal expansion data are obtained in each experiment at 1.9, 2.6, and 5.4 GPa for wüstite of two different compositions, Fe_0.987O and Fe_0.942O. At all three pressures, Fe_0.942O shows a thermal expansion that is about 30% larger than Fe_0.987O. Such findings represent the first experimental evidence of a substantial effect of nonstoichiometry on thermal expansivity, and based on previous thermodynamic calculations of the defect formation and interaction, this effect is likely associated with the distinct defects arrangements in iron-rich and more iron-deficient wüstite. This study also presents thermal equations of state for wüstite of two different compositions. Such volume-related properties at high temperatures are experimentally difficult to obtain in wüstite but important for thermodynamic studies in the binary Fe–O system.  相似文献   

High field strength element ratios in Archean basalts: a window to evolving sources of mantle plumes?   总被引：19，自引：0，他引：19  

Kent C. Condie   《Lithos》2005,79(3-4):491-504

In terms of high field strength element ratios Nb/Th, Zr/Nb, Nb/Y and Zr/Y, most basalts from non-arc type Archean greenstones are similar to oceanic plateau basalts, suggestive of mantle plume sources. A large number of these basalts have ratios similar to primitive mantle composition. Perhaps the Archean mantle was less fractionated than at present and “primitive mantle” comprised much of the deep mantle and made a significant contribution to mantle plumes. The near absence of Archean greenstone basalts similar to NMORB in composition is also consistent with a relatively unfractionated mantle in which a shallow depleted source (DM) was volumetrically insignificant. The element ratios in basalts also indicate the existence of recycled components (HIMU, EM1, EM2) in the mantle by the Late Archean. This suggests that oceanic lithosphere was recycled into the deep mantle and became incorporated in some mantle plumes by the Late Archean. High field strength element ratios also indicate an important contribution of continental crust or/and subcontinental lithosphere to some non-arc Archean greenstone basalts. This implies that at least thin continental lithosphere was relatively widespread in the Archean.  相似文献   

Assessment of geomorphic hazards in connection with permafrost occurrence in the Zugspitze area (Bavarian Alps, Germany)   总被引：1，自引：0，他引：1  

Martin Gude  Dietrich Barsch 《Geomorphology》2005,66(1-4):85

In the Zugspitze area (Bavarian Alps, Germany), permafrost conditions are present in limestone bedrock and in regolith. Distribution is strongly dependent on topography in the east–west oriented mountain crest with steep north- and south-facing slopes. Numerous structures mainly for tourist purposes (cable car and recreation buildings, ski-lift masts, rack-railway tunnel, tunnel with supply facilities) are situated in the area, and several of them are placed on ground with permafrost. Results from a temperature measurement programme and distribution modelling show that for some of these constructions, the effects of permafrost degradation have to be considered in terms of stability of the foundations.The permafrost limit is close to the summit crest, and therefore, stability evaluations for the constructions in this area have to bear in mind the possible warming or even melting of ice within the bedrock crevasses caused by climate warming. Stability of the foundations as well as stability of rock walls in this area will probably be affected by a shifting of the permafrost limit. Constructions in the Zugspitzplatt area are already affected by the melting ground ice, and stabilizing measures have to be evaluated for several foundations where subsidence is likely to occur.Besides the local results, the study provides for the first time data on permafrost distribution in the northern Alpine margin based on standard methods of BTS measurements and numerical modelling.  相似文献