Genesis of chlorine and sulphur in fumarolic emissions at Vulcano Island (Italy): assessment of pH and redox conditions in the hydrothermal system     

V. Di Liberto  P. M. Nuccio  A. Paonita   《Journal of Volcanology and Geothermal Research》2002,116(1-2)

Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P–T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and S_tot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite–magnetite buffer controls the hydrothermal fO₂ values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na–Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl, lowering the pH of the water. The increasing water–rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H₂S and SO₂. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.  相似文献   

Shallow seismicity, stress distribution and crustal deformation pattern in the Andaman-West Sunda arc and Andaman Sea, northeastern Indian Ocean     

M. Radha Krishna  T.D. Sanu 《Journal of Seismology》2002,6(1):25-41

Shallow seismicity and available source mechanisms in the Andaman–westSunda arc and Andaman sea region suggest distinct variation in stressdistribution pattern both along and across the arc in the overriding plate.Seismotectonic regionalisation indicates that the region could be dividedinto eight broad seismogenic sources of relatively homogeneousdeformation. Crustal deformation rates have been determined for each oneof these sources based on the summation of moment tensors. The analysisshowed that the entire fore arc region is dominated by compressive stresseswith compression in a mean direction of N23^°, and the rates ofseismic deformation velocities in this belt decrease northward from 5.2± 0.65 mm/yr near Nias island off Sumatra and 1.12 ±0.13 mm/yr near Great Nicobar islands to as much as 0.4 ±0.04 mm/yr north of 8^°N along Andaman–Nicobar islandsregion. The deformation velocities indicate, extension of 0.83 ±0.05 mm/yr along N343^° and compression of 0.19 ±0.01 mm/yr along N73^° in the Andaman back arc spreadingregion, extension of 0.18 ± 0.01 mm/yr along N125^° andcompression of 0.16 ± 0.01 mm/yr along N35^° in NicobarDeep and west Andaman fault zone, compression of 0.84 ±0.12 mm/yr N341^° and extension of 0.77 ± 0.11 mm/yralong N72^° within the transverse tectonic zone in the Andamantrench, N-S compression of 3.19 ± 0.29 mm/yr and an E-Wextension of 1.24 ± 0.11 mm/yr in the Semangko fault zone ofnorth Sumatra. The vertical deformation suggests crustal thinning in theAndaman sea and crustal thickening in the fore arc and Semangko faultzones. The apparent stresses calculated for all major events range between0.1–10 bars and the values increase with increasing seismic moment.However, the apparent stress estimates neither indicate any significantvariation with faulting type nor display any variation across the arc, incontrast to the general observation that the fore arc thrust events showhigher stress levels in the shallow subduction zones. It is inferred that theoblique plate convergence, partial subduction of 90^°E Ridge innorth below the Andaman trench and the active back arc spreading are themain contributing factors for the observed stress field within the overridingplate in this region.  相似文献   

近20年海南岛森林生态系统碳储量变化   总被引：49，自引：2，他引：49  

曹军  张镱锂  刘燕华 《地理研究》2002,21(5):551-560

热带森林在碳循环研究中有重要作用。根据目前森林碳储量的计算方法和海南森林资源二类调查数据 ,估算了不同时段的碳储量 ,并分析其动态变化特点。结果表明 :海南森林碳储量从 1979年的 30 4 5TgC增加到 1998年的 37 74TgC ,年均增加 0 36 4 5TgC ,增长率为1 19% ,是全国平均增长率的 2 5倍 ;海南森林在碳循环中起不断增强的碳汇作用 ;森林碳密度呈加速减少趋势 ,储碳潜力将很大 ;随着海南全面禁止采伐和封育等林业措施的实施 ,森林面积扩大 ,林龄结构改善 ,储碳能力将进一步提高 ,海南森林在全国或全球碳循环中的作用和社会价值与意义将日渐突出。通过对碳储量计算不确定性的分析和讨论 ,提出应加强对森林群落各层次生物量的实测与实地监测研究 ,统一计算方法 ,以提高碳储量计算的精度  相似文献   

