Arsenic Distribution Pattern in Different Sources of Drinking Water and their Geological Background in Guanzhong Basin,Shaanxi, China     

LUO Kunli  ZHANG Shixi  TIAN Yuan  GAO Xing 《《地质学报》英文版》2014,88(3):984-994

To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.  相似文献   

基于Budyko假设和分形理论的水沙变化归因识别——以北洛河流域为例   总被引：1，自引：0，他引：1  

薛帆  张晓萍  张橹  刘宝元  杨勤科  易海杰  何亮  邹亚东  贺洁  许小明  吕渡 《地理学报》2022,77(1):79-92

全球气候变化及人类活动深刻影响了区域水文过程,进行水沙变化归因识别对流域生态保护和高质量发展尤为重要。基于Budyko假设和分形理论,采用弹性系数法,对北洛河流域上（丘陵沟壑区）、中（土石山林—高塬沟壑区）、下游（渭北旱塬农区）3种不同地貌和植被类型区1959—2019年的水、沙通量变化进行归因分析。结果表明,北洛河上、中、下游径流量均显著减少,由20世纪60年代的35 mm、32 mm、34 mm,减少到21世纪10年代的19 mm、24 mm、6 mm,60 a减少率分别为0.3 mm a^-1、0.2 mm a^-1、0.4 mm a^-1。上游输沙量极显著减少,中游降低趋势不显著,下游显著减少,由20世纪60年代的99×10⁶ t、8×10⁶ t、3×10⁶ t,减少到21世纪10年代的10×10⁶ t、3×10⁶ t、0.3×10⁶ t,60 a减少率分别为1.5×10⁶ t a^-1、0.04×10⁶ t a^-1、0.1×10⁶ t a^-1。20世纪70年代以来,上游径流变化逐渐受人类活动影响,且影响程度逐渐增强,21世纪10年代人类活动贡献率达66.3%;气候变化是中游径流变化的主控因子,21世纪10年代降雨和潜在蒸散发的贡献率分别为77.0%和20.2%;下游径流减少主要为人类活动影响,21世纪10年代其贡献率为64.3%。对比20世纪60年代流域输沙量变化始终受人类活动主导,21世纪10年代人类活动对上、中、下游输沙量减少的贡献率分别为80.7%、59.2%和92.7%。上游人类活动对输沙量减少的贡献中,退耕还林等沟坡措施和沟道工程措施分别为39.0%、42.7%,中、下游人类活动贡献的估算结果反映出高植被覆盖区和农区汲水灌溉对区域水、沙的影响特征。  相似文献   

Revisiting natural and laboratory electron spin resonance (ESR) dose response curves of quartz from Chinese loess     

《Quaternary Geochronology》2022

Natural and laboratory ESR dose response curves (DRCs) of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰ were investigated for samples of quartz from the Luochuan loess-palaeosol master section, Chinese Loess Plateau. The natural and laboratory DRCs show a clear divergence above ∼1000 Gy, with much lower D₀ values and saturation levels observed for the natural DRCs, which is in agreement with the previous study by Tsukamoto et al. (2018). Young (<15 ka) samples from Luochuan and Jingbian – another site of the Chinese Loess Plateau, together with two modern samples of Chinese loess, were used to investigate the residual signals of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰ centres. Our results are in line with published studies and show that the significant residual signals corresponding to several tens to hundreds of Gy are present in both Al and Ti centres. These need to be taken into account before laboratory DRC construction. ESR pulse annealing experiments performed on samples irradiated with different doses show an apparent dose-dependent thermal instability of [AlO₄/h]⁰ and [TiO₄/M⁺]⁰, with the signals for higher doses decaying faster with increasing temperature. We attribute the change in D₀ with preheat reported in Tsukamoto et al.2018, as well as the difference between laboratory and natural DRCs, to this apparent dose-dependent thermal instability of the signals. The saturation level of the natural DRC, being the result of reaching the equilibrium between filling of the traps and emptying them due to thermal decay, is therefore additionally affected at higher doses, due to the increased thermal instability. The inability to recreate in the laboratory the same response to irradiation as the one observed in nature questions the accuracy of dating samples beyond ∼1000 Gy.  相似文献   

