Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Modelling linear wave transformation induced by dissipative structures—Random waves     

R. Silva  M.A. Losada  P. Salles 《Ocean Engineering》2006,33(16):2174-2194

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.  相似文献   

一种污水排海的近远区计算与控制方法──以大亚湾水容量计算及污水排海为例     

韩保新  彭海君  曾小清  胡康萍  吕先林 《热带海洋学报》1996,(4)

针对点容量计算中混合区限制的要求，采用了动量积分法、经验公式法和有限差分法，分别对污水排放后可能引起的近区、过渡区和远区的污水浓度变化进行了模拟预测，并就一定的限制性条件对容量点近区、高浓度混合区及容量点远区影响范围进行了分析。在大亚湾水容量计算及污水排海规划中的应用表明，该法具有计算机时较省、精度相对较高等优点。  相似文献   

柴达木盆地新构造运动主要特征与成因机制   总被引：10，自引：0，他引：10  

杨明慧 《海洋地质与第四纪地质》1997,17(3):71-78

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩  相似文献   

我国海啸灾害及预警现状与建议   总被引：8，自引：1，他引：8  

叶琳  于福江  吴玮 《海洋预报》2005,22(Z1):147-157

本文给出了海啸定义及其它有关概念与术语,简要给出了我国及全球的海啸灾害.全面介绍了我国海啸监测能力、预警现状、研究成果以及有关国际合作的情况,重点介绍了我国自主研制的海啸数值模式,利用该模式我们模拟了2004年12月26日发生在印度洋大海啸以及假想的发生在我国南海的海啸对周边国家的影响.对海啸预警中存在的问题及未来急需开展的工作,作者也将一一给予阐述.  相似文献   

Applying an alternative method of echo-integration     

Aksland  Magnar 《ICES Journal of Marine Science》2006,63(8):1438-1452

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Time changes in fishing power in the Danish cod fisheries of the Baltic Sea     

Marchal  Paul; Nielsen  J. Rasmus; Hovgard  Holger; Lassen  Hans 《ICES Journal of Marine Science》2001,58(1):298-310

  相似文献   

胶州湾营养盐的现状和变化   总被引：28，自引：3，他引：28  

沈志良 《海洋科学》1997,21(1):60-64

报道了１９９１年５月至１９９４年２月１２个航次胶州湾ＮＯ３－Ｎ，ＮＯ２－Ｎ，ＮＨ４－Ｎ，ＰＯ４－Ｐ和ＳｉＯ３－Ｓｉ的时空分布基本特征，６０年代于至９０年代的变化表明，胶州湾营养盐的浓度和分布已发生显变化。尤其从６０年代至８０年代，３０年来，胶州湾中东部水城ＰＯ４－Ｐ，ＮＯ３－Ｎ和ＮＨ４－Ｎ浓度分别增加２．２，７．３和７．１倍，ＴＯＮ浓度也增加了３．５倍，ＴＩＮ／ＰＯ４－Ｐ从１０增加至２４．２；Ｔ  相似文献   

对虾体内氯霉素含量测定方法的研究   总被引：1，自引：0，他引：1  

李兰生  王勇强 《中国海洋大学学报(自然科学版)》1995,(3)

应用ＨＰＬＣ技术建立常用药物氯霉素的虾体动力学研究方法。该方法的特点是：与微生物法、比色法、气相色谱法、荧光法及免疫法比较．测试准确、快速且灵敏度高。应用该方法可以从虾体内的血液、肌肉、肝胰脏、肠胃中分离出被虾吸收的氯霉素，并定量测定。在１—５０μｇ／ｍｌ范围内线性关系相关系数为０．９９９５。  相似文献   

琼州海峡岸礁潮间带生物   总被引：14，自引：0，他引：14  

王丽荣  陈锐球  赵焕庭 《台湾海峡》2003,22(3):286-294

本文记录了2000年7月琼州海峡西口雷州半岛灯楼角珊瑚岸礁调查采集的25种造礁石珊瑚，以及栖息于湖间带的7类39科88种底栖生物，其大多数种类属于印度-西太平洋热带区系。优势类群是软体动物和节肢动物。珊瑚礁段底栖生物的平均生物量、栖息密度和多样性值分别为1173．30g／m^2，790．0个／m^2和5．69，由于造礁石珊瑚的存在为其他底栖生物提供了良好的生态环境，从而丰富了本区底栖生物的种类组成、数量、分布和群落结构。  相似文献