Tracking recent recovery from eutrophication in a high arctic lake (Meretta Lake, Cornwallis Island, Nunavut, Canada) using fossil diatom assemblages   总被引：4，自引：0，他引：4  

Neal Michelutti  Marianne S.V. Douglas  John P. Smol 《Journal of Paleolimnology》2002,28(3):377-381

Meretta Lake (Resolute Bay, Cornwallis Island, Nunavut, Canada) is a high arctic lake that received raw sewage for almost 50 years from the Canadian Department of Transport Base. The lake was sampled from 1968–72 during the International Biological Programme, as part of the Char Lake Project. As the number of users at the Transport Base declined throughout the 1990s, so too did the lake's nutrient levels, and Meretta Lake is now classified as oligotrophic. A previous diatom-based paleolimnological study revealed marked species assemblage shifts coincident with sewage inputs beginning in the late 1940s; however, because the core was taken at a time when nutrient levels were still relatively high (i.e., 1993), the diatom record did not yet track any signs of recovery. In this present study, we examined fossil diatom assemblages from a sediment core taken in 2001. Our results indicate a shift to the pre-impact diatom assemblages in the most recent sediments, indicating that the paleolimnological record is tracking the decreased nutrient inputs to this high arctic lake, and confirms that no significant lags exist in these largely ice-covered lakes.  相似文献   

Source parameters of large historical (1917–1961) earthquakes, North Island, New Zealand     

Diane I. Doser  Terry H. Webb 《Geophysical Journal International》2003,152(3):795-832

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Receiver function study of the Hellenic subduction zone: imaging crustal thickness variations and the oceanic Moho of the descending African lithosphere   总被引：3，自引：0，他引：3  

X. Li  G. Bock  A. Vafidis  R. Kind  H.-P. Harjes  W. Hanka  K. Wylegalla  M. van der Meijde  X. Yuan 《Geophysical Journal International》2003,155(2):733-748

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Figure 1 Linear fitness of the index H' respectively calculated by the number or the area of the related Sus Pedodiversity analysis in Hainan Island     

ZHANG Xuelei  CHEN Jie  ZHANG Ganlin  TAN Manzhi  J.J. Ibá  ?ez 《地理学报》2003,13(2):181-186

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藏北新生代两套钾玄质火山岩系列地球化学特征   总被引：8，自引：2，他引：8  

刘燊  胡瑞忠  迟效国  李才  冯彩霞 《矿物岩石》2003,23(2):66-71

岩石学和元素地球化学特征研究表明，藏北新生代自南向北沿可可西里岩带和喀喇昆仑—玉门岩带出露有两套钾玄质系列火山岩。它们富集大离子亲石元素(LILE)和轻稀土(LREE)及明显亏损Nb—Ta—Ti，同时具有板内和岛弧(陆弧)的双重特征。源区来源于可能与俯冲带流体有关的相似交代富集地幔，成岩过程主要经历了低度(＜10％)辉石分离结晶作用，同时，源区伴有地壳物质的混染作用。  相似文献   

海南琼海烟塘梅岭铜钼矿床地质特征     

龙文国  林起玉  范庆贺  谢自甡  庄有光  杨志强 《华南地质与矿产》2003,(3):30-36

琼海烟塘梅岭铜钼矿床位于海南五指山隆起东北侧的一个“角砾岩筒”中，该“角砾岩筒”的形成受南北向、东西向构造一岩浆岩带控制，与燕山期花岗闪长岩、花岗闪长斑岩关系密切。工业矿体主要集中在岩筒边缘接触带附近，共发现大小铜、钼矿体23个，矿体多呈透镜状、脉状，全为盲矿体，埋深数十米至400余米。矿石为细脉浸染状，Cu品位0．4％～0．9％，Mo品位0．01％～0．1％。蚀变带可粗略划分为钾化带、石英-绢云母化带和青盘岩化带，可能属斑岩型矿床。  相似文献   

Temporal variations in magma composition at Merapi Volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity   总被引：1，自引：0，他引：1  

Ralf Gertisser  Jrg Keller 《Journal of Volcanology and Geothermal Research》2003,123(1-2):1

Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 ¹⁴C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO₂) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO₂) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO₂ contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO₂ range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.  相似文献