The upper Pleistocene loess-palaeosol sequence at solonovka on the Cis-Altai plain,west Siberia – First luminescence dating results     

《Quaternary Geochronology》2022

Loess-palaeosol deposits of the Upper Pleistocene cover an extensive territory in the south of Western Siberia. Previously, most studies of loess-palaeosol sequences were carried out on river bank sections of the Ob river around Novosibirsk and upstream of this location (Ob Loess plateau); more recently, the focus of research has shifted towards the inner part of the Cis-Altai plain. Despite a good knowledge of the structure of regional loess-palaeosol sequences, there is a considerable lack of absolute dating beyond the radiocarbon limit. However, recent high resolution luminescence dating of a key Marine Isotope Stage 5 (MIS 5) stratotype at Lozhok has identified the presence of a long hiatus in the deposit. As a result, the published ages of the main units have been underestimated, because the existing chronology is largely based on palaeosol counting. This new observation argues for an urgent re-evaluation of the accepted chronostratigraphy of Western Siberian Late Quaternary. Here we present the first luminescence data for a loess-palaeosol sequence of the Cis-Altai plain, at the Solonovka key section, using both quartz optically stimulated luminescence and feldspar post-infrared infrared stimulated luminescence from 25 samples. The results show that the deposits were formed during the Late Pleistocene. The ∼1 m thick well-developed upper pedocomplex (PC1) has cryoturbation cracks filled with upper loess; this a characteristic regional benchmark for stratigraphic correlation. Two distinct hiatuses in sedimentation are found in the section: at the boundary of MIS 3/2, and after the formation of the MIS 5 Berdsk pedocomplex (PC3 and 2) until the beginning of the formation of MIS 3 deposits. The age of the thick PC3 palaeosol at the base of the section is determined as MIS 5, confirming evidence for the pronounced Kazantsevo (Eemian) interglacial in the loess-palaeosol record of Western Siberia. The results of our study emphasize the importance of understanding the palaeogeomorphological background to soil development, and the necessity of absolute chronology; we consider that the position of MIS 5 in the regional chronostratigraphic chart of South Western Siberia requires further study.  相似文献   

黄土高原西部地区黄土地层有机质主要来源分析*     

饶志国  郭文康  薛骞  陈发虎 《第四纪研究》2015,35(4)

黄土有机质的主要来源是决定其稳定碳同位素(δ13Corg.)能否应用于重建过去C3/C4相对丰度变化及相应的古气候变化的关键基础科学问题.如若黄土地层当中的有机质主要由粉尘携带而来,而非当地植被,显然其δ13Corg.不是一个局地植被过去C3/C4相对丰度变化及古气候变化的良好指示器.本文对黄土高原西部地区(六盘山以西)新获得和已发表的相关数据进行综合分析,尝试对该地区黄土有机质的主要来源进行定量的分析.结果表明,总体而言,该地区黄土地层有机质主要来源于当地植被,由粉尘携带而来的有机质贡献量不超过8％,所造成的有机碳同位素变化幅度不超过1.7‰.这些结果说明该地区的黄土地层有机质δ13Corg.是可以用来重建过去C3/C4植物相对丰度及相应的古气候变化的.为了更精确的重建,后续的工作应当更多考虑粉尘搬运过程当中的有机质输入以及粉尘沉积之后的微生物活动的可能潜在影响.  相似文献   

黄土高原黄土地层的对比及细分          下载免费PDF全文

王洋  孙洪艳  田明中 《高校地质学报》2015,21(2):346

将前人对黄土高原黄土地层划分的研究成果进行全面总结、分析,结合洛川、宝鸡、西峰3个经典剖面,利用土壤 地层学、沉积学、磁性地层学、古生物学、年代学、地球化学等研究方法对黄土高原的黄土地层进行详细对比以及进一步 细分。将早、中更新世界线调整为B/M极性倒转开始的对应层位——L9顶部。根据岩性和气候旋回周期的差异性等,将离 石黄土三分,S8/L9作为离石黄土内部划分的一条新界线,S1~L5划分为上离石黄土,S5~S8划分为中离石黄土,L9~L15划分为 下离石黄土。在分析过程中发现关键层位（S0,L1,S1,S5,L9,L15,L33） 的年龄具有差异性。  相似文献   

