Multiple techniques for mineral identification on Mars:: a study of hydrothermal rocks as potential analogues for astrobiology sites on Mars     

Janice L. Bishop  Enver Murad  Rocco L. Mancinelli 《Icarus》2004,169(2):311-323

Spectroscopic studies of Mars analog materials combining multiple spectral ranges and techniques are necessary in order to obtain ground truth information for interpretation of rocks and soils on Mars. Two hydrothermal rocks from Yellowstone National Park, Wyoming, were characterized here because they contain minerals requiring water for formation and they provide a possible niche for some of the earliest organisms on Earth. If related rocks formed in hydrothermal sites on Mars, identification of these would be important for understanding the geology of the planet and potential habitability for life. XRD, thermal properties, VNIR, mid-IR, and Raman spectroscopy were employed to identify the mineralogy of the samples in this study. The rocks studied here include a travertine from Mammoth Formation that contains primarily calcite with some aragonite and gypsum and a siliceous sinter from Octopus Spring that contains a variety of poorly crystalline to amorphous silicate minerals. Calcite was detected readily in the travertine rock using any one of the techniques studied. The small amount of gypsum was uniquely identified using XRD, VNIR, and mid-IR, while the aragonite was uniquely identified using XRD and Raman. The siliceous sinter sample was more difficult to characterize using each of these techniques and a combination of all techniques was more useful than any single technique. Although XRD is the historical standard for mineral identification, it presents some challenges for remote investigations. Thermal properties are most useful for minerals with discrete thermal transitions. Raman spectroscopy is most effective for detecting polarized species such as CO₃, OH, and CH, and exhibits sharp bands for most highly crystalline minerals when abundant. Mid-IR spectroscopy is most useful in characterizing Si-O (and metal-O) bonds and also has the advantage that remote information about sample texture (e.g., particle size) can be determined. Mid-IR spectroscopy is also sensitive to structural OH, CO₃, and SO₄ bonds when abundant. VNIR spectroscopy is best for characterizing metal excitational bands and water, and is also a good technique for identification of structural OH, CO₃, SO₄, or CH bonds. Combining multiple techniques provides the most comprehensive information about mineralogy because of the different selection rules and particle size sensitivities, in addition to maximum coverage of excitational and vibrational bands at all wavelengths. This study of hydrothermal rocks from Yellowstone provides insights on how to combine information from multiple instruments to identify mineralogy and hence evidence of water on Mars.  相似文献   

BOOK REVIEWS     

《The Professional geographer》1987,39(3):363-386

Book Reviewed in this article: Hillslope Processes. Binghamton Symposia in Geomorphology International Series: 16. Athol D. Abrahams , ed. The Atlas of Central America and the Caribbean. The Diagram Group . The Cultural Atlas of Islam. Isma'il R. al Faruqi and Lois Lamaya'al Faruqi . Atlas of Israel Contemporary Africa: Development, Culture and the State. Morag Bell . Fundamentals of Physical Geography. David Briggs and Peter Smithson . The Bicentennial Census: New Directions for Methodology in 1990. Constance F. Citro and Michael L. Cohen , eds . World Patterns of Modern Urban Change: Essays in Honor of Chauncy D. Harris. Michael P. Conzen , ed . New Directions for Agriculture and Agricultural Research: Neglected Dimensions and Emerging Alternatives. Kenneth A. Dahlberg , ed . Water Resources Atlas of Florida. E.A. Fernald and D.J. Patton , eds . Landscape Ecology. R.T.T. Forman and M. Godron . The Myth of the North American City: Continentalism Challenged. Michael Goldberg and John Mercer . The Permafrost Environment. Stuart A. Harris . Climate and Circulation of the Tropics. Stefan Hastenrath . The Island of South Georgia. Robert Headland . The Making of Urban Europe, 1000-1950. Paul M. Hohenberg and Lynn Hollen Lees . Bombay in Transition: The Growth and Social Ecology of a Colonial City, 1889–1980. Meera Kosambi . Plant Closings; Public or Private Choices? Richard B. McKenzie , ed . Malaysia: Tradition, Modernity and Islam. R.S. Milne and Diane K. Mauzy . Technology on the Frontier: Mining in Old Ontario. Dianne Newell . The Maritime Political Boundaries of the World. J.R.V. Prescott . Tall Office Buildings in the United States. James W. Pygman and Richard Kateley (Real Estate Research Corporation). Technology, Regions, and Policy. John Rees , ed . The United States and the Regional Organization of Asia and the Pacific: 1965-1985. W.W. Rostow . Renewable Energy: Progress, Prospects. Stephen W. Sawyer Wisconsin Foundations. Gwen Schultz . Dwelling, Place and Environment: Towards a Phenomenology of Person and World. David Seamon and Robert Mugerauer , eds . Power and Place: Canadian Urban Development in the North American Context. Gilbert A. Stelter and Alan F.J. Artibise , eds . Small Firms in Regional Economic Development: Britain, Ireland and the United States. D. J. Storey , ed . Mathematical Methods in Human Geography and Planning. A. G. Wilson and R. J. Bennett . El Niño North: Niño Effects on the Eastern Subarctic Pacific Ocean. W. S. Wooster and D. L. Fluharty , eds . The Soviet Iron and Steel Industry. Craig ZumBrunnen and Jeffrey Osleeb .  相似文献   

