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181.
青藏高原北羌塘半岛湖新生代粗面玄武岩橄榄石电子探针和激光探针分析 总被引:4,自引:0,他引:4
利用电子探针和激光探针剥蚀系统(LA-ICP-MS),对北羌塘新第三纪粗面玄武岩中的橄榄石主元素和微量、稀土元素进行了系统分析。结果表明,本区橄榄石Fo平均为88,属贵橄榄石种属。相对富集Ni、Co和重稀土,而强烈亏损轻稀土及Rb、Sr、Ba、Zr等大离子亲石元素。其稀土元素配分型配分型式与粗面玄武岩全岩稀土配分型式呈互补状态。 相似文献
182.
河北矾山燕山期侵入岩地球化学特征及成因 总被引:8,自引:0,他引:8
河北矾山地区燕山期侵入岩可分为早、晚两期。早期(中侏罗世-晚侏罗世)侵入岩主要由二长闪长岩、石英二长闪长岩、石英二长岩、正长岩构成,以高钾钙碱性岩系列岩石为主;SiO2=53.58%-60.57%,Al2O3=16.16%-17.23%,Na2O K2O=5.76%-8.96%,K2O=2.25%-4.55%,Na2O/K2O=1.14-1.56;ACNK=0.72-0.86,NKA=0.47-0.77;Eu^*/Eu=0.80-0.95,轻稀土富集,重稀土和Nb、Ta、Hf、Ti亏损,相对低Zr、Rb和Rb/Sr,但高Sr和Sr/Y,具有埃达史质岩石质岩石的部分特征。晚期(白垩纪)侵入岩由碱长石英正长岩、石英正长岩、石英二长岩、碱工花岗岩、钾长花岗岩构成,以钾玄岩系列岩石为主;比早期岩石富SiO2,低Al2O3、富Na2O K2O和K2O,但低Na2O/K2O;ACNK=0.82-1.07,NKA=0.77-0.92;Eu^*/Eu=0.65-1.00,轻稀土富集,重稀土和Nb、Ta、Hf、Ti亏损,相对高Zr、Rb和Rb/Sr,但低Sr和Sr/Y。矾山地区早期侵入岩的形成可能与伊泽奈崎(Izanaqi)板块向欧亚大陆板块的俯冲所导致的挤压增厚有关;晚期侵入岩可能形成于拉张环境中。 相似文献
183.
碳酸盐岩差异性风化成土特征及其对石漠化形成的影响 总被引:35,自引:0,他引:35
碳酸盐岩极低的酸不溶物含量使岩石风化产生的残积土壤物质数量极少,并产生巨大的体积缩小,促使早期形成的残积土在重力作用下不断向下塌陷。显著的差异性风化使基岩面强烈起伏,甚至形成大量的岩溶尘洼地、裂隙、地下管道、洞穴系统等。在重力和水的作用下,土粒沿垂直和水平方向上经微距离或短距离搬运到上述低洼或地下空间中,甚至由地下河带到更远的地方,这是碳酸盐岩地区土壤丢失的重要方式,也是形成石漠化最主要的地质因素。土壤在地表分布高度不均匀,是碳酸盐岩地区的地表少土的重要原因。对于酸不溶物含量相当的石灰岩和白云岩而言,由于白云岩的差异性风化明显弱于石灰岩,以及受各种应力作用后,白云岩形成的节理及裂隙密集而均匀,从而提高了近地表白云岩的含水能力,延长了风化过程中的水-岩反应时间,使风化作用可以相对集中于地表或近地表进行,有利于岩石的整体风化作用的进行,同时使白云岩风化壳基岩面起伏相对较小,风化残积形成的土壤分布也相对均匀。因此,白云岩区地表土层较厚,石漠化程度也稍弱于灰岩区。 相似文献
184.
S. Shibuya 《Geotechnical and Geological Engineering》2002,20(4):333-369
A double exponential fitting model (DEFM) capable of expressing the non-linear stress-stiffness relationship of geomaterials has been proposed by Shibuya et al. (1997). The model comprises two material constants; the elastic stiffness at very small strains and the strength, together with other free parameters to determine the complete stress-stiffness relationship. In this paper, the capability of the original function used for DEFM in simulating the tangent stiffness-stress relationship of geomaterials is first discussed. Second, the methods for determining the free model parameters, as well as its conversion to obtain a stress-strain relationship are proposed. The applicability of DEFM to predicting non-linear stress-stiffness relationship is examined in detail in a total of forty-nine fitting cases of compression test data on sedimentary rock, artificial soft rock and soft clay. It is found that the DEFM is effective in expressing the non-linear stress-stiffness relationship of various kinds of geomaterials at small to intermediate strains, say less than 0.5%. The superiority of this model compared to other fitting models currently in use is also demonstrated in some of the fitting cases. 相似文献
185.
