A Melt Inclusion Record of Volatiles, Trace Elements and Li-B Isotope Variations in a Single Magma System from the Plat Pays Volcanic Complex, Dominica, Lesser Antilles   总被引：2，自引：0，他引：2  

GURENKO  ANDREY A.; TRUMBULL  ROBERT B.; THOMAS  RAINER; LINDSAY  JAN M. 《Journal of Petrology》2005,46(12):2495-2526

Glass inclusions in plagioclase and orthopyroxene from daciticpumice of the Cabrits Dome, Plat Pays Volcanic Complex in southernDominica reveal a complexity of element behavior and Li–Bisotope variations in a single volcanic center that would gounnoticed in a whole-rock study. Inclusions and matrix glassesare high-silica rhyolite with compositions consistent with about50% fractional crystallization of the observed phenocrysts.Estimated crystallization conditions are 760–880°C,200 MPa and oxygen fugacity of FMQ + 1 to +2 log units (whereFMQ is the fayalite–magnetite–quartz buffer). Manyinclusion glasses are volatile-rich (up to 6 wt % H₂O and 2900ppm Cl), but contents range down to 1 wt % H₂O and 2000 ppmCl as a result of shallow-level degassing. Sulfur contents arelow throughout, with <350 ppm S. The trace element compositionof inclusion glasses shows enrichment in light rare earth elements(LREE; (La/Sm)_n = 2·5–6·6) and elevatedBa, Th and K contents compared with whole rocks and similaror lower Nb and heavy REE (HREE; (Gd/Yb)_n = 0·5–1·0).Lithium and boron concentrations and isotope ratios in meltinclusions are highly variable (20–60 ppm Li with ⁷Li= +4 to +15 ± 2; 60–100 ppm B with ¹¹B = +6 to+13 ± 2) and imply trapping of isotopically heterogeneous,hybrid melts. Multiple sources and processes are required toexplain these features. The mid-ocean ridge basalt (MORB)-likeHREE, Nb and Y signature reflects the parental magma(s) derivedfrom the mantle wedge. Positive Ba/Nb, B/Nb and Th/Nb correlationsin inclusion glasses indicate coupled enrichment in stronglyfluid-mobile (Ba, B) and less-mobile (Th, Nb) trace elements,which can be explained by fractional crystallization of plagioclase,orthopyroxene and Fe–Ti oxides. The ⁷Li and ¹¹B valuesare at the high end of known ranges for other island arc magmas.We attribute the high values to a ¹¹B and ⁷Li-enriched slabcomponent derived from sea-floor-altered oceanic crust and possiblyfurther enriched in heavy isotopes by dehydration fractionation.The heterogeneity of isotope ratios in the evolved, trappedmelts is attributed to shallow-level assimilation of older volcanicrocks of the Plat Pays Volcanic Complex. KEY WORDS: subduction; volcanic arcs; igneous processes; melt inclusions; SIMS; trace elements; lithium and boron isotopes; diffusion  相似文献   

新疆西准噶尔地区晚石炭世洋内俯冲与成矿:来自苏云河钼矿区Ⅰ~#含矿花岗岩体的证据   总被引：1，自引：1，他引：0  

杨猛  王居里  王建其  刘存 《岩石学报》2015,31(2):523-533

新疆西准噶尔苏云河地区发育有斑岩型(铜-)钨钼共生矿床,通过对矿区内Ⅰ#含矿岩体进行详细的岩石学、地球化学及锆石U-Pb年代学研究,探讨岩浆起源、构造背景及其成矿意义。结果表明:(1)岩体高Si O2、Al2O3,中等富碱且相对富钠,A/CNK=1.08~1.28,σ=1.52~1.81,属钙碱性(强)过铝质花岗岩;稀土含量较低(∑REE=33.77×10-6~92.91×10-6),轻重稀土分馏程度中等且富集轻稀土((La/Yb)N=5.13~9.69),具弱Eu负异常(δEu=0.62~0.92);相对富集Rb、Th、U、K等LILE和LREE,亏损Ba、Sr、P、Ti、Nb、Ta和HREE等;(2)锆石LA-ICP-MS U-Pb定年获得岩浆结晶年龄为308.8±4.1Ma,岩体侵位时代为晚石炭世;(3)岩体具有正的εNd值(εNd=3.64~6.33)、低的87Sr/86Sr初始比值(ISr=0.704009~0.705313)和较年轻的二阶段模式年龄(t2DM=0.52~0.70Ga),形成于晚石炭世洋内俯冲背景下、有俯冲流体及少量洋盆陆源碎屑沉积物参与的晚元古代玄武质洋壳的部分熔融;(4)苏云河地区晚石炭世浅成岩浆侵入活动同时是一期重要的斑岩型(铜-)钨钼成矿事件,Ⅰ#岩体深部及巴尔鲁克断裂以西石炭纪中酸性岩体的含矿性值得做进一步评价。  相似文献   

