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171.
构造动力变质作用初论 总被引:3,自引:1,他引:2
本文提出了构造动力变质作用的基本概念。即在构造动力及其引发的动力热流共同作用下,岩石、矿物在构造运动中发生的形变、相变而呈现的变质作用。按构造动力变质作用的物理化学条件,动力变质岩的结构构造、动态重结晶和混合岩化作用、应力矿物共生组合关系及其空间分布等特征,将构造动力变质作用由弱到强划分为4个发展阶段和相应的4种基本变质类型——脆性、脆-塑性、塑性和动力热流变形变质,并论述了它们各自的基本特征。 相似文献
172.
武当山地块基性岩墙群地球化学研究及其大地构造意义 总被引:28,自引:5,他引:23
武当山地块基性岩墙群的地球化学特征表明,它们为具大陆拉斑玄武央珠大陆板内岸 浆侵入的产物,是古陆块裂并保存在造山带内基底岩块的重要证据,这表明南秦岭和扬子板块曾存在晋宁期固结的统一古陆块,该古陆块在新元古代早期发生了一次重要的裂解作用。 相似文献
173.
174.
再论煤中大分子基本结构单元演化的拼叠作用 总被引:3,自引:0,他引:3
芳构化作用和环缩合作用的传统煤化作用理论具有一定局限性,煤中基本结构单元拼叠作用是高煤级煤演化的特有机理。拼叠作用显著发生的起点位于镜质组最大反射率Ro,max为6.0%附近,大分子化学键的均裂提供了拼叠作用得以实现的微化学环境条件,其实质是一种“动力化学”过程,与氧接芳碳等有关的大量“均裂”是在短暂的煤化阶段中突然出现的,导致“拼叠作用”的显著发生具有“阶跃式”特征,是造成高煤级煤中期到后期阶段大分子基本结构单元急剧增大的根本原因和主要地球化学机理。 相似文献
175.
Constraints from high-pressure veins in eclogites on the composition of hydrous fluids in subduction zones 总被引:3,自引:0,他引:3
Hydrous high-pressure veins formed during dehydration of eclogites in two paleo-subduction zones (Trescolmen locality in the Adula nappe, central Alps and Münchberg Gneiss Massif, Variscan fold belt, Germany) constrain the major and trace element composition of solutes in fluids liberated during dehydration of eclogites. Similar initial isotopic compositions of veins and host eclogites at the time of metamorphism indicate that the fluids were derived predominantly from the host rocks. Quartz, kyanite, paragonite, phengite, zoisite and omphacite are the dominant minerals in the veins. The major element compositions of the veins are in agreement with experimental evidence indicating that the composition of solutes in such fluids is dominated by SiO2 and Al2O3. Relative to N-MORB, the veins show enrichments of Cs, Rb, Ba, Pb, and K, comparable or slightly lower abundances of Sr, U, and Th, and very low abundances of Nd, Sm, Zr, Nb, Ti and Y. The differential fractionation of highly incompatible elements such as K, U and Th in the veins, as well as the presence of hydrous minerals in the eclogites rule out partial melting as a cause for vein formation. These results confirm previous suggestions that fluids derived from subducted basalt may have low abundances of high field strength elements, rare earth elements and Y. Variable vein-eclogite enrichment factors of incompatible alkalis and to a lesser extent Pb appear to reflect mineralogical controls (phengite, epidote-group minerals) on partitioning of these elements during dehydration of eclogite in subduction zones. However, abundance variations of incompatible elements in minerals from eclogites suggest that the composition of fluids released from eclogites at temperatures <700°C may not reflect true equilibrium partitioning during dehydration. Simple models for the trace elements U and Th indicate the relative importance of the basaltic and sedimentary portions of subducted oceanic crust in producing the characteristic chemical signatures of these elements in convergent plate margin volcanism. 相似文献
176.
