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931.
932.
J. L. Mosenfelder 《Physics and Chemistry of Minerals》2000,27(9):610-617
The solubility of hydroxyl in coesite was investigated in multianvil experiments performed at 1200 °C over the nominal pressure
range 5–10 GPa, at an f
O2 close to the Ni-NiO buffer. The starting material for each experiment was a cylinder of pure silica glass plus talc, which
dehydrates at high P and T to provide a source of water and hydrogen (plus enstatite and excess SiO2). Fourier-transform infrared (FTIR) spectra of the recovered coesite crystals show five sharp bands at 3606, 3573, 3523,
3459, and 3299 cm−1, indicative of structurally bonded hydrogen (hydroxyl). The concentration of hydrogen increases with pressure from 285 H/106 Si (at 5 GPa) to 1415 H/106 Si (at 10 GPa). Assuming a model of incorporation by (4H)Si defects, the data are fit well by the equation C
OH=Af
2
H2<\INF>Oexp(−PΔV/RT), with A=4.38 H/106 Si/GPa, and ΔV=20.6 × 10−6 m3 mol−1. An alternative model entailing association of hydrogen with cation substitution can also be used to fit the data. These
results show that the solubility of hydroxyl in coesite is approximately an order of magnitude lower than in olivines and
pyroxenes, but comparable to that in pyropic garnet. However, FTIR investigations on a variety of ultrahigh pressure metamorphic
rocks have failed in all cases to detect the presence of water or hydrogen in coesite, indicating either that it grew in dry
environments or lost its hydrogen during partial transformation to quartz. On the other hand, micro-FTIR investigations of
quartz crystals replacing coesite show that they contain varying amounts of H2O. These results support the hypothesis that preservation of coesite is not necessarily linked to fast exhumation rates but
is crucially dependent on limited fluid infiltration during exhumation.
Received: 23 August 1999 / Accepted: 10 April 2000 相似文献
933.
应用FY-4A卫星红外和水汽云图资料,结合NCEP分析场资料以及地面自动气象站变压、变温、大风及降水资料,计算等熵面位涡,分析2018年3月4日中国江南—华南地区强飑线过程的发生发展机制及持续性大风产生的主要原因。结果表明:对流单体触发于低层辐合系统,由于雷暴下沉气流与其前方的低层暖湿西南气流形成地面辐合线,并且移入地区的水汽、静力不稳定及垂直风切变条件对强对流风暴的发展均十分有利,使得导致极端对流大风的强对流风暴持续发展。极端大风主要分布在飑线中弓形结构的顶端,落区与亮温梯度和变压梯度相对应,导致变压风增大;飑线的移动与引导气流方向一致,系统走向和低层西南急流接近于垂直,系统移速加快,动量下传效应增强,均是导致极端地面大风的成因。位涡分布表明高位涡的侵入和呈弓形分布的低位涡区的形成具有一定关联,干侵入区与等熵面上高位涡区有着较好的对应,飑线后部的暗区正是干侵入的前沿,高层高位涡的下传是飑线系统持续发展的成因。 相似文献
934.
红外云图的参数化及其与局地降雨的关系探讨 总被引:2,自引:0,他引:2
本文从大气探测原理和大气物理的基本概念出发,将地面气象观测资料与红外卫星云图相结合进行参数化估计,得到一些参数化估计结果。初步分析表明,这些参数化估计值与局地降雨有较好的相关关系。 相似文献
935.
Near-infrared (NIR) absorption bands related to total water (4000 and 7050 cm−1), OH groups (4500 cm−1) and molecular H2O (5200 cm−1) were studied in two polymerised glasses, a synthetic albitic composition and a natural obsidian. The water contents of the
glasses were determined using Karl Fischer titration. Molar absorption coefficients were calculated for each of the bands
using albitic glasses containing between 0.54 and 9.16 wt.% H2O and rhyolitic glasses containing between 0.97 and 9.20 wt.% H2O. Different combinations of baseline type and intensity measure (peak height/area) for the combination bands at 4500 and
5200 cm−1 were used to investigate the effect of evaluation procedure on calculated hydrous species concentrations. Total water contents
calculated using each of the baseline/molar absorption coefficient combinations agree to within 5.8% relative for rhyolitic
and 6.5% relative for albitic glasses (maximum absolute differences of 0.08 and 0.15 wt.% H2O, respectively). In glasses with water contents >1 wt.%, calculated hydrous species concentrations vary by up to 17% relative
for OH and 11% relative for H2O (maximum absolute differences of 0.33 and 0.43 wt.% H2O, respectively). This variation in calculated species concentrations is typically greater in rhyolitic glasses than albitic.
In situ, micro-FTIR analysis at 300 and 100 K was used to investigate the effect of varying temperature on the NIR spectra of the
glasses. The linear and integral molar absorption coefficients for each of the bands were recalculated from the 100 K spectra,
and were found to vary systematically from the 300 K values. Linear molar absorption coefficients for the 4000 and 7050 cm−1 bands decrease by 16–20% and integral molar absorption coefficients by up to 30%. Depending on glass composition and baseline
type, the integral molar absorption coefficients for the absorption bands related to OH groups and molecular H2O change by up to −5.8 and +7.4%, respectively, while linear molar absorption coefficients show less variation, with a maximum
change of ∼4%. Using the new molar absorption coefficients for the combination bands to calculate species concentrations at
100 K, the maximum change in species concentration is 0.08 wt.% H2O, compared with 0.39 wt.% which would be calculated if constant values were assumed for the combination band molar absorption
coefficients. Almost all the changes in the spectra can therefore be interpreted in terms of changing molar absorption coefficient,
rather than interconversion between hydrous species.
