Polymorphic phase transition in Superhydrous Phase B     

M. Koch-Müller  P. Dera  Y. Fei  H. Hellwig  Z. Liu  J. Van Orman  R. Wirth 《Physics and Chemistry of Minerals》2005,32(5-6):349-361

We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction, Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures (down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering occurs not only at the Mg sites but also at the hydrogen sites.  相似文献   

北方农牧交错带退耕还林还草经济政策优化调控   总被引：4，自引：0，他引：4  

甘超华  马礼  南秋菊 《地域研究与开发》2005,24(4):66-69

退耕还林还草作为北方农牧交错带生态重建的切入点,在实际操作中也不可避免地存在一定的问题。文章对当前退耕还林还草的社会经济特征、政策安排、协调机制及制约因素进行了分析。提出:区域粮食适度自给定位、部门协调机制创新、产权制度改革、区域产业专业化分工、适度生态移民及建立生态补偿机制为进行政策优化调控的主要途径。  相似文献   

Nine thousand years of upper montane soil/vegetation dynamics from the summit of Caratuva Peak,Southern Brazil     

《Journal of South American Earth Sciences》2014

Biodiversity loss, climate change, and increased freshwater consumption are some of the main environmental problems on Earth. Mountain ecosystems can reduce these threats by providing several positive influences, such as the maintenance of biodiversity, water regulation, and carbon storage, amongst others. The knowledge of the history of these environments and their response to climate change is very important for management, conservation, and environmental monitoring programs. The genesis of the soil organic matter of the current upper montane vegetation remains unclear and seems to be quite variable depending on location. Some upper montane sites in the very extensive coastal Sea Mountain Range present considerable organic matter from the late Pleistocene and other from only the Holocene. Our study was carried out on three soil profiles (two cores in grassland and one in forest) on the Caratuva Peak of the Serra do Ibitiraquire (a sub-range of Sea Mountain Range – Serra do Mar) in Southern Brazil. The δ¹³C isotopic analyses of organic matter in soil horizons were conducted to detect whether C₃ or C₄ plants dominated the past communities. Complementarily, we performed a pollen analysis and ¹⁴C dating of the humin fraction to obtain the age of the studied horizons. Except for a short and probably drier period (between 6000 and 4500 cal yr BP), C₃ plants, including ombrophilous grasses and trees, have dominated the highlands of the Caratuva Peak (Pico Caratuva), as well as the other uppermost summits of the Serra do Ibitiraquire, since around 9000 cal yr BP. The Caratuva region represents a landscape of high altitude grasslands (campos de altitude altomontanos or campos altomontanos) and upper montane rain/cloud forests with soils that most likely contain some organic matter from the late Pleistocene, as has been reported in Southern and Southeastern Brazil for other sites. However, our results indicate that the studied deposits (near the summit) are from the early to late Holocene, when somewhat wetter and warmer conditions (since around 9000 cal yr BP) enabled a stronger colonization of the ridge of Pico Caratuva by mainly C₃ plants, especially grassland species. However, at the same time, even near the summit, the soil core from the forest site already presented the current physiognomy (or a shrubby/elfin or successional forest), indicating that the colonization of the neighboring uppermost saddles and valleys were probably populated mainly by upper montane forest species.  相似文献   

Investigation of the elevation of saltwater wedge due to subsurface dams     

Qinpeng Chang  Tianyuan Zheng  Youyuan Chen  Xilai Zheng  Marc Walther 《水文研究》2020,34(22):4251-4261

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.  相似文献   

Alteration of hydrological processes and streamflow with juniper (Juniperus virginiana) encroachment in a mesic grassland catchment          下载免费PDF全文

Chris B. Zou  Donald J. Turton  Rodney E. Will  David M. Engle  Sam D. Fuhlendorf 《水文研究》2014,28(26):6173-6182

To understand the effect of woody plant encroachment on hydrological processes of mesic grasslands, we quantified infiltration capacity in situ, the temporal changes in soil water storage, and streamflow of a grassland catchment and a catchment heavily encroached by juniper (Juniperus virginiana, eastern redcedar) in previously cultivated, non‐karst substrate grasslands in north‐central Oklahoma for 3 years. The initial and steady‐state infiltration rates under the juniper canopy were nearly triple to that of the grassland catchment and were intermediate in the intercanopy spaces within the encroached catchment. Soil water content and soil water storage on the encroached catchment were generally lower than on the grassland catchment, especially when preceding the seasons of peak rainfall in spring and fall. Frequency and magnitude of streamflow events were reduced in the encroached catchment. Annual runoff coefficients for the encroached catchment averaged 2.1%, in contrast to 10.6% for the grassland catchment. Annual streamflow duration ranged from 80 to 250 h for the encroached catchment compared with 600 to 800 h for the grassland catchment. Our results showed that the encroachment of juniper into previously cultivated mesic grasslands fundamentally alters catchment hydrological function. Rapid transformation of mesic grassland to a woodland state with juniper encroachment, if not confined, has the potential to drastically reduce soil water, streamflow and flow duration of ephemeral streams in the Southern Great Plains. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Landform‐oriented flow‐routing algorithm for the dual‐structure loess terrain based on digital elevation models          下载免费PDF全文

Liyang Xiong  Guoan Tang  Shijiang Yan  Shijie Zhu  Yiying Sun 《水文研究》2014,28(4):1756-1766

