Hydrogen peroxide on Mars: evidence for spatial and seasonal variations     

Th Encrenaz  B Bézard  M.J Richter  S.K Atreya  S Lebonnois  F Forget 《Icarus》2004,170(2):424-429

Hydrogen peroxide (H₂O₂) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 10¹⁵-10¹⁶ cm⁻². However, a stringent upper limit of the H₂O₂ abundance on Mars (9×10¹⁴ cm⁻²) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H₂O₂ on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H₂O₂ shows a maximum in the morning around the sub-solar latitude. The mean H₂O₂ column density (6×10¹⁵ cm⁻²) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).  相似文献   

Sulfurous acid (H₂SO₃) on Io?     

Andreas F. Voegele  Christofer S. Tautermann  Andreas Hallbrucker  Erwin Mayer  Klaus R. Liedl 《Icarus》2004,169(1):242-249

Sulfurous acid (H₂SO₃) has never been characterized or isolated on Earth. This is caused by the unfavorable conditions for H₂SO₃ within Earth's atmosphere due to the high temperatures, the high water content and the oxidizing environment. Kinetic investigations by means of transition state theory showed that the half-life of H₂SO₃ at 300 K is 1 day but at 100 K it is increased to 2.7 billion years. Natural conditions to form H₂SO₃ presumably require cryogenic SO₂ or SO₂/H₂O mixtures and high energy proton irradiation at temperatures around 100 K. Such conditions can be found on the Jupiter moons Io and Europa. Therefore, we calculated IR-spectra of H₂SO₃ which we compared with Galileo's spectra of Io and Europa. From the available data we surmise that H₂SO₃ is present on Io and probably but to a smaller extent on Europa.  相似文献   

The atmospheric signature of Io's Prometheus plume and anti-jovian hemisphere: evidence for a sublimation atmosphere     

Kandis Lea Jessup  John R. Spencer  Robert R. Howell  Miquela Vigel 《Icarus》2004,169(1):197-215

Using the Hubble Space Telescope's Space Telescope Imaging Spectrograph we have obtained for the first time spatially resolved 2000-3000 Å spectra of Io's Prometheus plume and adjoining regions on Io's anti-jovian hemisphere in the latitude range 60° N-60° S, using a 0.1″ slit centered on Prometheus and tilted roughly 45° to the spin axis. The SO₂ column density peaked at 1.25×10¹⁷ cm⁻² near the equator, with an additional 5×10¹⁶ cm⁻² enhancement over Prometheus corresponding to a model volcanic SO₂ output of 10⁵ kg s⁻¹. Apart from the Prometheus peak, the SO₂ column density dropped fairly smoothly away from the subsolar point, even over regions that included potential volcanic sources. At latitudes less than ±30°, the dropoff rate was consistent with control by vapor pressure equilibrium with surface frost with subsolar temperature 117.3±0.6 K, though SO₂ abundance was higher than predicted by vapor pressure control at mid-latitudes, especially in the northern hemisphere. We conclude that, at least at low latitudes on the anti-jovian hemisphere where there are extensive deposits of optically-thick SO₂ frost, the atmosphere is probably primarily supported by sublimation of surface frost. Although the 45° tilt of our slit prevents us from separating the dependence of atmospheric density on solar zenith angle from its dependence on latitude, the pattern is consistent with a sublimation atmosphere regardless of which parameter is the dominant control. The observed drop in gas abundance towards higher latitudes is consistent with the interpretation of previous Lyman alpha images of Io as indicating an atmosphere concentrated at low latitudes. Comparison with previous disk-resolved UV spectroscopy, Lyman-alpha images, and mid-infrared spectroscopy suggests that Io's atmosphere is denser and more widespread on the anti-jovian hemisphere than at other longitudes. SO₂ gas temperatures were in the range of 150-250 K over the majority of the anti-jovian hemisphere, consistent with previous observations. SO was not definitively detected in our spectra, with upper limits to the SO/SO₂ ratio in the range 1-10%, roughly consistent with previous observations. S₂ gas was not seen anywhere, with an upper limit of 7.5×10¹⁴ cm⁻² for the Prometheus plume, confirming that this plume is significantly poorer in S₂ than the Pele plume (S₂ /SO₂<0.005, compared to 0.08-0.3 at Pele). In addition to the gas absorption signatures, we have observed continuum emission in the near ultraviolet (near 2800 Å) for the first time. The brightness of the observed emission was directly correlated with the SO₂ abundance, strongly peaking in the equatorial region over Prometheus. Emission brightness was modestly anti-correlated with the jovian magnetic latitude, decreasing when Io intersected the torus centrifugal equator.  相似文献   