Received: 17 December 1998 / Revised, accepted 8 July 1999 相似文献
936.
坡缕石的红外光谱研究 总被引:14,自引:0,他引:14
在仔细分析坡缕石结构特点的基础上,对坡缕石结构的组成离子进行了详细划分。利用晶体化学和分子轨道理论,深入研究了热液型和沉积型坡缕石的红外光谱谱图特点, 对坡缕石结构中的水以及 Si— O 区红外吸收带进行了归属研究。其中, 约 3694 cm - 1 、3611cm - 1 吸收带分别归属为 ν M g— O H 、ν Al— O H , 约 3540 cm - 1 吸收带归属为 ν O H 2 , 约 3394 cm - 1 、3294cm - 1 吸收带归属为ν H2 O , 约 1655 cm - 1、1400 cm - 1 吸收带归属为δ O H 2 、δ H 2 O ; Si— O 振动区,连接坡缕石倒转结构单元间的直线型 Si— O桥倒— Si的红外振动吸收频率最高, 与活性氧结合的 Si— O活红外振动吸收频率居次, 其中 Si— O活边 高于 Si— O活内, 而连接辉石式单链的 Si— O桥非— Si较低, 且 Si— O桥非间— Si比 Si— O桥非内 — Si低。 相似文献
937.
938.
This paper reviews research on coprolites from India, providing the first evidence of microcoprolites from the early Miocene (Aquitanian) Khari Nadi Formation sedimentary succession, exposed about 1.5 km northeast of the village of Kotada, Kachchh (Kutch) District, Gujarat State, western India. Morphometric and size comparisons (in a statistical framework) with known coprolites from the Mesozoic-Cenozoic successions of India (including those recorded herein) and globally suggest that fishes were the likely producers of the Kotada coprolites. Scanning electron microscopy confirms the presence of fish dental remains within the coprolites, while both Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) reveal the phosphatic nature of the microscopic coprolite specimens (recorded herein) hinting that the producer(s) were predominantly carnivorous (ichthyophagous) in their diet. Furthermore, X-Ray Fluorescence (XRF) analysis of the host and associated lithologies allows us to deduce that the Kotada coprolites were deposited in a shallow marine environment, with possible aerial exposure of the host lithology occurring at some point after deposition. To the best of our knowledge, the present report is the first record of microscopic fish coprolites from India, as well as being the first from the Aquitanian of India and the oldest Neogene record from India. 相似文献
939.
利用探空站数据对北京和张家口冬奥赛场周边地区的地基微波辐射计和FY 4A大气垂直探测仪资料进行验证分析。选取2020年全年FY 4A大气垂直探测仪资料以及2020年12月至2021年3月期间对冬奥赛事有重要影响的寒潮前后、雾霾和沙尘暴这3种不同天气现象下探测得到的气温廓线数据进行个例分析。结果表明:在晴空条件下,地基微波辐射计和FY 4A大气垂直探测仪探测大气垂直气温的精度较高,平均相关系数达到0.97,低层大气(500 hPa以下)较高层大气探测结果的一致性较好;大气污染对探测精度产生一定影响,其中PM2.5产生的影响较小,PM10的提高对FY 4A大气垂直探测仪的探测产生较大影响,尤其是发生沙尘暴时,星载探测仪无法对低层大气进行探测。经过对比和验证,卫星探测作为补充探测手段,可以与地基微波辐射计互相补充,尤其是在空间覆盖和时间分辨率上具备一定优势,但在有云和沙尘暴的天气条件下无法对低层大气开展探测;地基微波辐射计可以对一个地点的大气垂直参数开展不间断的探测,与探空站数据的一致性较高。卫星探测和地基微波辐射计均可以为冬奥赛事提供高时间分辨率的探测数据,为数值天气预报提供有力的数据支撑。 相似文献
940.
FY 4A上搭载的多通道扫描成像辐射计(AGRI)无论是时间分辨率还是空间分辨率与我国第一代静止气象卫星风云二号上搭载的扫描辐射计(VISSR)相比都有了明显的改进。本文基于FY 4A AGRI成像仪IDDI(红外差值沙尘指数)和新的昼夜沙尘遥感改进算法开展2021年中国北方沙尘过程连续遥感监测处理,并系统分析了2021年3个典型个例的沙尘暴特征和影响区域。结果表明:① 3次典型沙尘过程对我国北方各省份的影响面积总计最低达到260万km2以上,最高达到300万km2以上,4月14—17日的沙尘暴影响面积最大。②2021年沙尘高发区在新疆南部、甘肃河西走廊以北以及内蒙古西部。与2019、2020年同期相比,2021年我国北方沙尘发生频次更高、影响范围更大。③新一代FY 4A静止卫星对我国沙尘过程年际变化具备更加完整的监测能力。 相似文献