Approximate general solution of 2-degrees of freedom dynamical systems using `les solutions precieuses'     

C.L. Goudas  K.E. Papadakis  E. Valaris 《Astrophysics and Space Science》2003,286(3-4):461-486

This paper presents the procedure of a computational scheme leading to approximate general solution of the axi-symmetric,2-degrees of freedom dynamical systems. Also the results of application of this scheme in two such systems of the non-linear double oscillator with third and fifth order potentials in position variables. Their approximate general solution is constructed by computing a dense set of families of periodic solutions and their presentation is made through plots of initial conditions. The accuracy of the approximate general solution is defined by two error parameters, one giving a measure of the accuracy of the integration and calculation of periodic solutions procedure, and the second the density in the initial conditions space of the periodic solutions calculated. Due to the need to compute families of periodic solutions of large periods the numerical integrations were carried out using the eighth order, variable step, R-K algorithm, which secured for almost all results presented here conservation of the energy constant between 10^-9 and 10^-12 for single runs of any and all solutions. The accuracy of the approximate general solution is controlled by increasing the number of family curves and also by `zooming' into parts of the space of initial conditions. All families of periodic solutions were checked for their stability. The computation of such families within areas of `deterministic chaos' did not encounter any difficulty other than poorer precision. Furthermore, on the basis of the stability study of the computed families, the boundaries of areas of `order' and `chaos' were approximately defined. On the basis of these results it is concluded that investigations in thePoincaré sections have to disclose 3 distinct types of areas of `order' and 2 distinct types of areas of `chaos'. Verification of the `order'/`chaos' boundary calculation was made by working out several Poincaré surfaces of sections. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

A CCD Image Archive Of Comet C/1995 O1 (Hale-Bopp): Dust Expansion Velocities     

BRAUNSTEIN  M.  COMSTOCK  R.  HOFFMAN  P.  WOMACK  M.  DEGLMAN  F.  PINNICK  D.  AAKER  G.  GOLDSCHEN  M.  JACOBSON  A.  ZILKA  J.  FAITH  D.  MOORE  S.  RICOTTA  J.  WEIST  A.  MODI  C. 《Earth, Moon, and Planets》1997,78(1-3):219-227

An optical archive of comet Hale-Bopp was obtained over 28 nights from June 1996 to May 1997 covering a range of heliocentric distances of r = 4.12 − 0.91. The CCD images were obtained with the 0.8-m University of Washington Manastash Ridge Observatory and the 0.25-m Pennsylvania State University at Eriemobile observatory. The reduced images clearly document the evolution of features of the coma, which were dominated by radial jetsfrom r = 4.1 − 2.3 AU, curved fan-shaped jets from r = 1.2 − 1.0 AU, and arcs or shells for 0.9 < r < 1.0 AU. We present the images and derive an average dust expansion velocity of V_dust = 0.67 ± 0.07 km s⁻¹ from measurements of the arc features. The images in thearchive will be made available to other researchers for further study. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Numerical Investigation of the Galactic Problem by Computing Families of Periodic Solutions     

