Determination of Boron Concentration in Geochemical Reference Materials Extracted by Pyrohydrolysis and Measured by ICP‐MS          下载免费PDF全文

Agnès Michel  Johanna Noireaux  Mickaël Tharaud 《Geostandards and Geoanalytical Research》2015,39(4):489-495

This article presents new boron concentrations for nine geochemical reference materials (GS‐N, FK‐N, GL‐O, BX‐N, DT‐N, AN‐G, GH, Mica‐Fe, Mica‐Mg). After extraction by a modified pyrohydrolysis technique, boron concentrations were measured by ICP‐MS. The blank levels for the whole procedure were 0.091 ± 0.020 ng ml^?1 or 14 ± 5 ng of boron in total. The method was first validated by measuring nine reference materials with known boron concentrations. The determined boron concentrations are all within the range of recommended or published values, which means that the yields were 100%, and show precisions below 10% for samples containing over 2 μg g^?1 of boron.  相似文献   

Platinum‐Group Element Results for Two Cobalt‐Rich Seamount Crust Ultra‐Fine Reference Materials: MCPt‐1and MCPt‐2     

Yimin Wang  Xiaohong Wang  Wenjun Qu  Yushu Gao  Tiexin Gu  Xingtao Fan  S.I. Andreev  Xuefa Shi 《Geostandards and Geoanalytical Research》2011,35(3):341-352

Two Co‐rich seamount crust reference materials, MCPt‐1 and MCPt‐2, were prepared using ultra‐fine particle size milling technique and characterised for the platinum‐group elements (PGEs). The raw material for these two reference materials was collected separately from the Magellan seamounts of the western Pacific Ocean and the seamounts of the central Pacific Ocean by Russian and Chinese scientists. First, they were ground by ball mill to a ?200 mesh powder, then further processed by ultra‐fine jet mill and well‐mixed. The particle size distributions of the samples were tested by a laser particle analyser; the average particle size was 1.8 and 1.5 μm (equal to about 2000 mesh) respectively. The homogeneity of six major and minor elements in these two materials was tested at the milligram level of sampling mass by high‐precision wavelength dispersive X‐ray fluorescence (XRF) spectrometry and at the microgram level of sampling mass by electron probe microanalyser. The homogeneity of more than forty trace elements, including Pt, was tested at the microgram level of sampling mass by LA‐ICP‐MS. Except for Rh, all PGEs were determined by isotope dilution‐ICP‐MS. Platinum in MCPt‐1 and MCPt‐2 was characterised as certified values, whereas the other five PGEs in MCPt‐1 and MCPt‐2 were reported as reference values. In addition, the information values of sixty‐two major, minor and trace elements were obtained by XRF, ICP‐AES and ICP‐MS. The minimum sampling mass for the determination of PGEs was 1 g, while the minimum sampling mass for the determination of the other elements was 2–5 mg.  相似文献   

An Isotope Dilution ICP‐MS Method for the Determination of Mg/Ca and Sr/Ca Ratios in Calcium Carbonate     

Alex C. Gagnon  Jess F. Adkins 《Geostandards and Geoanalytical Research》2011,35(1):23-37

Mg/Ca and Sr/Ca ratios in calcium carbonate are important components of many palaeoclimate studies. We present an isotope dilution method relying on a single mixed spike containing ²⁵Mg, ⁴³Ca and ⁸⁷Sr. Dozens of samples per day, as small as 10 μg of carbonate, could be dissolved, spiked and run in an ICP‐MS with a precision of 0.8% (2 RSD). Two instruments types, a sector field and a quadrupole ICP‐MS, were compared. The best long term precision found was 0.4% (2 RSD), although this increased by up to a factor of two when samples of very different Mg or Sr content were run together in the same sequence. Long term averages for the two instruments concurred. No matrix effects were detected for a range of Ca concentrations between 0.2 and 2 mmol l^‐1. Accuracy, tested by measuring synthetic standard solutions, was 0.8% with some systematic trends. We demonstrate the strength of this isotope dilution method for (a) obtaining accurate results for sample sets that present a broad Mg and Sr range and (b) testing solid carbonates as candidate reference materials for interlaboratory consistency. Mg/Ca and Sr/Ca results for reference materials were in good agreement with values from the literature.  相似文献   