SOS: the visible spectroscopic survey of 820 asteroids     

D. Lazzaro  C.A. Angeli  T. Mothé-Diniz  M. Florczak 《Icarus》2004,172(1):179-220

We present the results of a visible spectroscopic survey of 820 asteroids carried on between November 1996 and September 2001 at the 1.52 m telescope at ESO (La Silla). The instrumental set-up allowed an useful spectral range of about 4900 Å<λ<9200 Å. The global spatial distribution of the observed asteroids covers quite well all the region between 2.2 and 3.3 AU though some concentrations are apparent. These are due to the fact that several sub-sets of asteroids, such as families and groups, have been selected and studied during the development of the survey. The observed asteroids have been classified using the Tholen and the Bus taxonomies which, in general, agree quite well.  相似文献   

Mapping of Io's thermal radiation by the Galileo photopolarimeter-radiometer (PPR) instrument   总被引：1，自引：0，他引：1  

J.A. Rathbun  J.R. Spencer  T.Z. Martin  L.D. Travis 《Icarus》2004,169(1):127-139

Between 1999 and 2002, the Galileo spacecraft made 6 close flybys of Io during which many observations of Io's thermal radiation were made with the photopolarimeter-radiometer (PPR). While the NIMS instrument could measure thermal emission from hot spots with T>200 K, PPR was the only Galileo instrument capable of mapping the lower temperatures of older, cooling lava flows, and the passive background. We tabulate all data taken by PPR of Io during these flybys and describe some scientific highlights revealed by the data. The data include almost complete coverage of Io at better than 250 km resolution, with extensive regional coverage at higher resolutions. We found a modest poleward drop in nighttime background temperatures and evidence of thermal inertia variations across the surface. Comparison of high spatial resolution temperature measurements with observed daytime SO₂ gas pressures on Io provides evidence for local cold trapping of SO₂ frost on scales smaller than the 60 km resolution of the PPR data. We also calculated the power output from several hot spots and estimated total global heat flow to be about 2.0-2.6 W m⁻². The low-latitude diurnal temperature variations for the regions between obvious hot spots are well matched by a laterally-inhomogeneous thermal model with less than 1 W m⁻² endogenic heat flow.  相似文献   

Near-infrared laboratory spectra of solid H₂O/CO₂ and CH₃OH/CO₂ ice mixtures     

Max P. Bernstein  Dale P. Cruikshank  Scott A. Sandford 《Icarus》2005,179(2):527-534

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.  相似文献   

活动星系核的多波段能谱及其发射机制──Ⅱ．红外连续辐射能谱     

吴建新  周又元 《天文学报》1995,(3)

本文讨论了１６个红外强ＰＧ类星体的红外辐射能谱。我们假设这些活动星系核的红外谱是由非热辐射机制和尘埃的热辐射共同产生的，通过对红外包的最佳拟合，我们发现大多数ＰＧ类星体的红外包位于７一２４μ的中远红外区，尘埃的热辐射机制能很好地产生观测到的红外包。通过模拟能定量地说明尘埃产生的热致辐射在这些天体的红外谱中的相对重要性，在模型与观测值之间的拟合中，我们得到了在这些天体中核加热的尘埃区的大小、尘埃的分布等模型参数。  相似文献   