M. Catti F. Freyria Fava C. Zicovich R. Dovesi 《Physics and Chemistry of Minerals》1999,26(5):389-395
The high-pressure equation of state of the normal spinels MgCr2O4 (picrochromite), MnCr2O4 and ZnCr2O4, and their reaction of decomposition into Cr2O3 (eskolaite) and MO (rocksalt-type) component oxides, were investigated by periodic unrestricted Hartree-Fock calculations.
All-electron basis sets, and an a posteriori correction for the electron correlation energy, based on Density-Functional-Theory, were employed. Interpolation of results
by the P-V Murnaghan equation of state yielded the equilibrium volume and energy, and the bulk modulus and its pressure derivative,
for each of the seven phases (three spinels, three rocksalt oxides and eskolaite) considered. The simulated behaviour of interatomic
distances vs pressure shows similar compressibilities of M-O bonds in both octahedral and tetrahedral coordinations. Binding
energies and formation enthalpies of spinels from oxides are also computed and compared to available experimental data. The
predicted decomposition pressures of Mg, Mn and Zn chromium spinels are 19, 23 and 34 GPa, respectively. The greater stability
of ZnCr2O4 is related to Zn2+ being better suited to tetrahedral coordination than the other M2+ cations. Such results are strongly supported by the excellent agreement previously obtained between simulated (11 GPa) and
experimental (13 GPa) pressures of the decomposition of MgAl2O4 spinel into corundum and periclase.
Received: 9 February 1998 / Accepted: 12 October 1998 相似文献
177.
Tectonothermal history of the basement rocks in the western zone of the North China Craton and its tectonic implications 总被引:47,自引:0,他引:47
The basement of the North China Craton can be divided into the eastern, central and western zones, based on lithological, structural, metamorphic and geochronological data. The western zone comprises two different petrotectonic units: Archaean tonalitic–trondhjemitic–granodioritic (TTG) grey gneisses and metamorphic mafic rocks, and Palaeoproterozoic khondalite series. The former is characterized by isobaric cooling (IBC)-type anticlockwise P–T paths in the north-northwestern part of the zone and near-isothermal decompression (ITD)-type clockwise P–T paths in the eastern part, adjacent to the central zone. On the other hand, the tectonothermal evolution of Palaeoproterozoic khondalite series rocks is characterized exclusively by nearly isothermal decompression following the peak of metamorphism and then cooling, defining clockwise P–T paths. The Archaean TTG gneisses and associated mafic rocks with anticlockwise metamorphic P–T paths reflects an origin related to underplating and intrusion of mantle-derived magmas which may be derived from mantle plumes. They represent a late Archaean continental block in the western part of the North China Craton. The Palaeoproterozoic khondalite series rocks represent passive continental margin deposits. They were metamorphosed and deformed in the late Palaeoproterozoic during the amalgamation of the western continental block with another continental block in the east part of the North China Craton. The ITD-type clockwise P–T–t paths of the Palaeoproterozoic khondalite series rocks record the tectonothermal histories of the collision of the western and eastern continental blocks which resulted in the final assembly of the North China Craton at c. 1800 Ma. 相似文献
178.
179.
对南秦岭北大巴山地区广泛分布的一套基性岩墙群中的辉绿岩进行采样,并进行了锆石U-Pb年代学、全岩地球化学分析。结果显示,岩石形成年龄为435~433 Ma,为早志留世晚期岩浆活动产物。这些辉绿岩具低硅、高碱、高钛的碱性岩特征。岩石微量及稀土元素具板内玄武岩特征,轻稀土元素相对富集,轻重稀土元素分异明显,富集不相容元素Ba、Nb、Ta,而K、Y、Yb相对亏损;K及Rb的负异常表明岩石源区残留角闪石或金云母,部分熔融模拟结果显示岩石起源于尖晶石角闪石岩高程度部分熔融。综合地球化学特征及前人研究结果,认为北大巴山地区在早古生代处于大规模伸展裂陷背景下,岩石圈的拉张诱发了低熔点的交代岩石圈地幔熔融,进而形成了这条碱性岩浆带。 相似文献
180.