Multi‐Element Determination of Trace Elements in Natural Water Reference Materials by ICP‐SFMS after Tm Addition and Iron Co‐precipitation     

Germain Bayon  Dominique Birot  Claire Bollinger  Jean Alix Barrat 《Geostandards and Geoanalytical Research》2011,35(1):145-153

We report on an improved method for determining trace element abundances in seawater and other natural waters. The analytical procedure involves co‐precipitation on iron hydroxides after addition of a Tm spike, and measurement by inductively coupled plasma‐sector field mass spectrometry (ICP‐SFMS). The validity of the method was assessed through a series of co‐precipitation experiments, using ultra‐diluted solutions of a certified rock reference material (BIR‐1). Results obtained for four natural water reference materials (NASS‐5, CASS‐4, SLEW‐3, SLRS‐4) are in agreement with published working values for rare earth elements, yttrium, vanadium and, when available, for hafnium, zirconium, thorium and scandium. A set of proposed values with uncertainties typically better than 8% RSD is proposed for Hf, Zr and Th.  相似文献   

Precise Determination of Silicon Isotopes in Silicate Rock Reference Materials by MC‐ICP‐MS     

Thomas Zambardi  Franck Poitrasson 《Geostandards and Geoanalytical Research》2011,35(1):89-99

A HF‐free sample preparation method was used to purify silicon in twelve geological RMs. Silicon isotope compositions were determined using a Neptune instrument multi‐collector‐ICP‐MS in high‐resolution mode, which allowed separation of the silicon isotope plateaus from their interferences. A 1 μg g^‐1 Mg spike was added to each sample and standard solution for online mass bias drift correction. δ³⁰Si and δ²⁹Si values are expressed in per mil (‰), relative to the NIST SRM 8546 (NBS‐28) international isotopic RM. The total variation of δ³⁰Si in the geological reference samples analysed in this study ranged from ‐0.13‰ to ‐0.29‰. Comparison with δ²⁹Si values shows that these isotopic fractionations were mass dependent. IRMM‐17 yielded a δ³⁰Si value of ‐1.41 ± 0.07‰ (2s, n = 12) in agreement with previous data. The long‐term reproducibility for natural samples obtained on BHVO‐2 yielded δ³⁰Si = ‐0.27 ± 0.08‰ (2s, n = 42) on a 12 month time scale. An in‐house Si reference sample was produced to check for the long‐term reproducibility of a mono‐elemental sample solution; this yielded a comparable uncertainty of ± 0.07‰ (2s, n = 24) over 5 months.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Diffuse Baryons in Cosmic Structures     

Alfonso Cavaliere 《Astrophysics and Space Science》2004,294(1-2):109-124

I review the processes that govern the amount and the thermal state of the hot plasma pervading clusters and groups of galaxies: the gravitational heating driven by the DM merging histories, the radiative cooling of baryons, and the energy fed back by SNe and by AGNs or quasars. I argue that the X-ray emissions and the entropy levels now observed from clusters to groups require the AGNs to contribute substantially to preheat the gas before it falls into clusters, and the quasars to blow some plasma out of groups and galaxies.  相似文献   

ICP算法及其在建筑物扫描点云数据配准中的应用   总被引：5，自引：1，他引：4  

郑德华 《测绘科学》2007,32(2):31-32

ICP算法是三维激光扫描数据处理中点云数据配准的一种高水平的数学方法。本文全面地回顾了ICP算法的研究背景,并重点阐述了迭代最近点法ICP的计算过程及其主要的改进算法;通过建筑物三维激光扫描数据的采集,对基于ICP算法的点云数据配准过程进行了详细地分析。实验分析表明三维激光扫描数据配准后的点云数据质量较大程度上依赖于专业技术人员的数据处理经验和专业知识。  相似文献   

The Geological Significance of a Tuffite Interlayer in the Cretaceous Port Island Formation in Northeastern Hong Kong     

