Leaching evaluation of cement stabilisation / solidification treated kaolin clay     

U.E. John  I. Jefferson  D.I. Boardman  G.S. Ghataora  C.D. Hills 《Engineering Geology》2011,(4):315

Sustainable land management often requires redevelopment of existing and often contaminated Brownfield sites over use of Greenfield or agricultural land. Stabilisation / solidification (S/S) offer a viable remediation option with particular suitability in treating heavy metal contaminants. However, uncertainties over long-term durability and previously cheap landfill disposal costs resulted in limited use in many countries. There is a need to characterise treated material and assess components containment and release, to improve S/S confidence and inform remedial design, using the evaluation of the leaching controlling mechanisms. To improve understanding of key features that will enable improvements to such designs, this paper presents an evaluation of leaching for CEM II stabilised kaolin, using the leaching behaviour of 4 main components—aluminium, silicon, calcium and sulphur. Results show no detrimental implications on chemical durability due to kaolin degradation with hydration under induced alkalinity, with increased formation of stable cementitious minerals. Availabilities for components show that aluminium and silicon had minimal leachability compared to total content, whilst calcium and sulphur show almost total leaching availability. Decreasing calcium and silicon leachability under natural chemical conditions with increased hydration duration supports the increased formation of stable cementitious products with time, using the products of kaolin dissociation.  相似文献   

Strontium and carbon isotope stratigraphy of the Late Jurassic shallow marine limestone in western Palaeo-Pacific,northwest Borneo     

《Journal of Asian Earth Sciences》2013

Strontium and carbon isotope stratigraphy was applied to a 202 m-thick shallow marine carbonate section within the Late Jurassic Bau Limestone at the SSF quarry in northwest Borneo, Malaysia, which was deposited in the western Palaeo-Pacific. Strontium isotopic ratios of rudist specimens suggest that the SSF section was formed between the latest Oxfordian (155.95 Ma) and the Late Kimmeridgian (152.70 Ma), which is consistent with previous biostratigraphy. The δ¹³C_carb values of bulk carbonate range from −0.10 to +2.28‰ and generally show an increasing upward trend in the lower part of the section and a decreasing upward trend in the upper part of the section. A comparable pattern is preserved in the δ¹³C_org isotope record. Limestone samples of the SSF section mainly preserve the initial δ¹³C_carb values, except for the interval 84–92 m, where an apparent negative anomaly likely developed as a result of meteoric diagenesis. Comparing with the Tethyan δ¹³C_carb profile, a negative anomaly in the lower SSF section can be correlated with the lowered δ¹³C values around the Oxfordian/Kimmeridgian boundary. In addition, δ¹³C_carb values of the Bau Limestone are generally ∼1‰ lower than the Tethyan values, but comparable with the values reported from Scotland and Russia, located in Boreal realm during the Late Jurassic. This suggests that either the Tethyan record or the other records have been affected by the δ¹³C values of regionally variable dissolved inorganic carbon (DIC). The Late Jurassic δ¹³C_DIC values are thought to have been regionally variable as a result of their palaeoceanographic settings. This study shows that δ¹³C chemostratigraphy of the Palaeo-Pacific region contributes to an improved understanding of global carbon cycling and oceanography during this time period.  相似文献   

广西荔浦石灰岩矿山地质环境保护与恢复治理          下载免费PDF全文

韦银泽 《山东国土资源》2013,29(3):26-28,33

目前,矿山地质灾害主要表现在崩塌、滑坡、岩溶地面塌陷、泥石流等方面,对矿区进行地质灾害的预测并根据情况提出相应防治措施,能有效避免和减轻地质灾害造成的损失;同时也维护了矿区的正常作业和人民生命和财产安全。根据广西荔浦石灰岩矿山的地质环境条件,结合矿山地质环境问题的实地调查,在综合分析的基础上进行影响评估,并有针对性地提出了恢复治理措施。  相似文献   

Carbon, oxygen, and strontium isotope geochemistry of carbonate rocks of the upper Miocene Kudankulam Formation, southern India: Implications for paleoenvironment and diagenesis   总被引：2，自引：0，他引：2  