An experimental study of grain scale melt segregation mechanisms in two common crustal rock types 总被引:3,自引:0,他引:3
Creation of pathways for melt to migrate from its source is the necessary first step for transport of magma to the upper crust. To test the role of different dehydration‐melting reactions in the development of permeability during partial melting and deformation in the crust, we experimentally deformed two common crustal rock types. A muscovite‐biotite metapelite and a biotite gneiss were deformed at conditions below, at and above their fluid‐absent solidus. For the metapelite, temperatures ranged between 650 and 800 °C at Pc=700 MPa to investigate the muscovite‐dehydration melting reaction. For the biotite gneiss, temperatures ranged between 850 and 950 °C at Pc=1000 MPa to explore biotite dehydration‐melting under lower crustal conditions. Deformation for both sets of experiments was performed at the same strain rate (ε.) 1.37×10?5 s?1. In the presence of deformation, the positive ΔV and associated high dilational strain of the muscovite dehydration‐melting reaction produces an increase in melt pore pressure with partial melting of the metapelite. In contrast, the biotite dehydration‐melting reaction is not associated with a large dilational strain and during deformation and partial melting of the biotite gneiss melt pore pressure builds more gradually. Due to the different rates in pore pressure increase, melt‐enhanced deformation microstructures reflect the different dehydration melting reactions themselves. Permeability development in the two rocks differs because grain boundaries control melt distribution to a greater extent in the gneiss. Muscovite‐dehydration melting may develop melt pathways at low melt fractions due to a larger volume of melt, in comparison with biotite‐dehydration melting, generated at the solidus. This may be a viable physical mechanism in which rapid melt segregation from a metapelitic source rock can occur. Alternatively, the results from the gneiss experiments suggest continual draining of biotite‐derived magma from the lower crust with melt migration paths controlled by structural anisotropies in the protolith. 相似文献
186.
An automated strategy for calculation of phase diagram sections and retrieval of rock properties as a function of physical conditions 总被引:9,自引:0,他引:9
We formulate an algorithm for the calculation of stable phase relations of a system with constrained bulk composition as a function of its environmental variables. The basis of this algorithm is the approximate representation of the free energy composition surfaces of solution phases by inscribed polyhedra. This representation leads to discretization of high variance phase fields into a continuous mesh of smaller polygonal fields within which the composition and physical properties of the phases are uniquely determined. The resulting phase diagram sections are useful for understanding the phase relations of complex metamorphic systems and for applications in which it is necessary to establish the variations in rock properties such as density, seismic velocities and volatile‐content through a metamorphic cycle. The algorithm has been implemented within a computer program that is general with respect to both the choice of variables and the number of components and phases possible in a system, and is independent of the structure of the equations of state used to describe the phases of the system. 相似文献
187.
Raman spectra of diopside were collected from atmospheric pressure to 71 GPa. The pressure dependences of 22 modes were determined.
Changes occurred in the spectra at three different pressures. First, at approximately 10 GPa, the two Raman modes at 356 and
875 cm−1 disappeared, while the mode at 324 cm−1 split into two modes, diverging at this pressure with significantly different pressure shifts; second, at approximately 15
GPa, a small (1 to 2 cm−1) drop in several of the frequencies was observed accompanied by changes in the pressure dependency of some of the modes;
and third, above 55 GPa, the modes characteristic of chains of tetrahedrally coordinated silicon disappeared, while those
for octahedrally coordinated silicon appeared. The first change at 10 GPa appears to be a C2/c to C2/c transition involving a change in the Ca coordination. The third change above 55 GPa appears to be a change in the silicon
coordination. At 15 GPa, it is suggested that a change in compressional mechanism takes place.
Received: 14 November 2000 / Accepted: 9 January 2002 相似文献
188.
The permeability of sedimentary rocks during triaxial compression tests was investigated to relate it to the complete strain–stress process. It was found that the permeability was not constant, but varied with the stress and strain states in the rocks. Prior to the peak strength, the permeability decreases with increasing load. A dramatic increase in permeability occurs during the strain softening period. In the present study, in situ measurements of fluid flow and pressure in floor strata was carried out in a double longwall mining face in the Yangzhuang colliery. These measurements show that both the strata pressure and the position with respect to the mining face influence the hydrogeologic properties. The permeability increased in the floor strata behind the mining face because those mining induced fractures opened as the strata pressure decreased. To better understand this change in hydraulic behavior around the mining faces, 3-D numerical modeling was carried out. The model provides the general picture of the stress distribution and failure zone both in the floor and roof strata. The field and model results demonstrate the importance of changes in the stress and strain states on the hydrogeology of a site. 相似文献
189.
In a statistical pattern recognition context, discriminant analysis is designed to classify, when possible, objects into predefined categories. Because this method requires precise input data, uncertainties cannot be propagated in the classifying process. In real case studies, this could lead to drastic misinterpretations of objects. A new nonparametric algorithm based on interval arithmetic has thus been developed to propagate interval-form data. They consist in calculating interval conditional probability density functions and interval posterior probabilities. Objects are eventually assigned to a subset of classes, consistent with the data and their uncertainties. The classifying model is thus less precise, but more realistic than the standard one, which we prove on a real case study. 相似文献
190.