Preservation of Palaeoproterozoic early Svecofennian structures in the Orijärvi area, SW Finland—Evidence for polyphase strain partitioning   总被引：1，自引：1，他引：0  

Pietari Skytt  Markku Visnen  Irmeli Mnttri 《Precambrian Research》2006,150(3-4):153-172

The predominantly migmatitic Palaeoproterozoic Uusimaa belt preserves early lower-grade Svecofennian structures in the Orijärvi area in SW Finland. This study aims at explaining the deformational history responsible for its preservation and also at defining the age of the early Svecofennian deformation. Detailed structural analysis reveals that the preservation was enabled by polyphase strain partitioning, which initiated during the early Svecofennian D₂ deformation, 1875 Ma ago, as revealed by ion microprobe U–Pb data on zircons from granodioritic and intermediate syn-D₂ intrusive dykes. The D₂ structures were low-strain upright folds at high crustal levels and sub-horizontal high-strain folds at deeper crustal levels. The sub-horizontal D₂ structures were refolded into upright folds during the subsequent late Svecofennian D₃ deformation, whereas the upright D₂ structures behaved as almost rigid blocks that caused strain partitioning into high-strain zones along the block margins. This accounts for the low cumulative strain in specific parts of the Orijärvi area. Further strain partitioning during D₄ caused reverse dip-slip movements along regional-scale shear zones. Crustal depth controlled the metamorphic grade during D₂, when local migmatisation took place at deep crustal levels. Later metamorphic overprint during D₃ deformation is evident from post-D₂ growth of sillimanite and a second generation of andalusite.Similarities in the structural patterns between the Orijärvi area and the Tampere-Vammala area (100 km to the north) suggest that irrespective of the age of the later overprint, subsequent deformation was localised along the margins of the early formed upright domains, while the low-grade rocks within the domains were preserved.  相似文献   

Experimental study of the effect of temperature on ion cluster formation using ion mobility spectrometry     

A.-K. Viitanen  T. Mattila  J.M. Mkel  M. Marjamki  O. Anttalainen  J. Keskinen 《Atmospheric Research》2008,90(2-4):115-ICNAA07

Ion mobility spectrometry offers a robust and effective technique to study ion clusters in ambient conditions. Here, we have experimentally studied the influence of temperature on the positive ion cluster formation of 2-propanol vapor in air, along with parallel measurements for n-butyl acetate vapor in air. For both of these low proton affinity compounds in the ppm concentration range, temperatures below 0 °C tend to favor formation of dimers and trimers. The measurements indicate that approximate estimations for the fractions of these n-mers (n > 1) in the ion spectra, can be obtained by classical theory for ion induced nucleation. Presence of natural background vapors however slightly blurs the data, especially for the fraction of monomers, so that accurate prediction of the fractions of n-mers in the spectra would require more accurate information on the gas composition. The findings concerning thermal behavior of ions help to understand better ion phenomena also in field conditions.  相似文献   

Plasma environment of Jupiter family comets     

A.J. Coates  G.H. Jones 《Planetary and Space Science》2009,57(10):1175-1191

As any comet nears the Sun, gas sublimes from the nucleus taking dust with it. Jupiter family comets are no exception. The neutral gas becomes ionized, and the interaction of a comet with the solar wind starts with ion pickup. This key process is also important in other solar system contexts wherever neutral particles become ionized and injected into a flowing plasma such as at Mars, Venus, Io, Titan and interstellar neutrals in the solar wind. At comets, ion pickup removes momentum and energy from the solar wind and puts it into cometary particles, which are then thermalised via plasma waves. Here we review what comets have shown us about how this process operates, and briefly look at how this can be applied in other contexts. We review the processes of pitch angle and energy scattering of the pickup ions, and the boundaries and regions in the comet-solar wind interaction. We use in-situ measurements from the four comets visited to date by spacecraft carrying plasma instrumentation: 21P/Giacobini-Zinner, 1P/Halley, 26P/Grigg-Skjellerup and 19P/Borrelly, to illustrate the process in action. While, of these, comet Halley is not a Jupiter class comet, it has told us the most about cometary plasma environments. The other comets, which are from the Jupiter family, give an interesting comparison as they have lower gas production rates and less-developed interactions. We examine the prospects for Rosetta at comet Churyumov-Gerasimenko, another Jupiter family comet where a wide range of gas production rates will be studied.  相似文献   

