Paleotemperatures and paleofluids recorded in fluid inclusions from calcite veins from the northern flank of the Ponta Grossa dyke swarm: Implications for hydrocarbon generation and migration in the Paraná Basin     

《Marine and Petroleum Geology》2014

The Paraná Basin, southern Brazil, has an atypical thermal and fluid history due to the occurrence of an episodic continental flood volcanism during the Early Cretaceous. So far, there are few data about the influence of this volcanic event on the paleotemperatures and paleofluids of the Paraná Basin sedimentary rocks. The Teresina Formation in the northern flank of the Ponta Grossa dyke swarm hosts high concentration of subsurface igneous rock bodies (sills and dykes), besides its covering by a hundreds meter thick volcanic rock cap. In this study, we used fluid inclusion analysis performed in horizontal and vertical calcite veins from the Teresina Formation and from a Late Cretaceous basic dyke to estimate paleotemperatures and to characterize the composition of diagenetic paleofluids. Homogenization temperatures of requilibrated fluid inclusions show that the Teresina Formation reached temperatures above 200 °C. Horizontal parallel bedding calcite veins from the Teresina Formation record low to high salinity (2–26 wt.% NaCl eq.) aqueous paleofluids. The prevalence of high salinity fluid inclusions associated with light hydrocarbon fluid inclusions indicates deep buried fluids. Fluid inclusions in vertical calcite vein from basic dyke comprise only low salinity aqueous fluids (0–3 wt.% eq.NaCl) interpreted as dominated by meteoric water. The recorded paleotemperatures are attributed to the heating by the Paraná volcanic event during the Early Cretaceous, with the thermal effect of the volcanic rock cap surpassing the effect of nearby sills and dykes. Estimated paleotemperatures higher than 200 °C would allow the generation of light liquid and gaseous hydrocarbons. Overpressured compartments in the Teresina Formation allowed the expulsion of buried pore fluids (high salinity aqueous fluids and hydrocarbons) to fracture systems, where they mixed with meteoric water. The input of meteoric water through fracture systems connected with the surface favored hydrocarbons degradation in the early stages of source rock maturation during the Early Cretaceous.  相似文献   

Hydrocarbon composition and distribution in a coastal region under influence of oil production in northeast Brazil   总被引：1，自引：0，他引：1  

Wagener Ade L  Carreira RS  Hamacher C  Scofield Ade L  Farias CO  Cordeiro LG  Luz LG  Baêta AP  Kalas FA 《Marine pollution bulletin》2011,62(8):1877-1882

Waters and sediments from the Potiguar Basin (NE Brazilian coast) were investigated for the presence and nature of polycyclic aromatic hydrocarbons (PAH) and aliphatic hydrocarbons. The region receives treated produced waters through a submarine outfall system serving the industrial district. The total dispersed/dissolved concentrations in the water column ranged from 10-50 ng L⁻¹ for ∑16PAH and 5-10 μg L⁻¹ for total aliphatic hydrocarbons. In the sediments, hydrocarbon concentrations were low (0.5-10 ng g⁻¹for ∑16PAH and 0.01-5.0 μg g⁻¹ for total aliphatic hydrocarbons) and were consistent with the low organic carbon content of the local sandy sediments. These data indicate little and/or absence of anthropogenic influence on hydrocarbon distribution in water and sediment. Therefore, the measured values may be taken as background values for the region and can be used as future reference following new developments of the petroleum industry in the Potiguar Basin.  相似文献   

Towards biomarker analysis of hydrocarbons trapped in individual fluid inclusions: First extraction by ErYAG laser     

Tomas Hode  Yngve Zebühr  Curt Broman   《Planetary and Space Science》2006,54(15):1575-1583

Fluid inclusions act as sealed vessels containing information about the fluid environment in which the minerals precipitated, and until decrepitated, the chemical composition of the fluid inside the inclusion stays intact. In many cases fluid inclusions contain trapped hydrocarbons, which may provide useful information in paleontological, organic geochemical and astrobiological research since they act as containers of non-contaminated organic matter with a defined minimum age. Here we present a novel concept for extraction of fluid inclusions in preparation for application to extract single fluid inclusions. The method is based on the illumination of a sample with an ErYAG laser (). The wavelength of the laser is absorbed by water and organic material, and with the minerals encapsulating the inclusions transparent to the wavelength, the fluid will expand and the inclusion will decrepitate. The initial results of our study demonstrate that fluid inclusions can be extracted by the use of an ErYAG laser, and that organic biomarkers may survive the process, readily available for GC–MS analysis.  相似文献   

Source apportionment of sedimentary hydrocarbons in the Segara Anakan Nature Reserve,Indonesia     

Agung Dhamar Syakti  Nuning Vita Hidayati  Endang Hilmi  Anne Piram  Pierre Doumenq 《Marine pollution bulletin》2013

The study aimed to determine the spatial distribution of n-alkanes and polycyclic aromatic hydrocarbons (PAHs) in surface sediments of the Segara Anakan nature reserve and their potential origins using gas chromatography–mass spectrometry. Total alkane concentrations ranged from 3755 to 129,027 μg kg⁻¹, and the concentrations of 16 PAHs ranged from 375 to 29,517 μg kg⁻¹. The ratios of specific n-alkanes (e.g., CPI_24–34, WaxC_n, and Paq), including a new proposed index, terrestrial–marine discriminant (TMD), as well as the ratios of selected PAHs (e.g., Ant/∑178, Fl/∑202, BaAnt/∑228, and IPyr/∑276), showed that the sources of hydrocarbons in the sediments were generally biogenic, including both terrigenous and marine, with an anthropogenic pyrolytic contribution (petrogenic and biogenic combustion). For the environmental risk assessment, a sediment quality guideline (SQGs) comparison indicated that the station risk levels ranged from low to medium-low, except for R6, which has a greater impact on the ecological risk for marine organisms.  相似文献   