C. L. Goudas  K. E. Papadakis  G. A. Katsiaris 《Astrophysics and Space Science》2006,301(1-4):97-116

The galactic dynamical system expressed by a third-order axisymmetric polynomial potential is investigated numerically by computing periodic solutions. We define as Sthe compact set of initial conditions generating bounded motions, and as S ^p , with S ^p ? S, the countable set of all initial conditions generating periodic solutions. Then, we consider the subsets S _s ^p and S _a ^p of S ^p , where S _s ^p ∪ S _a ^p = S ^p , S _s ^p S _a ^p = Ø, the first of which corresponds to symmetric periodic solutions, and the second to asymmetric solutions. Then, we approximate the set S _s ^p , leaving treatment of the set S _a ^p of asymmetric solutions for a future publication. The set S _s ^p is known to be dense in S (‘Last Geometric Theorem of Poincar;’, Birkhoff, 1913). Using a computer programme capable to locate all elements of the set S _s ^p that generate symmetric periodic solutions that re-enter after intersecting the axis of symmetry from 1 to ntimes. The results of the approximation of S _s ^p in the total domain and in the sample sub-domains of zooming, we present in graphical form as family curves in the (x, C) plane. The solutions located with the largest periods re-enter after 440 galaxy revolutions while the families calculated fully (initial conditions, period, energy, stability co-efficient) include solutions that re-enter after 340 galaxy revolutions. To advance further the approximation of the set S _s ^p thus obtained, we applied the same procedure inside eight sub-domains of the domain Sinto which we ‘zoomed’ through selection of finer search steps and double maximum periods. The family curves thus calculated presented in the (x, C) plane do not intersect anywhere in some sub-domains and their pattern resembles that of laminar flow. In other sub-domains, however, we found family curves from which branching families emanate. The concepts of completeand non-completeapproximation of S _s ^p in sub-domains of laminar and sub-domains with branching family curves, respectively, is introduced. Also, the concept of basic family of order1, 2, ..., n, are defined. The morphology of individual periodic solutions of all families is investigated, and the types of envelopes found are described. The approximate set S _s ^p was also checked by computing Poincar; sections for energy values corresponding to the mean energy range of the eight sub-domains of zooming mentioned above. These sections show that most parts of the compact domain in Sgenerating non-periodic but bounded solutions correspond to with well-shaped tori that intersect the x-axis, a fact that implies that dominant to exclusive type of periodic solutions are the symmetric ones with two normal crossings of this axis. The presence of non-symmetric periodic solutions as well as of chaotic regions is encountered. All calculations reported here were performed using the variable step R-K 8th-order direct integration and setting the allowable energy variation Δ C= |C _start? C _end| < 10^?13. The output, consisting of many thousands of families and their properties (initial conditions, morphology, stability, etc.), is stored in a directory entitled ‘Atlas of the Symmetric Periodic Solution of the Galactic Motion Problem’.  相似文献   

Geochemistry of the Pegmatitic Rocks and Minerals in the Kenticha Belt, Southern Ethiopia: Implication to Geological Setting     

Solomon Tadesse 《Gondwana Research》2001,4(1):97

Trace element distribution patterns are reported for whole rocks (granites, aplites, greisens, pegmatites, alaskites) and minerals from the Kenticha pegmatite field. The data shed light on the evolution, regional and local zonal pattern of the granitepegmatites and associated mineralization in the Kenticha belt. The complex mineralization of commercial concentrations of Ta, Nb, Hf, Zr, REE, U and Th is related to Be, Li, Cs, Rbbearing zones of pegmatites and is structurally controlled. Whole rock chemical signatures of the suite of felsic rocks of the Kenticha belt are predominantly similar to those generated by subduction in modern magmatic arcs and indicate a mantle derivation. Columbotantalite concentrates extracted from the pegmatitic ores represent the basic raw materials from which a number of possible byproducts can be recovered.  相似文献   

Univariate data analysis system: deciphering mean compositions of island and continental arc magmas,and influence of the underlying crust     

《International Geology Review》2012,54(15):1922-1940

Our aim is to determine the mean compositions of modern island and continental arcs, along with dispersion estimates, and use them to evaluate their similarities and differences in such subduction settings. First, following the conventional approach, the statistical parameters of mean, median, and standard deviation were simply calculated from the available combined data from all island or continental arcs. However, it is mandatory to ascertain from significance tests that all island or continental arcs used for these estimates are statistically similar in their compositions before combining the data from different arcs and calculating the mean values and their uncertainties for the chemical parameters of interest. A new computer program, Univariate Data Analysis System (UDASYS), was developed for this purpose because the available programs are not efficient for applying the significance test of analysis of variance (ANOVA) to large numbers of sample groups, as in the present work. Compositional data for 16 island and 12 continental arcs around the world were compiled and processed in UDASYS. The best compositional estimates for all three types of magmas (basic, intermediate, and acid) from island and continental arcs were statistically evaluated to document, for the first time, significant differences for 64–94% of the geochemical parameters under study. These differences in large-ion lithophile elements, light rare earth elements, high-field strength elements, and numerous log-ratios are likely caused by different types of underlying crust beneath island and continental arcs. More specifically, the examination of two nearby arcs, Izu-Bonin (island) arc and Japan (continental) arc, confirmed that about 65–77% of the parameters showed significant differences, which may be related to the different types of crusts beneath these spatially close areas. The differences between the log-ratios of island and continental arc basic magmas further indicate that new multi-dimensional discrimination diagrams can certainly be proposed in future to discriminate such basic magmas from these two very similar tectonic settings, which at present is possible only from diagrams for intermediate and acid magmas.  相似文献   

