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11.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed. 相似文献
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Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure. 相似文献
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1 IntroductionAccordingtogeologicalstructure ,theGansu Ningxia Qinghaiareabelongstothenortheastmar ginofQinghai Tibetblock .Thisareahasbeenpaidmuchattentionby geo specialistsinChinaandabroadbecauseofitssignificanttectonicmovement,itsintensiveseismicity ,anditsimportanceinearth quakehazardmitigation .IntheDevelopmentPro gramonNationalKeyBasicResearchesundertheProject“MechanismandPredictionofContinentalStrongEarthquakes”,themechanismsofcontinen talstrongearthquakesarestudied ,usinghypo… 相似文献
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本文简要介绍了陆地系列地球资源卫星的轨道特征,并以陆地—5号资源卫星为例,根据南山站的座标计算出该站对陆地—5号资源卫星的可观测范围及以该站为中心的卫星的覆盖区域。 相似文献
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ENVIRONMENTAL SUSTAINABILITY AND SCENARIOS OF URBANIZATION IN ARID AREA——A Case Study in Wuwei City of Gansu Province 总被引:1,自引:0,他引:1
YOUFei LIYu DONGSuo-cheng 《中国地理科学(英文版)》2005,15(2):120-130
1IN T R O D U C T IO N The western China isfacinggrowing problems of eco- logicaland economic development. The disparitiebse- tween the socio-economy of the western and eastern China were enlarging, and the major ecologicalprob- lems stilelvolve as past(H… 相似文献
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青藏块体东北缘断层形变与中强地震 总被引:7,自引:4,他引:3
对祁连山-海原断裂带近期断层形变特征进行了初步研究,发现多场地,大范围的断层活动异常是中等强度地震发生的显著背景,并且往往与大陆地震活动的阶段性总体状况相呼应;区域形变存在明显的特征量,包括特征形态和特征时间,同一场地在不同地震前的异常特征具有重复性,但会受到背景差异显著的不同地震的影响,目前形变状况表明研究区仍具有发生中强地震的地壳运动背景。 相似文献
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Optimal deflection of NEOs en route of collision with the Earth 总被引:1,自引:0,他引:1
Recently, a method for the n-body analysis of the velocity change required to deflect a hazardous near-Earth object (NEO) was presented by Carusi et al. [Carusi, A., Valsecchi, G.B., D'Abramo, G., Boattini A., 2002. Icarus 159, 417-422]. We extent this method in order to optimize the velocity change vector instead of its along-track magnitude. From an application of both methods to a fictitious NEO we find Carusi's parallel approach to be reasonable for phases of unperturbed two-body motion. But, for orbit phases inhering third-body perturbations, i.e., for planetary close approaches or prior to a collision, the results obtained from the new method show the radial component of deflection impulse to play a major role. We show that a fivefold greater efficiency can be achieved by a deflection impulse being non-parallel to orbital velocity. The new method is applied to two possible 99942 Apophis impact trajectories in order to provide constraints for future Apophis deflection mission analysis. 相似文献