天津地区表层土壤多环芳烃类污染物污染源辨析   总被引：5，自引：1，他引：4  

叶必雄  陶澍  张枝焕 《地理科学进展》2005,24(5):61-68

利用因子分析法及离散点曲面张力样条函数插值法对天津地区表层土壤多环芳烃类污染物污染源的类型及空间分布进行分析,表明研究区不同土地利用类型的污染源大多以混合源（包括燃煤与原油渗漏）为主,其中污灌农田、普通农田、荒地和城市绿地中混合源所占比重依次为61.26%、69.35%、52.86%、64.45%。而各污染源在空间分布上与其所处地理位置、地理条件及该区域内人们的生活习性都比较符合。  相似文献   

Phase distribution of hydrocarbons in the water column after a pelagic deep ocean oil spill     

Saioa Elordui-Zapatarietxe  Núria Moraleda  Joan Albaigés 《Marine pollution bulletin》2010,60(10):1667-1673

Spills from wrecks are a potential major source of pollution in the deep ocean. However, not much is known about the fate of a spill at several kilometers depth, beyond the oceans continental shelves. Here, we report the phase distribution of hydrocarbons released from the wrecks of the Prestige tanker, several years after it sank in November 2002 to depths between 3500 and 3800 m. The released oil reached the surface waters above the wrecks without any signs of weathering and leaving an homogenous signature throughout the water column. At depths of several kilometers below the sea surface, the occurrence and spread of the deep sea oil spill could be evaluated better by quantifying and characterizing the dissolved hydrocarbon signature, rather than just the investigation of hydrocarbons in the suspended particulate matter.  相似文献   

Subsea Channels and Incidence of Thermogenic Hydrocarbons in the Mid-proximal Bengal Fan, West of the Andaman-Nicobar Islands     

A. Bandopadhyay  R. R. Bandyopadhyay 《Marine Georesources & Geotechnology》1999,17(1):1-16

Mid-fan areas in the Bay of Bengal to the west of the Andaman-Nicobar Islands and to the east of the 90 E ridge display remarkable channel-levee and interlevee characteristics over the seabed. These subsea channels at 3,000 m or more water depth have specific orientations along NNE or NNW. Most of these major and minor channels are at present inactive, except one running along the eastern part of the area following the reported subduction suture (Currey et al., 1979). The other channels in the western part retain the configuration of a floor-bank combination but are covered with a thin deposition of pelagic organisms without any significant terrigenous inputs to a depth of around 25 cm below the seabed. On the other hand, the active channel to the east is filled with continuous hemipelagic to terrigenous inputs up to at least 1.5 m bsf. The pelagic organisms of the upper 25 cm of seabed over the inactive channels as well as in their banks and interlevee areas are mainly represented by foraminiferal tests and thus constitute foraminiferal ooze. Most of the seafloor is covered by such ooze except in the easternmost part, where the active channel brings a terrigenous influx in the form of turbidites. The fan deposition has been restricted to the easternmost active channel since the early Holocene. The age of the pelagites that constitute the 25-cm top sediment slice is assumed to represent about 8,000 years, calculated at the rate of deposition of 3 cm 1,000 years (Kennet, 1982). Thus, most of the western seabed has not experienced any fan deposition during the last 8,000 years. However, below 25 cm, the entire area is seen to have experienced fan deposition as evidenced by occurrence of terrigenous silt and clay. Significantly, incidence of thermogenic hydrocarbons is proved in the levee-in terlevee complexes of the central part. Being closer to the subduction zone, gas seepages through pervasive fissures are perhaps more pronounced here.  相似文献   

Recognizing and compensating for interference from the sediment’s background organic matter and biodegradation during interpretation of biomarker data from seafloor hydrocarbon seeps: An example from the Marco Polo area seeps,Gulf of Mexico,USA     

Harry Dembicki Jr. 《Marine and Petroleum Geology》2010

A suite of seep samples from the vicinity of the Marco Polo field in the Green Canyon area of the Gulf of Mexico provides an exceptional opportunity to study the impact of interference from sediment background organic matter and alteration by biodegradation on thermogenic hydrocarbons from seafloor seeps. These seep samples contain a range in both the concentration of seeped hydrocarbons present and level of biodegradation experienced. In addition, the subsurface oil that sources the seepage was available for comparison.  相似文献   

The cone penetration test and 2D imaging resistivity as tools to simulate the distribution of hydrocarbons in soil     

《Physics and Chemistry of the Earth》2016

The purpose of geophysical electrical surveys is to determine the subsurface resistivity distribution by making measurements on the ground surface. From these measurements, the true resistivity of the subsurface can be estimated. The ground resistivity is related to various geological parameters, such as the mineral and fluid content, porosity and degree of water saturation in the rock. Electrical resistivity surveys have been used for many decades in hydrogeological, mining and geotechnical investigations. More recently, they have been used for environmental surveys. To obtain a more accurate subsurface model than is possible with a simple 1-D model, a more complex model must be used. In a 2-D model, the resistivity values are allowed to vary in one horizontal direction (usually referred to as the x direction) but are assumed to be constant in the other horizontal (the y) direction. A more realistic model would be a fully 3-D model where the resistivity values are allowed to change in all three directions. In this research, a simulation of the cone penetration test and 2D imaging resistivity are used as tools to simulate the distribution of hydrocarbons in soil.  相似文献   

Porosity and hydrocarbon distribution in the North Sea chalk reservoirs   总被引：1，自引：0，他引：1  

Michel D'Heur 《Marine and Petroleum Geology》1984,1(3):211-238

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