Trends in the training and employment of geoscientists in Australia from 1967 to 1978     

D. A. Berkman 《Australian Journal of Earth Sciences》2013,60(1-2):83-88

There are now 14 universities and 8 colleges of advanced education in Australia with geology or earth science departments, which comprised 278 professional staff, 2020 undergraduates, and 556 graduate students in 1978. Academic staff, engaged in a wide range of research, represent less than 10 percent of the total number of Australian geoscientists. Almost all non‐academic employers (98 percent of the sample) presently accept a graduate with a B.Sc. (Hons) degree, while 85 percent accept a B.Sc pass degree. About 65 percent of non‐academic geologists work for industry, and the remainder are employed by government surveys and research organisations. Mining and mineral exploration employ 76 percent of the geologists in industry, followed by petroleum exploration with 11 percent. Geologists make up 83 percent of geoscientists in non‐academic employment, the remainder being geophysicists 15 percent and geochemists 2 percent. Information on vacancies available in early 1979 suggests that all the recent graduates would be absorbed by government and industry, and pointed to a resurgence in demand for qualified geoscientists. There has been striking growth in the number of consulting/contracting geological firms, with 65 firms employing 242 geoscientists replying to the 1978 census.  相似文献   

Stretching lineation and transport direction in the Ibero-Armorican arc during the siluro-devonian collision     

Jean-Pierre Burg  Pascal Bale  Jean-Pierre Brun  Jacques Girardeau 《Geodinamica Acta》2013,26(1):71-87

Abstract

Large structures, lineations, foliations and sense of shear criteria are examined on the scale of the whole Ibero-Armorican Arc. Four sections (Galicia, Brittany-Vendée, Limousin and Eastern Massif Central) exemplify the major thrust sheets observed around the Arc. Stretching lineations are contemporaneous with the siluro-devonian metamorphism and are either transverse, oblique or parallel to the collision zone. A kinematic analysis shows that these lineations have resulted from a dominanüy transverse shear deformation which was followed by, or combined with, a longitudinal shear direction. On the scale of the entire Arc, this variation in the shear direction is interpreted as resulting from an early head on thrusting relative movement evolving to large scale movements parallel to the plate boundaries. Experiments with sand-silicone models support a model which generates the Arc by interaction between a transform sinistral direction, and a converning zone at a high angle to the transform direction.  相似文献   

The missing half of the subduction factory: shipboard results from the Izu rear arc,IODP Expedition 350     

Cathy J. Busby  Yoshihiko Tamura  Peter Blum  Gilles Guèrin  Graham D. M. Andrews  Abigail K. Barker 《International Geology Review》2017,59(13):1677-1708

IODP Expedition 350 was the first to be drilled in the rear part of the Izu-Bonin, although several sites had been drilled in the arc axis to fore-arc region; the scientific objective was to understand the evolution of the Izu rear arc, by drilling a deep-water volcaniclastic section with a long temporal record (Site U1437). The Izu rear arc is dominated by a series of basaltic to dacitic seamount chains up to ~100-km long roughly perpendicular to the arc front. Dredge samples from these are geochemically distinct from arc front rocks, and drilling was undertaken to understand this arc asymmetry. Site U1437 lies in an ~20-km-wide basin between two rear arc seamount chains, ~90-km west of the arc front, and was drilled to 1804 m below the sea floor (mbsf) with excellent recovery. We expected to drill a volcaniclastic apron, but the section is much more mud-rich than expected (~60%), and the remaining fraction of the section is much finer-grained than predicted from its position within the Izu arc, composed half of ashes/tuffs, and half of lapilli tuffs of fine grain size (clasts <3 cm). Volcanic blocks (>6.4 cm) are only sparsely scattered through the lowermost 25% of the section, and only one igneous unit was encountered, a rhyolite peperite intrusion at ~1390 mbsf. The lowest biostratigaphic datum is at 867 mbsf (~6.5 Ma), the lowest palaeomagnetic datum is at ~1300 mbsf (~9 Ma), and the rhyolite peperite at ~1390 mbsf has yielded a U–Pb zircon concordia intercept age of (13.6 + 1.6/?1.7) Ma. Both arc front and rear arc sources contributed to the fine-grained (distal) tephras of the upper 1320 m, but the coarse-grained (proximal) volcaniclastics in the lowest 25% of the section are geochemically similar to the arc front, suggesting arc asymmetry is not recorded in rocks older than ~13 Ma.  相似文献