John S. Armstrong-Altrin  Yong Il Lee  Richard H. Worden 《Chemie der Erde / Geochemistry》2009,69(1):45-60

The carbon, oxygen, and strontium isotope compositions of carbonate rocks from the upper Miocene Kudankulam Formation, southern India, were measured to understand palaeoenvironment and carbonate diagenesis of this formation. Both carbon and oxygen isotope ratios of various carbonate phases including whole rocks, ooids, molluscan mold-fill and sparry pore-fill calcite cements are depleted in ¹⁸O and ¹³C compared to those of contemporaneous seawater, indicating that the Kudankulam carbonates underwent extensive meteoric diagenesis. Based on δ¹³C and δ¹⁸O values for sparry calcite cements (pore-fill and molluscan mold-fill) formed in the meteoric diagenetic realm (δ¹³C from −7.8‰ to −6.0‰ and −9.0‰ to −7.0‰; δ¹⁸O from −9.2‰ to −6.5‰ and −9.4‰ to −2.6‰, respectively), it is interpreted that the diagenetic system was open and was proximal to the vadose water recharge zone. The negative δ¹⁸O values of various carbonate components (about −9.4‰ to −4.1‰ for whole rocks; about −8.4‰ to −2.6‰ for ooids) suggest that during the late Miocene the paleoclimate of the study area was humid, unlike today, probably due to the intense Indian monsoon system. The carbon isotope compositions (−7.9‰ to −3.6‰ for whole rocks; −4.9‰ to −1.5‰ for ooids) are consistent with the interpretation that the paleo-ecosystem comprised a significant proportion of C₄ type plants, supporting a scenario of expansion of C₄ plants during the late Miocene in the Indian subcontinent as far south as the southern tip of India. The ⁸⁷Sr/⁸⁶Sr ratios of the Kudankulam carbonates (0.70920 to 0.72130) are much greater than those of the contemporaneous or modern seawater (between 0.7089 and 0.7091) and show a general decrease up-sequence. Such high Sr isotope ratios indicate significant radiogenic ⁸⁷Sr influx to the system from the Archean rocks exposed in the drainage area, implying that the deep-seated Archean rocks were already exposed in southern India by the late Miocene.  相似文献   

双溪堆积体的成因及其主要工程地质特征   总被引：1，自引：0，他引：1  

陈立德  陈州丰  邵长生 《工程地质学报》2009,17(3):308-312

双溪堆积体是大宁河上游广泛发育的、钙质胶结的碎石土堆积体,其成因与大宁河流域新近系不同时期发育的崩塌、滑坡和泥石流有密切的关系。在大宁河沿岸的双溪、中坝、神基坪一带,志留系泥岩粉砂岩等易风化软弱碎屑岩构成斜坡下部相对较缓的部位,二叠系或三叠系相对坚硬的灰岩则形成斜坡上部高陡的崖坡,坡脚则广泛分布着这种钙质胶结的双溪堆积体。  相似文献   

Precise Seismic Substructural Model of the Eocene Chorgali Limestone in the Turkwal Oil Field,Central Potwar,Pakistan     

Khawar Ashfaq AHMED  Sarfraz KHAN  Mahmood SULTAN  UMAIR Bin Nisar  Kalim ULLAH  Al -Hseinat MU’AYYAD 《《地质学报》英文版》2019,93(6):1711-1720

The precise seismic substructural interpretation of the Turkwal oil field in the Central Potwar region of district Chakwal of Pakistan has been carried out. The research work was confined to the large fore-thrust that serves as an anticlinal structural trap through ten 2D seismic lines. A precise seismic substructural model of the Eocene Chorgali Limestone with precise orientation of thrust and oblique slip faults shows the presence of a huge fracture, which made this deposit a good reservoir. The abrupt surface changes in dip azimuth for the Eocene Chorgali Limestone verifies the structural trends and also the presence of structural traps in the Turkwal field. The logs of three wells (Turkwal deep X-2, Turkwal-01 and Fimkassar-01) were analyzed for petrophysical studies, well synthetic results and generation of an Amplitude Versus Offset (AVO) model for the area. The AVO model of Turkwal deep X-2 shows abrupt changes in amplitude, which depicts the presence of hydrocarbon content. Well correlation technique was used to define the overall stratigraphic setting and the thickness of the reservoir formation in two wells, Turkwal-01 and Turkwal deep X-2. The Eocene Chorgali Limestone in Turkwal-01 is an upward thrusted anticlinal structure and because of the close position of both wells to the faulted anticlinal structure, its lesser thickness differs compared to Turkwal deep X-2. The overall results confirm that the Turkwal field is comparable to several similar thrust-bound oil-bearing structures in the Potwar basin.  相似文献   