The loess landform in the Loess Plateau of China is with typical dual structure, namely, the upper smooth positive terrain and the lower cliffy negative terrain (P–N terrain for short). Obvious differences in their morphological feature, geomorphological mechanism, and hydrological process could be found in the both areas. Based on the differences, a flow‐routing algorithm that separately addresses the dual‐structure terrain would be necessary to encompass this spatial variation in their hydrological behaviour. This paper proposes a mixed flow‐routing algorithm to address aforementioned problems. First, the loess landform surface is divided into P–N terrains based on digital elevation models. Then, specific catchment area is calculated with the new algorithm to simulate the water flows in both positive and negative terrain areas. The mixed algorithm consists of the multiple flow‐routing algorithm (multiple‐flow direction) for positive areas and the D8 algorithm for negative areas, respectively. The approach is validated in two typical geomorphologic areas with low hills and dense gullies in the northern Shaanxi Loess Plateau. Four indices are used to examine the results, which show that the new algorithm is more suitable for loess terrain in simulating the spatial distribution of water accumulation, as well as in modeling the flow characteristics of the true surface by considering the morphological structures of the terrain. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Efficient DEM‐based overland flow routing using integrated recursive algorithms          下载免费PDF全文

Pin‐Chun Huang  Kwan Tun Lee 《水文研究》2017,31(5):1007-1017

Two primary concerns in performing watershed overland flow routing are the numerical instability and computational efficiency. The stability of executing an explicit scheme has to be maintained by observing the Courant–Friedrich–Lewy criterion, which is adopted to confirm that the numerical marching speed is larger than the wave celerity. Moreover, there is another criterion of time step devised in previous studies to avoid back‐and‐forth refluxing between adjacent grids. The situation of refluxing usually occurs on flat regions. In light of this, the selection of a small time increment to honor both restrictions simultaneously is believed to decrease the computational efficiency in performing overland flow routing. This study aims at creating a robust algorithm to relax both restrictions. The proposed algorithm was first implemented on a one‐dimensional overland plane to evaluate the accuracy of the numerical result by comparing it with an analytical solution. Then, the algorithm was further applied to a watershed for 2D runoff simulations. The results show that the proposed integrated algorithm can provide an accurate runoff simulation and achieve satisfactory performance in terms of computational speed.  相似文献   

中国东部高空颠簸时空分布特征及其与热带中东太平洋海温的关系   总被引：1，自引：0，他引：1  

阿利曼  王君  冯锦明  李秀连 《大气科学》2016,40(5):1073-1088

本文利用1979～2014年NCEP-DOE日平均再分析资料和中国区域2375份航空器空中颠簸报告资料,研究中国东部区域高空颠簸的时空分布特征及其与热带中东太平洋海温异常（简称“海温异常”;空间范围:5°S～5°N,120°～170°W）的关系以及产生这种关系的可能原因。结果表明:中国东部地区高空颠簸与东亚副热带西风急流之间存在显著时空相关关系,其原因是高空纬向风引起的垂直风切变是构成高空颠簸时空分布的主导因素。中国东部夏季高空颠簸与海温异常存在正相关关系;冬季呈现南北两个正负相关区:以30°N为界,北部区域存在显著的负相关,南部区存在显著的正相关,在30°N急流轴附近区域无显著相关关系。海温异常影响中国高空颠簸时空分布的可能原因是海温变化引起对流层高层温度出现异常,进而影响温度的经向梯度,导致东亚副热带西风急流强度和位置出现异常（夏季,急流轴南侧出现西风异常;冬季,急流轴北侧出现东风异常,南侧出现西风异常）。高空纬向风的变化导致纬向风的垂直梯度和经向梯度出现异常,最终影响高空颠簸的时空分布特征。对流层高层温度的异常变化可能是由与热带海温异常相关的平流层水汽变化所引起。  相似文献   

Study of high temperature targets identification and temperature retrieval experimental model in SWIR remote sensing based Landsat8     

《International Journal of Applied Earth Observation and Geoinformation》2016

For surface features in short-wave infrared (SWIR, 1.3–3.0 μm) in remote sensing imagery, pixel values depict the total energy including reflection and emission. For surface features at normal temperature in SWIR band, emission energy can be ignored. While for surface features at high temperature in SWIR band, emission energy is equal to or even higher than the reflection energy. So remote sensing imagery of SWIR band can be used to separate emission and reflection energy as well as to realize temperature retrieval of high temperature targets. In this study, the seventh band (SWIR band) of Landsat8 OLI remote sensing imagery is used to perform the theoretical model research for temperature retrieval of high temperature targets. In the meantime, it is also used with the corresponding observation experiment of synchronization satellite to check the theoretical model. The result shows that the radiant flux density for mixed pixels with high temperature targets is higher than adjacent pixels without high temperature targets. Thus, the high temperature pixels can be identified in SWIR band. The retrieval results of temperature and fractional area for high temperature targets are consistent with reality. In the study, the result illustrates that it is effective to identify high temperature targets in remote sensing imagery of SWIR band and the model is appropriate for temperature retrieval use.  相似文献   

GPS 高程转换的总体最小二乘组合方法     

王乐洋  吴飞  吴良才 《测绘工程》2016,25(4):11-14

在现有GPS高程转换的研究中,通常只采用单一的解算方法,然而,不同的计算方法由于适用的条件不同,在对同一组数据进行解算时,解算的精度也各有优劣。针对以上问题,文中提出GPS高程转换的总体最小二乘组合方法,对多种不同的高程转换方法进行组合,运用总体最小二乘法计算不同方法的权值,结合实际工程数据,验证该方法的可行性。计算结果表明,提出的方法能够有效地提高高程转换精度。  相似文献