An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan     

Yasumasa Ogawa  Naotatsu Shikazono  Daizo Ishiyama  Hinako Sato  Toshio Mizuta 《Mineralium Deposita》2005,39(8):813-821

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz  相似文献   

绿柱石与硅铍石原位结晶实验研究     

王娴  李建康  丁欣  张德会 《地质论评》2016,62(S1):407-408

绿柱石与硅铍石均为铍矿物家族中的主要成员,是重要的工业铍矿物,利用背散射和电子探针研究矿物特性时,常可见两者共生或发生交代的现象（饶灿,2009;Reyf, 2008; Evensen, 1999）,其结晶条件对于成矿环境与成矿机制均具有重要的指示意义。前人已进行了关于绿柱石,硅铍石等铍矿物稳定性的实验研究,但研究多采用高温淬火的高温高压实验装置,误差大,且无法原位观测矿物结晶习性（王振杰, 1992;Sirbescu et al., 2009）,本文利用热液金刚石压腔,原位观测了绿柱石与硅铍石的结晶过程,得到了它们结晶的温压条件及结晶习性。  相似文献   

苏鲁超高压变质带超镁铁岩深部碳酸盐交代作用的证据     

陈世忠  杨经绥  许志琴  朱筱婷 《地质学报》2016,90(10):2721-2732

中国大陆科学钻探工程第三先导孔(PP3钻孔),位于秦岭-大别-苏鲁超高压造山带的东部,赣榆岗上超镁铁岩体中。钻孔中超镁铁岩的岩性包括纯橄岩和石榴超镁铁岩等,该超镁铁岩的SiO_2含量均值在43.68%,变化范围为41.9%~47.11%;MgO均值在44.71%,变化范围为47.12%~48.62%;Cr_2O_3均值在0.39%,变化范围为0.30%~0.47%;CaO均值0.12%(变化范围为0.006%~0.34%);Na2O均值在0.05%(变化范围为0.005%~0.32%)。超镁铁质岩的Mg#(Mg/(Mg+Fe)×100)稳定在91.9~93.0之间,Cr#(Cr/(Cr+Fe)×100)均值在38,较高;变化在30~45之间,变化小。其中闪石化金云母超镁铁岩具有最低的值(Cr#=19)。Ni含量在2100×10~(-6)~2500×10~(-6),CaO含量均值为0.13%,Al_2O_3含量均值为0.41%。岩体成分均一,表现为高镁,低钙和低铝的特征。超镁铁岩的不相容元素和稀土元素总量很低,稀土元素总量均值在0.60×10~(-6)。(La/Yb)N比值在6.9~51.2,均值在16.1,重稀土元素严重亏损,是中国东部最亏损的地幔岩之一。超镁铁岩中橄榄石成分(Fo在88.7~93.1之间,Fa在6.8~11.1之间),从早期到晚期,岩石Fo值从93→91~92.4→88.7~89.1。铬尖晶石Cr#值从51到89变化,TiO_2和MnO_2值分别低于0.26%和0.46%,晚期铬尖晶石Cr#值增大,Ti含量减小。单斜辉石由透辉石(Wo_(45.9)8En_(47.89)Fs_(2.73)Ac_(3.39))和顽透辉石(Wo_(27.61)En_(68.78)Fs_(2.27)Ac_(1.34))两种,透辉石(Cpx_Ⅰ)在顽透辉石(Cpx_Ⅱ)中呈被交代的残余粒状。角闪石和金云母呈明显的条带状和脉状,局部发育。岩石具有弱的Na和K交代作用,较高的Sr和Ba等元素,亏损高场强元素(HSFE),以及特征的稀土元素和微量元素配分曲线;岩石中主要组成矿物橄榄石从早期到晚期,矿物Mg#指数下降(Mg#从93→88);单斜辉石中可看到透辉石被顽透辉石交代现象;次生角闪石和金云母的形成等特征都显示超镁铁岩经历了碳酸盐交代作用。在超镁铁岩矿物橄榄石中发现细小白云石和菱镁矿等碳酸盐矿物更有力证明了苏鲁超高压变质带超镁铁岩经历了深部碳酸盐交代作用。PP3钻孔超镁铁岩属于强烈亏损地幔岩区域,单斜辉石和角闪石等含水矿物在超镁铁岩中含量低,交代作用的范围和规模有限,且交代作用在动力学上是快速的和不平衡的过程。  相似文献   