气相色谱法测试土壤中分段石油烃的标准化定量方法初探   总被引：2，自引：1，他引：1  

刘玉龙  黄燕高  刘菲 《岩矿测试》2019,38(1):102-111

目前土壤样品中分段石油烃的分析方法中石油烃包括的碳原子数范围和采用的校准物质不统一,造成不同实验室的量值不具有可比性。为保证不同实验室之间结果的可比性,本文尝试建立一种石油烃相邻碳原子数标准化定量方法。该方法主要包括:(1)规定了石油烃包括的碳原子数范围为气相色谱峰中正己烷和正四十碳烷之间所有的烃(含正己烷);(2)总石油烃(TPH)分为挥发性石油烃(VPH)和半挥发性石油烃(SPH),分别选取碳原子数为6～10的5个正构烷烃作为VPH校准物质,选取碳原子数为10～40的31个正构烷烃作为SPH校准物质。采用平均响应因子法或一次线性回归法,建立校准物质的峰面积-浓度的校准关系;(3)采用相邻峰标准化校准方法,逐一定量所有的目标色谱峰;(4)计算正构烷烃含量、总石油烃含量和任意分段的石油烃含量。该方法为环境样品中石油烃分析方法的标准化建设提供了数据基础。  相似文献   

Li₂SO₄溶液中离子间的缔合相互作用:基于密度泛函理论和分子动力学模拟的研究   总被引：1，自引：1，他引：0  

胡俊  夏斐斐  杨凤丽  郑纯智  房春晖  曾德文  易海波 《盐湖研究》2018,26(1):39-47

基于密度泛函理论,使用B3LYP/aVDZ方法对[Li_2SO_4(H_2O)_n]~0(n=0~10、18)水合团簇的结构和性质进行了系统地研究,并结合Car-Parrinello分子动力学(CPMD)模拟了不同浓度的Li_2SO_4溶液结构,目的在于理解在Li_2SO_4溶液中离子间缔合相互作用及可能存在的物种。研究发现,对于[Li_2SO_4(H_2O)_n]~0(n=0~10、18)水合团簇,双配位单齿螯合接触离子对结构比双配位双齿螯合接触离子对结构更稳定,溶剂共享离子对结构最不稳定。同时,CPMD模拟结果表明,在3.09和3.17 mol/kg的Li_2SO_4溶液中,双配位单齿螯合接触离子对结构仍然是主要物种。以上结果表明在饱和的Li_2SO_4溶液(3.16 mol/kg)中,Li~+和SO_4~(2-)离子间的相互缔合作用主要以双配位单齿螯合接触离子对结构的物种存在,而具有双配位双齿螯合离子对结构的物种占少数,溶剂共享离子对结构几乎不存在。  相似文献   

黄河口磷酸盐缓冲机制的研究Ⅱ.黄河口磷—钙矿物的离子平衡     

石晓勇  史致丽 《海洋与湖沼》1999,30(6):737-743

1994年5月—1995年6月,利用黄河口悬浮颗粒物,在实验室内于不同温度、盐度、磷酸盐浓度、pH值及悬浮物粒度条件下进行了悬浮物对磷酸盐的吸附和解吸模拟实验,通过水体中几种磷—钙矿物的离子平衡计算,对黄河口磷酸盐的缓冲机制进行了探讨。结果表明,黄河口现场条件下水体中钙与磷之间存在某些离子平衡,黄河口水体中磷—钙矿物的离子积受温度、悬浮物种类及粒度影响较小,而与水体盐度、磷酸盐及钙含量有关,但不足以形成磷—钙矿物沉淀;磷—钙矿物的沉淀和溶解在黄河口磷酸盐浓度的控制机制上所起的作用较小,而悬浮颗粒物表面对磷酸盐的吸附和解吸起了较大的作用。  相似文献   