Enigmatic sedimentary–volcanic successions in the central European Variscides: a Cambrian/Early Ordovician age for the Wojcieszów Limestone (Kaczawa Mountains,SW Poland) indicated by SHRIMP dating of volcanic zircons     

Ryszard Kryza  Jan Zalasiewicz  Nikolay Rodionov 《Geological Journal》2008,43(4):415-430

Metamorphosed volcanic and sedimentary successions in the central European Variscides are, in many areas, poorly biostratigraphically constrained, making palaeotectonic interpretations uncertain. In such instances, geochronological data are crucial. Sensitive high resolution ion microprobe (SHRIMP) dating of volcanic zircons from a quartz–white mica schist (interpreted as deformed metavolcaniclastic/epiclastic rock) within the stratigraphically controversial Wojcieszów Limestone of the Kaczawa Mountains (Sudetes, SW Poland), near to the eastern termination of the European Variscides, has yielded an age of 498 ± 5 Ma (2σ error), corresponding to late Cambrian to early Ordovician magmatism in that area and constraining the depositional age of the limestones. The new SHRIMP data are not consistent with the recent revision of the age of the Wojcieszów Limestone based on Foraminifera findings that ascribed them to a Late Ordovician—Silurian or even younger interval. They are though, consistent with sparse macrofossil data and strongly support earlier interpretations of the lower part of the Kaczawa Mountains succession as a Cambrian–Early Ordovician extensional basin‐fill with associated initial rift volcanic rocks, likely emplaced during the breakup of Gondwana. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

北京石花洞地区水系氢氧同位素及氚含量研究──石花洞研究系列之一   总被引：9，自引：0，他引：9       下载免费PDF全文

李红春  赵树森 《地震地质》1996,18(4):325-328

北京石花洞地区水系的δＤ平均值为（－６５．４±３．０）‰（ＳＭＯＷ），δ１８Ｏ平均值为（－９．４±０．３）‰（ＳＭＯＷ），氚含量平均值为（３０．８±４．５）ＴＵ。石花洞洞内滴水是由地表水很快下渗得来，受古老地下水的混合作用很小。因此，洞内滴水的稳定同位素组成能够灵敏地反映地表水同位素组成（即重量加权的年平均雨水的同位素组成）的变化。影响洞内滴水的稳定同位素组成的因素主要是年平均气温、年降雨量以及降水气团的来源的变化。利用高分辨率的洞穴碳酸盐的稳定同位素记录．可以建立以湿度变化为主的古气候信息．尤其是我国季风气候的变化历史  相似文献   

粤北石灰岩地区降水资源的估算     

陈新光  植石群 《热带地理》1996,16(3):220-225

本文利用粤北石灰岩地区气象站和水文有关的降水资料、经纬度资料和海拔高度资料进行了统计分析，建立了该区域１、４、７、１０月和年降水量的推算模式。经统计检验，效果显著。  相似文献   

Stone chute development on a limestone scree     

Robert J. Loughran  Ann I. Loughran 《地球表面变化过程与地形》1979,4(2):191-197

The modification of limestone scree slopes in North Yorkshire takes the form of downslope trains of finer stones. These features, termed stone chutes, usually coincide with a narrow defile in the limestone scar above. Investigations of four stone chutes below Raven Scar in Twisleton Dale revealed intermittent downslope movement of stones. On these coarse limestone screes, where there is insufficient fine material for debris flow formation, stone chutes are the visible evidence of slope evolution.  相似文献