Sulphur-bearing carbon chains in IRC+10216     

T.J. Millar  J.R. Flores  A.J. Markwick 《Monthly notices of the Royal Astronomical Society》2001,327(4):1173-1177

We have updated the chemical model of IRC+10216 developed by Millar, Herbst & Bettens to include recent routes to the formation of sulphuretted hydrocarbons. The routes are based on a quantum chemical study of the S+C₂H system. In addition, we have altered the parent species for sulphur to reflect new observational results. We find that the model calculations give excellent agreement with the observed column densities, and discuss the significance of these reactions to the formation of species as yet unobserved and to dark interstellar clouds.  相似文献   

Injection of molecules from the surfaces of grains into the gas phase chemistry of an expanding cloud     

J.G.L. Rae  T.W. Hartquist  D.A. Williams 《Astrophysics and Space Science》2004,291(2):177-184

We present model results for the chemistry in an expanding cloud or clump in which molecules are injected into the gas phase from grain surfaces when the clump reaches a certain visual extinction A _v during the expansion. We consider separately injection at two different values of A _v, and include a representative large hydrocarbon, C₆H, and sulphur-bearing molecule, H₂SO₄, as well as H₂O and CO. We examine the abundances of certain molecules which have been observed in diffuse and translucent clouds, and compare the results obtained for these abundances with and without an injection during expansion. We also compare our results withpublished observations, and conclude that in most clouds an injection of molecules has occurred.  相似文献   

Magnetic field in the intracluster medium: Rydberg matter with almost free electrons     

Shahriar Badiei  Leif Holmlid 《Monthly notices of the Royal Astronomical Society》2002,335(4):L94-L98

  相似文献   

Solar, interplanetary, planetary, and related extra-solar system science for LOFAR     

Iver H. Cairns   《Planetary and Space Science》2004,52(15):1423-1434

The low frequency array (LOFAR) radiotelescope will be a powerful instrument for answering fundamental, unresolved scientific questions concerning solar system radio phenomena and related emissions from nearby stellar systems. This paper reviews the phenomena, emission mechanisms, open scientific questions, and LOFAR's capabilities. LOFAR will detect metric solar radio bursts in the corona and interplanetary medium, out to distances of order 10 solar radii, as well as Jovian radio emissions. Arguments are given that LOFAR may be sufficiently sensitive to detect stellar analoges of solar type II and III bursts, and may detect cyclotron-maser emissions from extra-solar planets. LOFAR may also aid space weather research, by passively detecting coronal mass ejections (CMEs) via scintillation and Faraday rotation effects, or by detecting radar signals bounced off CMEs and coronal density structures if a suitable solar radar is developed.  相似文献   

Modeling global impact effects on middle-sized icy bodies: applications to Saturn's moons     

Lindsey S Bruesch  Erik Asphaug 《Icarus》2004,168(2):457-466

Disrupted terrains that form as a consequence of giant impacts may help constrain the internal structures of planets, asteroids, comets and satellites. As shock waves and powerful seismic stress waves propagate through a body, they interact with the internal structure in ways that may leave a characteristic impression upon the surface. Variations in peak surface velocity and tensile stress, related to landform degradation and surface rupture, may be controlled by variations in core size, shape and density. Caloris Basin on Mercury and Imbrium Basin on the Moon have disturbed terrain at their antipodes, where focusing is most intense for an approximately symmetric spheroid. Although, the icy saturnian satellites Tethys, Mimas, and Rhea possess giant impact structures, it is not clear whether these structures have correlated disrupted terrains, antipodal or elsewhere. In anticipation of high-resolution imagery from Cassini, we investigate antipodal focusing during giant impacts using a 3D SPH impact model. We first investigate giant impacts into a fiducial 1000 km diameter icy satellite with a variety of core radii and compositions. We find that antipodal disruption depends more on core radius than on core density, suggesting that core geometry may express a surface signature in global impacts on partially differentiated targets. We model Tethys, Mimas, and Rhea according to their image-derived shapes (triaxial for Tethys and Mimas and spherical for Rhea), varying core radii and densities to give the proper bulk densities. Tethys shows greater antipodal values of peak surface velocity and peak surface tensile stress, indicating more surface damage, than either Mimas or Rhea. Results for antipodal and global fragmentation and terrain rupture are inconclusive, with the hydrocode itself producing global disruption at the limits of model resolution but with peak fracture stresses never exceeding the strength of laboratory ice.  相似文献   