拉果错盐湖卤水蒸发过程中Li⁺富集行为的分子动力学模拟          下载免费PDF全文

刘鑫  马艳芳  张志宏  付振海 《盐湖研究》2022,30(4):61-71

采用分子动力学模拟,研究了西藏拉果错盐湖卤水中阴、阳离子以及水分子间的相互作用行为。以盐湖卤水等温蒸发过程中粒子浓度变化的四个阶段为研究对象,分别计算了不同体系的扩散系数、配位数、均方位移和径向分布函数。计算结果表明,液相浓度越低时,H₂O分子对各离子之间的相互作用有抑制作用,液相中离子浓度越高时,SO₄2-易与CO₃2-竞争Li⁺形成离子对,从而影响盐湖卤水中Li⁺的富集。本文研究结果对盐湖卤水中Li⁺的迁移行为作出了机理解释,为盐湖卤水提锂的发展奠定了理论基础。  相似文献   

Effects of mineral-organic fertilizer on the biomass of green Chinese cabbage and potential carbon sequestration ability in karst areas of Southwest China     

Qibiao Sun  Yulong Ruan  Ping Chen  Shijie Wang  Xiuming Liu  Bin Lian 《Acta Geochimica》2019,(3):430-439

The karst mountain areas of Southwest China contain barren farmland soils and suffer from nutritional and water deficiencies that affect crop productivity. Hence,it is imperative to apply suitable fertilizers to restore soil fertility and maintain crop yield. The aim of this study is to investigate the effects of mineral-organic fertilizer(MOF)made of potassic rock and organic waste on the growth of crops. For this purpose, green Chinese cabbage grown using three different fertilization methods including MOF,inorganic fertilizer(IF), and a control was evaluated. We determined soil water content, agronomic characteristics,and biomass of green Chinese cabbage in different treatments. Furthermore, surface runoff from the pot experiments and soil leachate from pot experiments were collected to determine water temperature, pH, and cation and anion concentrations. The results demonstrate thatMOF can improve the soil water-holding capacity of soil,and the basic agronomic characteristics of the cabbage treated with MOF were superior to those with IF. Using MOF can promote the increase in cabbage biomass.Additionally, the concentration of inorganic carbon(largely in the form of HCO_3^-) in surface runoff water treated by MOF was higher than the other treatments, establishing carbon sequestration potential. This work provides a novel and environmentally friendly fertilization pattern in karst areas, which will improve crop yield and also increase the carbon sequestration potential of crops.  相似文献   

太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定   总被引：4，自引：0，他引：4  

史双昕  卢婉云  邵丁丁  周丽  张烃  黄业茹 《湖泊科学》2009,21(5):631-636

使用气相色谱质谱技术测定了青虾肌肉组织中的8种有机氯农药.包括六氯苯、氯丹、滴滴涕(ΣDDTs)、艾氏剂、狄氏剂、异狄氏剂、七氯和灭蚁灵,对太湖和洞庭湖15个点位29组野士青虾样品的测定结果显示,青虾肌肉组织内残留的有机氯农药主要是六氯苯和滴滴涕,六氯苯含量为nd-13.2μg/kg(湿重),滴滴涕含量为0.790-5.82μg/kg(湿重),洞庭湖青虾肌肉中有机氯农药的含量略高于太湖青虾,两湖青虾肌肉残留有机氯农药在枯水期时的含量多数大于丰水期时的含量.  相似文献   

Ion Chromatography (IC) as a Method in Studies on the Odra River Pollution with F–, Cl–, NO3–, PO43–, SO42– Ions     

R. Wjcik  W. S. Sikora  M. Strzebo&#x;ska  J. Motyka 《洁净——土壤、空气、水》1999,27(5):392-396

The paper presents the ion chromatography (IC) – DIONEX DX-100 system – in the studies on the Odra River water pollution with some inorganic anions. The precision of analysis, detection and quantification limits of each anion have been presented in order to evaluate the method. Results obtained with IC are compared with those using other analytical methods: ICP-AES for SO42–, and the argentometric titration for Cl–. It has been found that the IC method can be applied in the investigation of the anion pollution of the Odra River water: concentrations of Cl–, NO3– and SO42– can be determined with sufficient accuracy, while F– concentration, on the account of common presence of carbonate anions, can only be roughly estimated. The results have been compared with maximum permitted levels (MPL) for Polish water quality classes.  相似文献