中太平洋YJA海山富钴结壳矿物组成与元素地球化学   总被引：4，自引：3，他引：1  

胡大千  初凤友  姚杰 《吉林大学学报(地球科学版)》2006,36(1):32-37

研究样品采自马尔库斯（MARCUS）海脊YJA海山。利用等离子光谱、等离子质谱、X-射线衍射、红外光谱、场发射电镜等分析测试方法,对富钴结壳中不同构造层的矿物组成和元素地球化学进行了研究。该结壳为一大型板状新结壳,矿石矿物是水羟锰矿,脉石矿物是石英、斜长石、磷灰石等,微量矿物有蒙脱石、高岭石、钠沸石、水黑云母、片沸石等。从结壳的底部构造层到顶部构造层,TMn,Ni,Cu, Ba,Zn等元素的质量分数逐渐减少,TFe逐渐增加,Co变化不大;在相对疏松的构造层中,Si,Al,K,Na,Ca,Mg,Ti,P,Li,Rb等元素相对富集;结壳的稀土元素总量是1 982.27×10^-6,Ce具明显的正异常。不同构造层稀土元素的演化趋势是：Ce与Mn等元素相同,其他稀土元素（Y除外）与Fe等相似。  相似文献   

Sm–Nd geochronology and petrography of garnet pyroxene granulites in the northern Sulu region of China and their geotectonic implication     

Mingguo Zhai  Bolin Cong  Jinghui Guo  Wenjun Liu  Yonggang Li  Qingchen Wang 《Lithos》2000,52(1-4):23-33

Abundant garnet-bearing granulite lenses are widely distributed in the northern part of the Sulu region and adjacent areas. They are possibly re-metamorphosed high-pressure metamorphic rocks. On the basis of detailed petrographic study, samples WD01, WD04 and ML06 from Laixi and Wendeng were identified as high-pressure granulites, and WH1 from Weihai as an original coesite-bearing eclogite. Three high-pressure granulite samples give mineral-WR isochron ages of 1846±76, 1743±79 and 1752±30 Ma. TDM ages are 3.3, 3.0 and 2.8 Ga. The Sm–Nd mineral-WR isochron ages are interpreted to date as the metamorphic resetting within the medium-pressure granulite facies, representing an isotopic re-homogeneity during uplifting of the high-pressure granulites from deep continent crust. It is important that Sm–Nd chronological characteristics are the same as Archaean high-pressure granulites in the North China craton. However, sample WH1 from Weihai demonstrates abnormal Sm–Nd characteristics. Its whole rock _Nd (0) value is +129. TDM age is 1.3 Ga, and constrains the minimum age of re-metamorphosed eclogite protolith formation to the mid-Proterozoic. This result is identical to those reported by Jahn (1994), showing complicated processes of metamorphism and metasomatism. The data in this paper provide further evidence to define the boundary between the North China craton and UHPM belt in eastern Shandong and to understand the geotectonic nature of the boundary.  相似文献   

Binary gas adsorption/desorption isotherms: effect of moisture and coal composition upon carbon dioxide selectivity over methane   总被引：6，自引：0，他引：6  

C. R. Clarkson  R. M. Bustin 《International Journal of Coal Geology》2000,42(4)

The effect of coal moisture content and composition upon methane/carbon dioxide mixed gas adsorption characteristics is investigated. Separation factors are used to quantify the relative adsorption of carbon dioxide and methane. Experimental data indicate that carbon dioxide separation factors vary slightly between coal lithotypes, but the effects of variable coal composition and moisture upon selective adsorption are difficult to isolate. Model predictions based upon single-component isotherms show that although some variability in carbon dioxide selectivity exists for different coal types, there is no clear relationship between coal composition and carbon dioxide selectivity. Model predictions also indicate that coal moisture decreases carbon dioxide selectivity. The ideal adsorbed solution (IAS) theory and the extended Langmuir model differ substantially in their ability to predict binary gas adsorption behaviour. Comparison of model predictions to experimental data demonstrates that IAS theory, in conjunction with the Dubinin–Astakhov single-component isotherm equations are more accurate for the prediction of mixed gas desorption isotherms collected in this study than the extended Langmuir. IAS predictions, however, are strongly dependent upon the choice of pure gas isotherm equation.  相似文献   

Isotopic composition of xenon in petroleum from the shell bullwinkle field     

J. Nuzzo  M. Hyman  M. W. Rowe  M. N. Rao  R. L. Palma  J. Westrich 《Journal of Earth System Science》2000,109(1):89-94

We have measured the abundance and isotopic composition of xenon in petroleum samples from the Shell Bullwinkle Field off the coast of Louisiana. We used an oxidation and purification procedure designed to insure complete extraction and clean up of xenon from the petroleum. The xenon isotopic composition was found to be similar to the atmospheric value for one petroleum sample. While the results of the second sample suggest possible enrichment of the heavier isotopes, the errors associated with these excesses preclude a definitive statement to that effect. No monoisotopic enrichment in¹²⁹Xe was detected in either sample, the presence of which might have allowed us to deduce the petroleum age. Our results represent only the second xenon measurement from petroleum, and the concentrations are within the range of values published in the earlier report.  相似文献   