Kinetics of sulfide mineral oxidation in seawater: Implications for acid generation during in situ mining of seafloor hydrothermal vent deposits     

《Applied Geochemistry》2016

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塔西台地寒武纪沉积环境演化与海陆耦合     

刘沛显  关平  冯帆  贾文博  张巍  邓世彪  金亦秋 《沉积学报》2016,34(6):1092-1107

碳酸盐岩台地作为陆地与深海间的过渡带,其沉积记录了海洋和邻近陆地的演化。结合已有的沉积学工作,对塔里木盆地西部台地寒武系碳酸盐岩进行全岩及酸不溶物地球化学研究。塔西台地寒武纪主要发育局限台地、局限-蒸发台地或蒸发台地相沉积。碳酸盐岩的地球化学特征主要受沉积环境和成岩作用影响,对研究区寒武系白云岩来说,其元素组成极易受沉积微相的控制,氧同位素组成则很可能已被成岩作用改造,仅原生、准同生白云岩的Sr/Ba、Fe/Mn和C同位素可反映沉积相演化对应的古盐度、离岸距离等沉积环境特征的变化,酸不溶物化学蚀变指数（CIA值）则指示邻近陆地的化学风化强度与气候特征。寒武纪时期,塔西台地在相对海平面较高时发育局限台地相沉积,以水体盐度较低、沉积环境离岸较远和生物活动相对较弱为特征,陆地化学风化强度适中,气候温暖湿润;在相对海平面较低时发育蒸发台地相沉积,具有水体盐度较高、沉积环境离岸较近和生物活动相对较强等特点,陆地化学风化强烈,气候炎热极端;在相对海平面适中时发育局限-蒸发台地,沉积环境和邻近陆地的特征介于前述二者之间。沉积相演化对应的较长周期的海陆演化可能主要受全球海平面升降及宏观气候变化控制,具体表现为相对海平面升降所导致的海相沉积环境的变化,以及气候变化引起的陆地化学风化强度的变化。寒武纪塔西台地所处区域的海洋-陆地演化具有高度耦合的特征。  相似文献   

Hydrothermal Fluid Sources of the Fengjia Barite–fluorite Deposit in Southeast Sichuan,China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes          下载免费PDF全文

Hao Zou  Shou‐ting Zhang  An‐qing Chen  Yi Fang  Zhao‐fa Zeng 《Resource Geology》2016,66(1):24-36

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm³. The fluid composition was mainly H₂O (>91.33%), followed by CO₂, CH₄ and traces of C₂H₆, CO, Ar, and H₂S. The dominant cation was Na⁺ and the dominant anion Cl^‐, followed by Ca²⁺, SO₄^2‐, K⁺, and Mg²⁺, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H₂O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.  相似文献   

Testing and modeling of the mechanical behavior of dolomite in the Wudongde hydropower plant     

J. C. Zhang  W. Y. Xu  H. L. Wang  Q. X. Meng 《Geomechanics and Geoengineering》2016,11(4):270-280

In order to understand the mechanical behaviours of the surrounding rocks in the underground caverns of the Wudongde hydropower plant, triaxial tests are performed on a type of dolomite. It is revealed that damage induced by crack development is the main factor controlling the nonlinear plastic deformation and failure behaviour of the dolomite in both pre- and post-peak regimes. Based on this understanding, a coupled elastoplastic damage model is developed for capturing the dolomite’s mechanical behaviours. In the model, the effects of plasticity and damage on rocks is described by introducing plastic hardening and damage softening commonly in the plastic yield surface. Which are both derived from a suitable Helmholtz free energy function. The model is used to simulate the triaxial tests. Comparisons between test results and the numerical modelling show that the developed model is capable of describing the macro mechanical behaviours of the Wudongde dolomite.  相似文献   

