Calibration of Infrared Absorption Coefficients for Structural Hydroxyl in Garnet by a Combined Study of Isotope Ratio Spectrometry and Vibrational Spectroscopy     

Lin Zhu  Ren-Xu Chen  Yong-Fei Zheng  Jing Wang  Bing Gong 《Geostandards and Geoanalytical Research》2023,47(1):105-124

An accurate determination of water content in garnet is critical to quantify the transport of water to the deep mantle by the subducted oceanic crust beyond the breakdown of hydrous phases. Fourier transform infrared spectroscopy (FTIR) is the most widely used approach to determine the species and contents of water in garnet. Accurate quantification of OH in garnet requires independent calibration using an external method, as OH absorbance is mineral and composition specific. To obtain the infrared absorption coefficients of structural hydroxyl in garnet, a combined study of spectrometric analyses by FTIR and a method combining a thermal conversion elemental analyser with isotope ratio mass spectrometry (TC/EA-MS) was carried out for fourteen gem-quality natural garnet crystals with variable compositions. The obtained molar absorption coefficients were 9322 ± 338 and 240 ± 26 l mol⁻¹ cm⁻² for grossular- and spessartine-rich garnet and pyrope-almandine garnet, respectively. These results are within the range of previous studies. A new molar absorption coefficient of 689 ± 177 l mol⁻¹ cm⁻² was obtained for pyrope-spessartine garnet. The large variation in the absorption coefficient indicates it is controlled by both garnet composition and OH-absorption bands. The obtained absorption coefficients are only appropriate for certain types of eclogitic garnet, and more studies should be carried out on eclogitic garnets.  相似文献   

赣西石竹山硅灰石矿床石榴子石特征及其地质意义     

张鹏浩  王先广  丁枫  范宇航  王骏怡  邹婧  孙培均  李文韬 《岩石矿物学杂志》2023,42(4):521-540

江西省石竹山硅灰石矿床位于钦杭成矿带东段的萍乐坳陷带内,是世界资源储量规模最大的硅灰石矿床。为了厘清区内成矿流体性质及进一步找矿潜力,本文根据矿物间的穿插关系和光学特征,将该矿床的石榴子石分为早(GrtⅠ)、晚(GrtⅡ)两个世代,在详细的野外工作基础上,利用电子探针(EMPA)和LA-ICP-MS原位微区分析技术,对石竹山矿床中的石榴子石开展了系统研究。结果表明,石竹山硅灰石矿床石榴子石属于钙铝榴石-钙铁榴石固溶体系列,早期形成的石榴子石(GrtⅠ)Fe含量更高,且震荡环带发育,而晚期形成的石榴子石(GrtⅡ)则发育复杂环带。石榴子石GrtⅠ和GrtⅡ都亏损大离子亲石元素K、Rb、Ba、Sr等,而Nb、Ta、Zr等高场强元素相对含量较高,U含量与∑REE成正比。GrtⅡ的∑REE较低(12.92×10^-6~21.12×10^-6),具有较平坦的稀土元素配分模式,轻微富集轻稀土元素(Ce、Pr、Nd、Sm),微弱负铕异常;GrtⅠ的∑REE相对较高(13.78×10^-6~73.52×10^-6),更富集轻稀土元素(Ce、Pr、Nd、Sm),呈右倾的稀土元素配分模式,负铕异常明显。推测石榴子石GrtⅠ形成于相对开放、水岩比值较高、高氧逸度的酸性体系中,GrtⅡ则形成于相对封闭、水岩比值较低、高氧逸度的中酸性体系中。此外,将石榴子石的端员组分和微量元素特征与国内外不同矿种的接触交代型金属矿床进行对比,结果显示该矿床存在成Cu、Fe、Mo矿体的潜力。  相似文献   