BOOK REVIEWS     

《The Professional geographer》1983,35(4):488-524

Book Reviewed in this article: Main Street: Northeastern Oregon: The Founding and Development of Small Towns . Barbara Ruth Bailey . Food Politics: The Regional Conflict . David N. Balaam and Michael J. Carey , eds. The International Economy and Industrial Development: Trade and Investment in the Third World . R. Ballance , J. Ansari and H. Singer . Neighborhoods in Urban America . Ronald H. Bayor , ed. The English Heartland . By Robert Beckinsale and Monica Beckinsale . Regional Dimensions of Industrial Policy . Michael E. Bell and Paul S. Lande , eds. Tension Areas of the World . D. Gordon Bennett , ed. Latin America: an Introductory Survey . B. W. Blouet and O. M. Blouet , eds. Integration and Division: Geographical Perspectives on the Northern Ireland Problem . Frederick W. Boal and J. Neville H. Douglas , eds. Energy and Land Use . Robert W. Burchell and David Listokin , eds. Slopes and Weathering . Michael Clarke and John Small . Alaska's Rural Development . Peter G. Cornwall and Gerald Mc Beath , eds. The Politics of Park Design: A History of Urban Parks in America . Galen Cranz . World Congress on Land Policy, 1980, Proceedings . Matthew Cullen and Sharon Woolery , eds. Oregon Divided: A Regional Geography . Samuel N. Dicken and Emily F. Dicken . Urban Food Marketing and Third World Rural Development . T. Scarlett Epstein . South Africa: Spatial Frameworks for Development . T. J. D. Fair . Institutions and Geographical Patterns . Robin Flowerdew , ed. Industrialization of U.S. Agriculture, An Interpretive Atlas . Howard F. Gregor . Planning Theory: Prospects for the 1980s . Patsy Healy , Glen Mc Dougall and Michael J. Thomas , eds. Neighborhood Mobilization: Redevelopment and Response . Jeffrey R. Henig . The American Urban System: A Geographical Perspective . R. J. Johnston . Climate, History and the Modern World . Hubert H. Lamb . Climate and History: Studies in Past Climates and Their Impact on Man . T. M. L. Wigley , M. J. Ingram and G. Farmer . China: Railways and Agricultural Development, 1875–1935 . Ernest P. Liang . A Desirable Energy Future—A National Perspective . Robert S. Livingston , T. D. Anderson , T. M. Besmann , M. Olszewski , A. M. Perry , and C. D. West . Topothesia: Essays Presented to T. S. Ó Máille . B. S. Mac Aodha , ed. Transportation for the Poor: Research in Rural Mobility . Hal S. Maggied . Land Uses in American Cities . Harold M. Mayer and Charles R. Haves . Industrial Organisation and Location . Philip Mc Dermott and Michael Taylor . Human Adaptability: an Introduction to Ecological Anthropology . Emilio F. Moran . Regional Analysis and the New International Division of Labor . Frank Moulaert and Patricia W. Salinas , eds. The Nuclear War Atlas. Victoriaville, Quebec, Canada : Urbanization and Environmental Quality . Isao Orishimo . The Garden of Eden: The Botanic Garden and the Re-Creation of Paradise . John Prest . Earthfire, The Eruption of Mount St. Helens . Charles Rosenfeld and Robert Cooke . Contest for the South China Sea . Marwyn S. Samuels . The Future of the Wetlands: Assessing Visual-Cultural Values . Richard C. Smardon , ed. Tucson: the Life and Times of An American City. C. L. Sonnichsen . The Geography of Multinationals . Michael Taylor and Nigel Thrift , eds. Impact of Marine Pollution on Society . Virginia Tippie and Dana Kester . Reviving the Industrial City: the Politics of Urban Renewal in Lyon and Birmingham . Jerry A. Webman . Andean Reflections: Letters from Carl O. Sauer While on a South American Trip under a Grant from the Rockefeller Foundation, 1942 . Robert C. West , ed. Cartographic Drawing with Computers . P. Yoeli .  相似文献   