Runoff and sediment loss responses to rainfall and land use in two agricultural catchments on the Loess Plateau of China     

Shaozhong Kang  Lu Zhang  Xiaoyu Song  Shuhan Zhang  Xianzhao Liu  Yinli Liang  Shiqing Zheng 《水文研究》2001,15(6):977-988

Soil erosion is a severe problem hindering sustainable agriculture on the Loess Plateau of China. Plot experiments were conducted under the natural rainfall condition during 1995–1997 at Wangdongguo and Aobao catchments in this region to evaluate the effects of various land use, cropping systems, land slopes and rainfall on runoff and sediment losses, as well as the differences in catchment responses. The experiments included various surface conditions ranging from bare soil to vegetated surfaces (maize, wheat residue, Robinia pseudoacacia L., Amorpha fruticosa L., Stipa capillata L., buckwheat and Astragarus adsurgens L.). The measurements were carried out on hill slopes with different gradients (i.e. 0 ° to 36 °). These plots varied from 20 to 60 m in length. Results indicated that runoff and erosion in this region occurred mainly during summer storms. Summer runoff and sediment losses under cropping and other vegetation were significantly less than those from ploughed bare soil (i.e. without crop/plant or crop residue). There were fewer runoff and sediment losses with increasing canopy cover. Land slope had a major effect on runoff and sediment losses and this effect was markedly larger in the tillage plots than that in the natural grass and forest plots, although this effect was very small when the maximum rainfall intensity was larger than 58·8 mm/h or smaller than 2·4 mm/h. Sediment losses per unit area rose with increasing slope length for the same land slope and same land use. The effect of slope length on sediment losses was stronger on a bare soil plot than on a crop/plant plot. The runoff volume and sediment losses were both closely related to rainfall volume and maximum intensity, while runoff coefficient was mainly controlled by maximum rainfall intensity. Hortonian overland flow is the dominant runoff process in the region. The differences in runoff volume, runoff coefficient and sediment losses between the catchments are mainly controlled by the maximum rainfall intensity and infiltration characteristics. The Aobao catchment yielded much larger runoff volume, runoff coefficient and sediment than the Wangdongguo catchment. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

秦岭太白山古冰川发育与黄土高原气候变迁   总被引：4，自引：1，他引：3  

田泽生  黄春长 《地理研究》1990,9(3):15-23

本文通过古冰川遗迹的系统分析,揭示了太白山雪线变化和冰川发育过程,将其与黄土高原晚第四纪气候变化模式对比,阐明了太白山雪线变化和冰川发育的时代和时间序列问题。  相似文献   

榆林地区黄土窑洞崩塌灾害的多发性原因及其防治对策研究     

缪祥生  韩许恒 《地球科学与环境学报》1993,(3)

本文通过对榆林地区米脂、绥德、子洲、清涧、吴堡和榆林市黄土窑洞建窑环境进行考察,总结分析了在黄土介质中修建的土窑洞崩塌灾害多发性原因,并提出了可操作性的防治对策。该对策可广泛适用于我国黄土窑洞分布区。  相似文献   

欧亚黄土沉积环境对比研究     

陈志清 《云南地理环境研究》1991,3(2):23-33

本文对采自中国、法国、比利时等国43块黄土样品进行实验室处理后,分析对比了它们在碳酸盐含量、粒度组成、重矿物组成及粘土矿物成分方面的共同特性及差异性。结果表明,中国黄土碳酸盐含量稳定,西欧不同类型的黄土碳酸盐含量差别很大。在粒度组成上,欧亚黄土并没有本质的差别,但西欧不同层位的黄土粒度组成呈有规律变化。对西欧重矿物的分析可以追溯黄土的物质来源,粘土矿物含量在欧亚不同黄土中也有差别。比较结果说明,欧洲的黄土堆积受第四纪冰期、间冰期的气候波动影响较大,中国黄土在堆积期间始终处在干旱、半干旱的气候条件下。  相似文献