大青山地区2.5 Ga紫苏花岗岩——对深熔石榴花岗岩成因模式的启示     

石强  马龙  陈湘智  徐仲元  李世超  徐进贵  陈开运 《地质论评》2023,69(6):2023060007-2023060007

华北克拉通北缘西部陆块早前寒武纪基底分布广泛,现有的研究普遍认为经历 2.5 Ga,2.45~2.37 Ga,1.95 Ga和1.85 Ga变质热事件影响。华北克拉通北缘阴山陆块中2.5 Ga的紫苏花岗岩研究已经成为了揭示华北克拉通北缘早前寒武纪构造演化的一个热点,但孔兹岩带中却鲜少有新太古代晚期构造热事件的相关报道。近年来,相继从大青山地区的孔兹岩带石榴黑云母片麻岩中分辨出一期具有2.45~2.37 Ga变质锆石年龄的大青山表壳岩,同时出露与其成因关系密切的深熔石榴花岗岩,但其深熔成因的模式存在争议。本文对大青山地区新发现的新太古代晚期紫苏花岗岩、石榴花岗岩及其围岩的野外空间产出关系和锆石年代学进行对比分析,为探究深熔石榴花岗岩成因模式提供重要的启示。  相似文献   

西藏拉隆穹窿淡色花岗岩中石榴子石矿物学研究及对岩浆-热液过程的指示   总被引：1，自引：0，他引：1       下载免费PDF全文

付建刚  李光明  董随亮  张海  郭伟康  张林奎  梁维  焦彦杰  凌晨 《沉积与特提斯地质》2022,42(2):288-299

为建立淡色花岗岩演化和稀有金属成矿的矿物学指标,本文选取了北喜马拉雅拉隆淡色花岗岩的石榴子石为研究对象,对其开展电子探针分析和矿物原位LA-ICP-MS微量分析,结果表明MnO含量从白云母花岗岩(12.42%~13.48%)到钠长石花岗岩(16.83%~22.09%)逐渐增高,白云母花岗岩石榴子石主要为铁铝榴石,钠长石花岗岩中石榴子石主要为锰铝榴石,其均为典型岩浆成因的石榴子石。石榴子石微量元素结果显示白云母花岗岩和钠长石花岗岩石榴子石稀土均呈现HREE富集、LREE亏损,Eu负异常的特征。从白云母花岗岩到钠长石花岗岩,石榴子石中Zn含量增加,Sc、Y和HREE等元素含量降低,特别是当HREE含量小于1000×10^-6时,稀有金属元素Be、Nb和Ta含量增加,标志着岩浆演化从正岩浆阶段进入了岩浆-热液过渡阶段。形成于岩浆-热液过渡阶段的锰铝榴石可以作为拉隆淡色花岗岩Be-Nb-Ta稀有金属矿化的矿物学指标,此外,石榴子石中Sc、Y和HREE等元素的变化也可以作为淡色花岗岩稀有金属矿化的判别标志。  相似文献   