Mapping of the Culann-Tohil region of Io from Galileo imaging data     

David A Williams  Paul M Schenk  Laszlo P Keszthelyi  Elizabeth P Turtle  Windy L Jaeger  Moses P Milazzo  Ronald Greeley 《Icarus》2004,169(1):80-97

We have used Galileo spacecraft data to produce a geomorphologic map of the Culann-Tohil region of Io's antijovian hemisphere. This region includes a newly discovered shield volcano, Ts?i Goab Tholus and a neighboring bright flow field, Ts?i Goab Fluctus, the active Culann Patera and the enigmatic Tohil Mons-Radegast Patera-Tohil Patera complex. Analysis of Voyager global color and Galileo Solid-State Imaging (SSI) high-resolution, regional (50-330 m/pixel), and global color (1.4 km/pixel) images, along with available Galileo Near-Infrared Mapping Spectrometer (NIMS) data, suggests that 16 distinct geologic units can be defined and characterized in this region, including 5 types of diffuse deposits. Ts?i Goab Fluctus is the center of a low-temperature hotspot detected by NIMS late during the Galileo mission, and could represent the best case for active effusive sulfur volcanism detected by Galileo. The Culann volcanic center has produced a range of explosive and effusive deposits, including an outer yellowish ring of enhanced sulfur dioxide (SO₂), an inner red ring of SO₂ with short-chain sulfur (S₃-S₄) contaminants, and two irregular green diffuse deposits (one in Tohil Patera) apparently produced by the interaction of dark, silicate lava flows with sulfurous contaminants ballistically-emplaced from Culann's eruption plume(s). Fresh and red-mantled dark lava flows west of the Culann vent can be contrasted with unusual red-brown flows east of the vent. These red-brown flows have a distinct color that is suggestive of a compositional difference, although whether this is due to surface alteration or distinct lava compositions cannot be determined. The main massif of Tohil Mons is covered with ridges and grooves, defining a unit of tectonically disrupted crustal materials. Tohil Mons also contains a younger unit of mottled crustal materials that were displaced by mass wasting processes. Neighboring Radegast Patera contains a NIMS hotspot and a young lava lake of dark silicate flows, whereas the southwest portion of Tohil Patera contains white flow-like units, perhaps consisting of ‘ponds’ of effusively emplaced SO₂. From 0°-15° S the hummocky bright plains unit away from volcanic centers contains scarps, grooves, pits, graben, and channel-like features, some of which have been modified by erosion. Although the most active volcanic centers appear to be found in structural lows (as indicated by mapping of scarps), DEMs derived from stereo images show that, with the exception of Tohil Mons, there is less than 1 km of relief in the Culann-Tohil region. There is no discernable correlation between centers of active volcanism and topography.  相似文献   

Shocked plagioclase signatures in Thermal Emission Spectrometer data of Mars     

Jeffrey R. Johnson  Matthew I. Staid  Kris Becker 《Icarus》2006,180(1):60-74

The extensive impact cratering record on Mars combined with evidence from SNC meteorites suggests that a significant fraction of the surface is composed of materials subjected to variable shock pressures. Pressure-induced structural changes in minerals during high-pressure shock events alter their thermal infrared spectral emission features, particularly for feldspars, in a predictable fashion. To understand the degree to which the distribution and magnitude of shock effects influence martian surface mineralogy, we used standard spectral mineral libraries supplemented by laboratory spectra of experimentally shocked bytownite feldspar [Johnson, J.R., Hörz, F., Christensen, P., Lucey, P.G., 2002b. J. Geophys. Res. 107 (E10), doi:10.1029/2001JE001517] to deconvolve Thermal Emission Spectrometer (TES) data from six relatively large (>50 km) impact craters on Mars. We used both TES orbital data and TES mosaics (emission phase function sequences) to study local and regional areas near the craters, and compared the differences between models using single TES detector data and 3×2 detector-averaged data. Inclusion of shocked feldspar spectra in the deconvolution models consistently improved the rms errors compared to models in which the spectra were not used, and resulted in modeled shocked feldspar abundances of >15% in some regions. However, the magnitudes of model rms error improvements were within the noise equivalent rms errors for the TES instrument [Hamilton V., personal communication]. This suggests that while shocked feldspars may be a component of the regions studied, their presence cannot be conclusively demonstrated in the TES data analyzed here. If the distributions of shocked feldspars suggested by the models are real, the lack of spatial correlation to crater materials may reflect extensive aeolian mixing of martian regolith materials composed of variably shocked impact ejecta from both local and distant sources.  相似文献