ZHAO Longlong  WANG Lulin  TIAN Mingzhong  WU Fadong 《《地质学报》英文版》2018,92(3):1041-1052

The Port Island Formation(PIF), a typical Cretaceous red bed in Hong Kong, is dominated by non-fossiliferous, reddish clastic rocks, making it difficult to determine the sedimentary age of PIF precisely. Previous studies assigned the PIF to Late Cretaceous provisionally only on the basis of its stratigraphic sequence and lithology. This study identified a tuffite interlayer in the PIF and a zircon UPb age of 128.2±2.7 Ma by LA-ICP-MS method was obtained. It's the first time to date the depositional age of the PIF with a reliable chronological constraint. With the support of stratigraphic evidence, we concluded that the geological age of PIF should be Early Cretaceous rather than Late Cretaceous. Based on the volcanic history of Hong Kong and Southeast China and the distribution of the PIF in Mirs Bay, it is believed that there was no volcanic activity in Hong Kong in ca. 128 Ma. The tuffite interlayer discovered in PIF was formed by the deposition of volcanic ash, which might originate from remote region outside Hong Kong, in an aquatic environment on Port Island. The identification of the tuffite interlayer, as the response to a volcanic event, has great significance not only to the studies of establishment and regional correlation of the strata system and the geological evolution in Hong Kong,but also to the study of volcanic activities in Southeast China.  相似文献   

内蒙古东乌旗达亚纳钨-钼矿成岩成矿时代及其岩体地球化学研究     

向安平  陈毓川  佘宏全  李光明  李应栩 《地质学报》2018,92(1):107-124

内蒙古东乌旗达亚纳钨-钼矿是近年来正在勘查的一个规模有望达中型的新矿床,矿床位于兴蒙造山带中西部,矿床类型为典型的石英脉型黑钨-钼矿,黑钨矿石英脉以近于直立(75°)的平直脉体产出在黑云母花岗岩内或岩体与地层的外接触带,并向下尖灭于岩体内部,主要的矿化蚀变类型有云英岩化、钾长石化、钠长石化、硅化等。伴随黑钨矿化共生大量的辉钼矿,辉钼矿化多产出在黑钨矿石英脉两侧或石英脉内。本文在系统研究矿床地质特征的基础上,对成矿岩体——黑云母花岗岩进行了高精度LA-ICP-MS锆石U-Pb测年及地球化学分析,U-Pb测年结果显示,两件黑云母花岗岩样品(DYN-19、DYN-30)有着一致的U-Pb谐和年龄,分别为134±1Ma(MSWD=0.41)、135±1Ma(MSWD=0.52)。地球化学特征显示,岩体富硅、富碱,SiO_2平均74.43%,Na_2O+K_2O平均8.33%,Na_2O/K_2O平均0.73,明显富钾,属高钾钙碱性系列;Al_2O_3平均为12.72%,铝饱和指数A/CNK全部近1.0,为准铝质到弱过铝质花岗岩类,相对贫Mg;稀土总量较低,ΣREE变化于63.68×10~(-6)~91.11×10~(-6),表现为右倾稀土元素配分模式,弱富集轻稀土,并具有明显的负铕异常,高场强元素Th、U、Nd、Hf明显富集,而Ba、Sr、P、Ti、Nb显著亏损;为壳源重熔型花岗岩的地球化学特征。锆石Hf同位素分析显示,~(176)Hf/~(177)Hf值0.28295~0.28302,ε_(Hf)(t)值+6.4~+8.8,二阶段模式年龄值408~540Ma,年轻的二阶段模式年龄和不大的ε_(Hf)(t)正值,指示了其岩浆源区可能为新生下地壳。同时对矿区7件辉钼矿样品进行了铼-锇同位素分析测试,获得等时线年龄为133±3Ma,MSWD值为2.2。可见成岩年龄和成矿年龄在误差范围内具有一致性,为同一期地质作用的产物,即成岩成矿时代为早白垩世,属燕山期构造岩浆活动的产物。  相似文献