云南个旧锡铜矿集区石榴子石地球化学特征及成矿指示     

张银平  邵拥军  熊伊曲  席振铢  芦磊  张敏  毛禹杰 《矿床地质》2022,41(4):682-701

云南高松矿床中高峰山矿段和老厂矿床中竹叶山矿段分别是个旧超大型锡铜多金属矿集区发育的典型矽卡岩型锡、铜矿段。为查明个旧矿集区锡铜成矿环境的差异,文章选取上述2个矿段矽卡岩中的石榴子石为研究对象,根据产状和矿物共生关系将石榴子石分为与高峰山花岗岩有关早期（Grt-GS1）、晚期（Grt-GS2）、与竹叶山花岗岩有关（Grt-ZS）和与玄武岩有关（Grt-ZX）共4类。电子探针（EPMA）和激光剥蚀等离子质谱（LA-ICP-MS）分析表明：Grt-GS1(Adr_10.58-20.27Grs_38.62-48.28Spe_21.06-32.37Alm_11.88-18.03)成分复杂且变化范围较大,而Grt-GS2(Adr_48.09-69.73Grs_23.84-48.87Spe_3.29-9.58)和Grt-ZS (Adr_13.97-16.06Grs_78.08-79.71Spe_2.15-2.60)成分简单且变化小;稀土元素配分曲线均呈HREE富集、LREE亏损的“左倾型”,并具明显的负Eu异常。Grt-ZX成分简单且较均一(Adr_20.12-21.99Grs_70.84-71.44Pyr_6.29-7.92),稀土元素配分曲线呈HREE亏损、LREE富集的“右倾型”,呈明显的正Eu异常,且F、Cl、U、Th、Pb、V、Cr、Co、Ni、Zn、Ti等元素含量均高于其余3类石榴子石。所有石榴子石REE³⁺与Mg²⁺的正相关性表明,REE³⁺受[X²⁺]Ⅷ-1[REE³⁺]Ⅷ+1[Y³⁺]Ⅳ-1[Y²⁺]Ⅳ+1替换机制的控制,REE³⁺主要替代Mg²⁺进入石榴子石晶格。石榴子石的U、Sn含量及稀土元素配分特征指示：高峰山石榴子石（Grt-GS1和Grt-GS2）在演化过程中氧逸度明显升高、竹叶山石榴子石（Grt-ZS和Grt-ZX）形成的氧逸度总体高于高峰山,但Grt-ZX形成时氧逸度低于Grt-ZS。稀土元素特征显示：Grt-GS1、Grt-GS2与Grt-ZS均形成于弱酸性环境,而Grt-ZX形成于近中性且富F、Cl的环境下。∑REE³⁺与Y呈良好的正相关性和REE含量变化指示4类石榴子石均形成于封闭或近封闭的体系中,在接近平衡和低水岩比的条件中受扩散交代作用缓慢生长而形成。综合研究表明,玄武岩对成矿的影响在于改变了流体性质,为成矿提供了大量微量元素（如Co、Ni、V、Cr等）和有利于成矿离子运移和富集的卤族元素（如F、Cl）,而高峰山矿段锡富集的原因可能是在演化过程中水岩反应的加强和氧逸度的升高。  相似文献   

Melt Pockets in Garnet Megacrysts from Cenozoic Alkali Basalts of the Shavaryn Tsaram Vicinity, Mongolia     

Anna ASEEVA  Oleg AVCHENKO  Alexander KARABTSOV  Alexander CHASHCHIN  Sergey VYSOTSKIY  Victoria YAKOVENKO  Natalia ZARUBINA  Natalia KHARITONOVA 《《地质学报》英文版》2022,96(1):111-122

Garnet megacryst with a multiphase inclusion from intraplate alkali basalts of the Shavaryn Tsaram(Tariat,Mongolia)was the object of the study.This unusual aggregate consists of porous glass,Ti-rich biotite,orthopyroxene,spinel,clinopyroxene,olivine,and ilmenite.Win TWQ 2.32 thermodynamic simulation of this system revealed a few intervals of equilibrium.Pressure and temperature adjustment reflected in the paragenetic minerals of the melt pocket.The capture of already crystallised garnet megacryst was at P=0.8-1 GPa and T=1120-1160℃.Mineral crystallisation inside the melt pocket,accompanied by external inputs,occurred at P=0.75-0.95 GPa;T=790-1120℃.Symplectite assemblage formed in the garnet megacryst due to decomposition at(P=0.55-0.7 GPa;T=850-930℃).The study of the oxygen isotope content in primary garnet and biotite of the melt pocket showed that the δ¹⁸O_VSMOW values are the same and correspond to that of typical mantle xenoliths.However,the chemical and microcomponent composition of the melt pocket minerals reveals a material that differs from basalts and peridotites.Thus,it has been revealed that the multiphase inclusion in the garnet megacryst formed not only on account of the garnet’s substance,but also due to the entrapped material of the Earth’s interior.  相似文献   