Detection of new hydrocarbons in Uranus' atmosphere by infrared spectroscopy     

Martin Burgdorf  Glenn Orton  Victoria Meadows 《Icarus》2006,184(2):634-637

Ethane (C₂H₆), methylacetylene (CH₃C₂H or C₃H₄) and diacetylene (C₄H₂) have been discovered in Spitzer 10-20 μm spectra of Uranus, with 0.1-mbar volume mixing ratios of (1.0±0.1)×¹⁰⁻⁸, (2.5±0.3)×¹⁰⁻¹⁰, and (1.6±0.2)×¹⁰⁻¹⁰, respectively. These hydrocarbons complement previously detected methane (CH₄) and acetylene (C₂H₂). Carbon dioxide (CO₂) was also detected at the 7-σ level with a 0.1-mbar volume mixing ratio of (4±0.5)×¹⁰⁻¹¹. Although the reactions producing hydrocarbons in the atmospheres of giant planets start from radicals, the methyl radical (CH₃) was not found in the spectra, implying much lower abundances than in the atmospheres of Saturn or Neptune where it has been detected. This finding underlines the fact that Uranus' atmosphere occupies a special position among the giant planets, and our results shed light on the chemical reactions happening in the absence of a substantial internal energy source.  相似文献   

Near-infrared adaptive optics imaging of the satellites and individual rings of Uranus     

S.G. Gibbard  I. de Pater 《Icarus》2005,174(1):253-262

We present the first Earth-based images of several of the individual faint rings of Uranus, as observed with the adaptive optics system on the W.M. Keck II telescope on four consecutive days in October 2003. We derive reflectivities based on multiple measurements of 8 minor moons of Uranus as well as Ariel and Miranda in filters centered at wavelengths of 1.25(J), 1.63(H), and 2.1(Kp) μm. These observations have a phase angle of 1.84°-1.96°. We find that the small satellites are somewhat less bright than in observations made by the HST at smaller phase angles, confirming an opposition surge effect. We calculate albedoes for the ring groups and for each ring separately. We find that the ε ring particles, as well as the particles in the three other ring groups, have albedoes near 0.043 at these phase angles. The equivalent depths of some of the individual rings are different than predicted based upon ring widths from occultation measurements (assuming a constant particle ring brightness); in particular the γ ring is fainter and the η ring brighter than expected. Our results indicate that q, the ratio of ε ring intensity at apoapse vs. periapse, is close to 3.2±0.16. This agrees well with a model that has a filling factor for the ε ring of 0.06 (Karkoschka, 2001, Icarus 151, 78-83). We also determine values of the north to south brightness ratio for the individual rings and find that in most cases they are close to unity.  相似文献   

Spectral observations of 19 weathered and 23 fresh NEAs and their correlations with orbital parameters     

Ronald A. Fevig  Uwe Fink 《Icarus》2007,188(1):175-188

Results of our visible to near-infrared spectrophotometric observations of 41 near-Earth asteroids (NEAs) are reported. These moderate-resolution spectra, along with 14 previously published spectra from our earlier survey [Hicks, M.D., Fink, U., Grundy, W.M., 1998. Icarus 133, 69-78] show a preponderance of spectra consistent with ordinary chondrites (23 NEAs with this type of spectrum, along with 19 S-types and 13 in other taxonomic groups). There exists statistically significant evidence for orbit-dependent trends in our data. While S-type NEAs from our survey reside primarily in (1) Amor orbits or (2) Aten or Apollo orbits which do not cross the asteroid main-belt, the majority of objects with spectra consistent with ordinary chondrites in our survey are in highly eccentric Apollo orbits which enter the asteroid main-belt. This trend toward fresh, relatively unweathered NEAs with ordinary chondrite type spectra in highly eccentric Apollo orbits is attributed to one or a combination of three possible causes: (1) the chaotic nature of NEA orbits can easily result in high eccentricity orbits/large aphelion distances so that they can enter the collisionally enhanced environment in the main-belt, exposing fresh surfaces, (2) they have recently been injected into such orbits after a collision in the main-belt, or (3) such objects cross the orbits of several terrestrial planets, causing tidal disruption events that expose fresh surfaces.  相似文献