从成岩-蚀变特征探讨塔深1井白云岩储层成因     

尤东华  王亮  胡文瑄  钱一雄  王小林  陈强路  张军涛 《岩石矿物学杂志》2018,37(1):34-46

塔深1井钻遇的寒武系地层属于中寒武统阿瓦塔格组和上寒武统丘里塔格下亚群。阿瓦塔格组以灰色-深灰色粉晶-细晶藻白云岩为主,丘里塔格下亚群以灰色-浅灰色晶粒结构白云岩与残余亮晶结构白云岩为主。藻白云岩在阴极发光下以明亮的中等强度砖红色-桔黄色为主要特点,具有相对偏重的δ18O值(-6.3‰~-4.5‰,平均为-5.3‰,VPDB)、相对较高的稀土总量以及与正常海相碳酸盐岩相似的稀土配分样式。晶粒白云岩与残余亮晶结构白云岩在阴极发光下以偏暗的中等强度蓝紫色-砖红色为主要特点,具有相对偏轻的δ18O值(-9.2‰~-5.7‰,平均为-7.5‰,VPDB)、相对偏低的稀土总量、Eu正异常与重稀土明显亏损为特点的稀土配分模式。阿瓦塔格组和丘里塔格下亚群白云岩在上述岩石学特征和地球化学特征上的差异表明储层发育的成岩-蚀变过程存在差异。研究认为,埋藏较深的阿瓦塔格组优质储层的形成受多种因素控制,其中准同生期大气淡水作用下石膏结核的溶解及非稳定碳酸盐矿物的溶解奠定了基础,后期成岩改造及流体作用进行了强化,局部遭充填破坏。  相似文献   

Geochemical Constraints on the Origin of Banded Iron Formation‐Hosted Iron Ore from the Archaean Ntem Complex (Congo Craton) in the Meyomessi Area,Southern Cameroon     

《Resource Geology》2018,68(3):287-302

Banded iron formations (BIFs) are the most significant source of iron in the world. In this study, we report petrographic and geochemical data of the BIF from the Meyomessi area in the Ntem Complex, southern Cameroon, and discuss their genesis and the iron enrichment process. Field investigations and petrography have revealed that the studied BIF samples are hard; compact; weakly weathered; and composed of magnetite, subordinate quartz, and geothite. The geochemical composition of the whole rock reveals that iron and silica represent more than 98 wt% of the average composition, whereas Al₂O₃, TiO₂, and high‐field strength elements (HFSE) contents are very low, similar to detritus‐free marine chemical precipitates. The total iron (TFe) contents range from 48.71 to 65.32 wt % (average of 53.29 wt %) and, together with the low concentrations of deleterious elements (0.19 wt % P on average), are consistent with medium‐grade iron ores by global standards. This interpretation is confirmed by the SiO₂/Fe₂O_3total versus (MgO + CaO + MnO)/Fe₂O_3total discrimination plot in which most of the Meyomessi BIF samples fall in the field of medium‐grade siliceous ore. Only one sample (MGT94) plots in the high‐grade magnetite–geothite ore domain. The high Fe/Ti (376.36), Fe/Al (99.90), and Si/Al (29.26) ratios of the sample are consistent with significant hydrothermal components. The rare earth elements (REE) contents of the studied BIF samples are very low (∑REE: 0.81–1.47 ppm), and the Post‐Archaean Australian Shale (PAAS)‐normalized patterns display weak positive Eu anomalies (Eu/Eu*: 1.15–1.33), suggesting a syngenetic low‐temperature hydrothermal solutions, similar to other BIF worldwide. However, the Meyomessi BIFs show high Fe contents when compared to the other BIFs. This indicates an epigenetic mineralization process affected the Meyomessi BIF. From the above results and based on the field and analytical data, we propose that the genetic model of iron ores at the Meyomessi area involves two stages of the enrichment process, hypogene enrichment of BIF protore by metamorphic and magmatic fluids followed by supergene alteration as indicated by the presence of goethite in the rocks.  相似文献   

Origin of natural sulfur-metal chimney in the Tangyin hydrothermal field,Okinawa Trough: constraints from rare earth element and sulfur isotopic compositions     

《China Geology》2018,1(2):225-235

For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10^–6–4.580×10^–6) followed by metal sulfides (ΣREE=1.71×10^–6–11.63×10^–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10^–6–33.06×10^–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)_N, La/Sm, (Gd/Yb)_N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ³⁴S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ³⁴S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.  相似文献