有关埃达克岩实验应用中几个问题的探讨   总被引：1，自引：0，他引：1  

张旗 《岩石矿物学杂志》2015,34(2):257-270

实验研究非常重要,是花岗岩(和埃达克岩)理论创新的源泉之一。近年来,国内在埃达克岩实验研究方面取得了很大的成绩。在这个领域,中国在国际上是处于领先水平的,虽然得到的认识并不相同,这是很正常的。本文讨论了与埃达克岩有关的一些实验研究问题,认为:1下地壳底部是缺水的,花岗岩是在缺水条件下部分熔融的,应当慎重对待在饱和水和有水加入情况下的实验结果。2要注意残留相组分中是否有斜长石出现,不能只关注石榴石,石榴石与斜长石配合起来才能得出正确的认识。3 1.0 GPa压力下石榴石出现线的真实含义是什么?它只表明与之平衡的熔体是贫Yb的。但是,贫Yb的花岗岩不只是埃达克岩,喜马拉雅型花岗岩也贫Yb,因此,还需要考虑斜长石消失的情况,如果石榴石出现而斜长石消失了,熔体是埃达克岩;如果石榴石出现而斜长石没有消失,则熔体为喜马拉雅型花岗岩。由于国外没有喜马拉雅型花岗岩的概念,因此,对国外某些在1 GPa条件下得到的实验资料应当仔细鉴别,也许其中有一些熔体并非埃达克岩,而是喜马拉雅型花岗岩。4相变反应不同于部分熔融反应,不能把相变反应的结果解释为部分熔融的结果。相变反应是在温度压力增加的情况下发生的,不是产生花岗岩的主要方式;部分熔融反应主要是在温度增加压力不变的条件下发生的,是产生花岗岩的主要方式。5实验研究得出的一个重要的结论是:与榴辉岩平衡的熔体是埃达克岩,因此,埃达克岩的真谛可能就是非常简单的一句话:源区有石榴石无斜长石。只要符合这个标志,与其平衡的熔体必然是高Sr低Yb的;只要符合这个标志,与其平衡的熔体必然是在较高的压力下形成的。高压可能就是埃达克岩最重要的构造意义。  相似文献   

西藏日喀则地区白朗蛇绿岩中石榴辉石岩的岩石地球化学、年代学及其构造意义   总被引：2，自引：1，他引：1  

赵佳楠  许志琴  梁凤华 《岩石学报》2015,31(12):3687-3700

白朗石榴辉石岩位于西藏南部雅鲁藏布江蛇绿岩带上,地处于日喀则地区白朗县境内,因其具有重要的大地构造位置和意义,得到了国内外诸多学者关注。国内外学者对该岩体的研究有助于深入剖析雅鲁藏布江蛇绿岩带的就位机制。本文以白朗石榴辉石岩为研究对象,其野外产出为构造岩块,围岩为没有变形特征的蛇纹石化地幔橄榄岩,早白垩世昂仁组和紫红色硅质岩也没有构造变质现象,且石榴辉石岩与蛇纹石化地幔橄榄岩间界限截然。通过对其进行岩石地球化学和年代学的研究,并结合大地构造动力学观点,认为西藏日喀则地区石榴辉石岩属钙碱性超基性岩,形成于无流体无水的稳定物理化学环境中,略亏损高场强元素Th、Ta、Nb等,锆石LA-ICP-MS U-Pb年龄为149.0±3.1Ma,且锆石εHf(t)平均值为+17.7,说明原始岩浆主要源于亏损地幔,且没有发生岩浆混染。总结:本文确定白朗石榴辉石岩原始岩浆来源于上地幔,并且该岩石的形成与印度板块和欧亚板块俯冲有关,但在该岩石形成过程中印度板块和欧亚板块没有发生陆陆碰撞。  相似文献   

An Early Palaeozoic HP/HT granulite–garnet peridotite association in the south Altyn Tagh, NW China: P–T history and U-Pb geochronology     