准噶尔盆地阜东斜坡区侏罗系沉积特征   总被引：2，自引：0，他引：2       下载免费PDF全文

张满郎  朱筱敏  张琴 《沉积与特提斯地质》2000,20(4):60-70

通过对准噶尔盆地阜东斜坡区侏罗系的沉积背景,沉积岩成分,结构、构造及岩性序列等综合研究表明,该区侏罗系具有较好的旋回性,可划分为６个沉积层序和两个构造层序,侏罗系沉积物具有较低的成分成熟度和中等结构成熟度,粒度概率图及沉积构造均显示其具有牵引流沉积特征及三角洲沉积序列。在研究区侏罗系发育南、北两大特源区及方向的水系,据此可识别出辫状河,辫状河三角洲、曲流河、正常三角洲、滑塌浊积扇和湖泊等多种沉积体  相似文献   

铼-锇同位素体系介绍及其在矿床学研究中的应用   总被引：1，自引：0，他引：1  

江思宏  聂凤军  赵省民 《内蒙古地质》2000,(2)

Re Os同位素体系是目前唯一能够直接对矿石矿物 (硫化物和氧化物 )进行测年的同位素方法 ,利用 1 87Os/ 1 88Os比值还可以示踪成岩物质与流体的来源及其随后的演化历史 ,因此在矿床学研究及矿床勘探中正扮演着越来越重要的角色。本文对 Re Os同位素测年方法及其在矿床学研究中的应用作了简要介绍。  相似文献   

Sulfur Isotopic Study of the Toyoha Deposit, Hokkaido, Japan Comparison between the Earlier-Stage and the Later-Stage Veins     

Morihisa HAMADA  Akira IMAI 《Resource Geology》2000,50(2):113-122

Abstract: The sulfur isotopic ratios (δ³⁴S) of ore minerals from the Toyoha deposit, Hokkaido, one of the largest Pb–Zn–Ag polymetallic vein-type deposits in Japan, were studied. More than 90% of the δ³⁴S values of the studied sulfide minerals collected from the Toyoha deposit range from +5 to +9%, with an average of approximately +7% irrespective of the mineral species, veins, elevations, depth, mineralization stages and mineral assemblages. Relatively uniform δ³⁴S values obtained in this study suggest that the reduced aqueous sulfur species predominated over the oxidized sulfur in the ore solution throughout the mineralization stages. Thus, the source of sulfur for the ore sulfides is postulated to be magmatic.
The temperature obtained from the fluid inclusion study and the temperature of the sulfur isotopic geothermometer are not consistent. This suggests that each mineral precipitated under disequilibrated conditions with respect to the sulfur isotope.
The change in redox conditions presumably encountered between the mineralization stages did not account for the isotopic fluctuations since the isotopic exchanges between the oxidized and reduced aqueous sulfurs are much slower than the rate of oxidation of the ore solution.  相似文献   

不同采出程度下石油组分变化特征   总被引：6，自引：1，他引：5  

刘晓艳  李宜强  冯子辉  李景坤  郭树岐 《沉积学报》2000,18(2):324-326

利用GHM烃分析仪对水驱模拟实验过程中不同阶段的采出原油进行分析,研究其原油组成的变化规律,探索原油组成与采出程度之间的内在关系。实验表明 :原油的采出程度与采出流体PV数之间具有良好的对应关系;随着采出程度逐渐提高,原油中正构烷烃的碳数范围及主峰碳数逐渐后移,原油的轻 /重比值呈现降低趋势。实验还证明,某些在空间上呈圆柱型、具有规则支链的分子比相近碳数的直链分子更容易被驱出。该项研究对于从微观角度深入探索驱油机理、提高原油采收率具有实际意义。  相似文献   

云开元古宙眼球状花岗岩Sm—Nd和Rb—Sr同位素体系定年及其动力学意义   总被引：10，自引：3，他引：7  

彭松柏张业明  战明国陈富文　邱瑞照 《岩石学报》2000,16(1):99-105

对云开核部韧性-流变剪切变形眼球状花岗岩石样品进行了全岩Sm-Nd、Rb-Sr同位素年龄测定,获得1414±68Ma的Sm-Nd等时线和490±36Ma的Rb-Sr等时线年龄,它们分别代表这套花岗岩的形成时代和加里东期韧性-流变剪切部分熔融构造热事件发生时间,表明云开地区不仅在加里东期发生造山运动,而且在中元古晚期发生了更为重要的构造—岩浆造山运动,其时代与全球性的格林威尔造山运动时间可以对比。  相似文献   

孔兹岩系——山西吕梁地区界河口群的年代学和地球化学   总被引：35，自引：14，他引：21  

万渝生耿元生  沈其韩张如心 《岩石学报》2000,16(1):49-58

吕梁地区界河口群主要由变泥砂质岩石和一定数量的大理岩及少量斜长角闪岩等类岩石组成。7个变泥砂质岩石样品分析,ΣREE=152～322 μg/g,Eu/Eu  相似文献