J. X. ZHANG  C. G. MATTINSON  F. C. MENG  Y. S. WAN 《Journal of Metamorphic Geology》2005,23(7):491-510

High‐pressure kyanite‐bearing felsic granulites in the Bashiwake area of the south Altyn Tagh (SAT) subduction–collision complex enclose mafic granulites and garnet peridotite‐hosted sapphirine‐bearing metabasites. The predominant felsic granulites are garnet + quartz + ternary feldspar (now perthite) rocks containing kyanite, plagioclase, biotite, rutile, spinel, corundum, and minor zircon and apatite. The quartz‐bearing mafic granulites contain a peak pressure assemblage of garnet + clinopyroxene + ternary feldspar (now mesoperthite) + quartz + rutile. The sapphirine‐bearing metabasites occur as mafic layers in garnet peridotite. Petrographical data suggest a peak assemblage of garnet + clinopyroxene + kyanite + rutile. Early kyanite is inferred from a symplectite of sapphirine + corundum + plagioclase ± spinel, interpreted to have formed during decompression. Garnet peridotite contains an assemblage of garnet + olivine + orthopyroxene + clinopyroxene. Thermobarometry indicates that all rock types experienced peak P–T conditions of 18.5–27.3 kbar and 870–1050 °C. A medium–high pressure granulite facies overprint (780–820 °C, 9.5–12 kbar) is defined by the formation of secondary clinopyroxene ± orthopyroxene + plagioclase at the expense of garnet and early clinopyroxene in the mafic granulites, as well as by growth of spinel and plagioclase at the expense of garnet and kyanite in the felsic granulite. SHRIMP II zircon U‐Pb geochronology yields ages of 493 ± 7 Ma (mean of 11) from the felsic granulite, 497 ± 11 Ma (mean of 11) from sapphirine‐bearing metabasite and 501 ± 16 Ma (mean of 10) from garnet peridotite. Rounded zircon morphology, cathodoluminescence (CL) sector zoning, and inclusions of peak metamorphic minerals indicate these ages reflect HP/HT metamorphism. Similar ages determined for eclogites from the western segment of the SAT suggest that the same continental subduction/collision event may be responsible for HP metamorphism in both areas.  相似文献   

Constraining the P–T path of a MORB-type eclogite using pseudosections, garnet zoning and garnet-clinopyroxene thermometry: an example from the Bohemian Massif     

P. &#;TÍPSKÁ  R. POWELL 《Journal of Metamorphic Geology》2005,23(8):725-743

A mid‐ocean ridge basalt (MORB)‐type eclogite from the Moldanubian domain in the Bohemian Massif retains evidence of its prograde path in the form of inclusions of hornblende, plagioclase, clinopyroxene, titanite, ilmenite and rutile preserved in zoned garnet. Prograde zoning involves a flat grossular core followed by a grossular spike and decrease at the rim, whereas Fe/(Fe + Mg) is also flat in the core and then decreases at the rim. In a pseudosection for H₂O‐saturated conditions, garnet with such a zoning grows along an isothermal burial path at c. 750 °C from 10 kbar in the assemblage plagioclase‐hornblende‐diopsidic clinopyroxene‐quartz, then in hornblende‐diopsidic clinopyroxene‐quartz, and ends its growth at 17–18 kbar. From this point, there is no pseudosection‐based information on further increase in pressure or temperature. Then, with garnet‐clinopyroxene thermometry, the focus is on the dependence on, and the uncertainties stemming from the unknown Fe³⁺ content in clinopyroxene. Assuming no Fe³⁺ in the clinopyroxene gives a serious and unwarranted upward bias to calculated temperatures. A Fe³⁺‐contributed uncertainty of ±40 °C combined with a calibration and other uncertainties gives a peak temperature of 760 ± 90 °C at 18 kbar, consistent with no further heating following burial to eclogite facies conditions. Further pseudosection modelling suggests that decompression to c. 12 kbar occurred essentially isothermally from the metamorphic peak under H₂O‐undersaturated conditions (c. 1.3 mol.% H₂O) that allowed the preservation of the majority of garnet with symplectitic as well as relict clinopyroxene. The modelling also shows that a MORB‐type eclogite decompressed to c. 8 kbar ends as an amphibolite if it is H₂O saturated, but if it is H₂O‐undersaturated it contains assemblages with orthopyroxene. Increasing H₂O undersaturation causes an earlier transition to SiO₂ undersaturation on decompression, leading to the appearance of spinel‐bearing assemblages. Granulite facies‐looking overprints of eclogites may develop at amphibolite facies conditions.  相似文献