绿岩中金淋滤作用的实验研究   总被引：7，自引：0，他引：7  

刘玉山  田军 《地质学报》1992,66(4):362-370

在200—550℃和60MPa条件下,以氯化物溶液对绿岩中金进行了淋滤实验,部分实验控制了氧逸度。实验结果显示,金的淋滤率与温度、溶液成分、酸碱度及氧逸度有关。在氧化和酸性溶液的实验中,淋滤率达50％以上。已查明金的淋滤作用受岩石中金溶解形成氯络合物的反应制约。因此,笔者认为花岗岩浆活动派生的酸性氯化物溶液话化迁移了绿岩中的金并富集成矿。  相似文献   

陕西商县蔷薇辉石玉石矿床地质、工艺性质及成因   总被引：1，自引：0，他引：1  

李靠社 《陕西地质》1992,(2)

陕西商县蔷薇辉石(粉翠)矿床是陕西省首次发现并评价的玉石矿床。蔷薇辉石产于宽坪群四岔口组中段下部二云石英片岩所夹的含锰石英白云石大理岩、含锰石英岩等含锰岩中。矿体既成层分布又相对集中。粉翠玉料质优且加工工艺性能良好。蔷薇辉石矿床的形成主要经历了沉积期和区域变质期两大阶段。成因类型属变质岩型低温变质相蔷薇辉石矿床。  相似文献   

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren     

M. Sager  W. Vogel 《洁净——土壤、空气、水》1993,21(1):21-32

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.  相似文献   

同仁双朋西金矿浮选尾矿中提铜扩大试验的研究          下载免费PDF全文

龙光明  康永峰 《盐湖研究》2000,8(2):22-28

在小试的工艺基础上 ,对双朋西金矿浮选后的尾矿进行铜、金回收扩大试验。对铜的浸取试验结果表明 ,本工艺对该尾矿具有较高的铜浸取率和回收率  相似文献   

Silica fume stabilization of an expansive clay subgrade and the effect of silica fume-stabilised soil cushion on its CBR     

B. R. Phanikumar  Jagapathi Raju m  Ramanjaneya Raju e 《Geomechanics and Geoengineering》2020,15(1):64-77

ABSTRACT

Expansive soil subgrades, which are subjected to dual swell-shrink problem consequent upon absorption and evaporation of water, need to be improved by chemical stabilization or compacted cushion or geosynthetic reinforcement in order that pavements constructed over them are even, stable and safe. This paper presents extensive experimental data on plasticity, free swell index (FSI) and compaction characteristics of a highly swelling expansive clay stabilized with varying silica fume contents. In another series of tests on a laterite soil to be used as a cushion over the expansive clay subgrade, plasticity properties, compaction characteristics and strength characteristics were determined at varied silica fume contents. Further, CBR of the expansive clay subgrade was determined in the laboratory stabilizing it with varied silica fume contents and providing a cushion of 50 mm thickness of silica fume-stabilized lateritic soil. Liquid limit (LL), plasticity index (PI) and free swell index (FSI) of the expansive clay decreased with increasing silica fume contents. The compaction and strength characteristics of both the soils improved with silica fume stabilization. The CBR of the expansive clay provided with silica fume-stabilized cushion improved significantly.  相似文献   

Analytical perspective on trace element species of interest in exploration   总被引：1，自引：0，他引：1  

Gwendy E. M. Hall 《Journal of Geochemical Exploration》1998,61(1-3)

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   

P–Y Curves for Piles Under Seismic Lateral Loads     

M.P. Romo  E. Ovando-Shelley 《Geotechnical and Geological Engineering》1998,16(4):251-272

This paper describes an experimentally based procedure for building dynamic P–Y curves for clays from the Campeche sound in the Gulf of Mexico and for Mexico City clays. Cyclic triaxial and resonant column tests were used to derive hyperbolic stiffness–strain and damping–strain functions that depend on soil plasticity and on relative consistency. The dynamic P–Y curves incorporate these functions and also include hysteretical and geometrical damping characteristics of the pile–soil system; they can be used directly in dynamic interaction analyses of structure–pile–soil systems in the time or the frequency domains. Usual practice relies on pseudo static formulations and a simplified alternative to include P–Y curves in this kind of analysis is also proposed, which is essentially the same as the dynamic ones but does not include radiation or hysteretical damping.  相似文献   

软岩的强度—变形—时间之间关系的试验分析   总被引：6，自引：4，他引：2  

廖红建  赵树德 《岩土力学》1998,19(2):8-13

对软岩和有不连续面的软岩试样进行一系列固结不排水三轴压缩和蠕变试验,测定并分析了它们在正常固结和超固结状态下的应变软化性状、蠕变特性和残余强度的变化规律。探讨了软岩中存在的不连续面对应力－应变关系、残余强度特性和蠕变应变速率的影响。  相似文献   

粘土矿物研究在塔里木盆地石油勘探中的应用   总被引：2，自引：1，他引：1  

孙玉善  杨帆 《现代地质》1998,12(2):269-276

以塔里木盆地粘土矿物的分布特征及其组合形式、演化与形成机理为依据,探讨了粘土矿物在地层划分对比中的应用及其与有机质热演化、成岩阶段的关系和对储层物性的影响。研究表明,在侏罗系和白垩系两个不同古环境中形成的粘土矿物及其组合特征,为地层对比提供了一定的证据。泥岩中伊利石／蒙皂石间层中蒙皂石含量的纵向变化与有机质热演化及成岩阶段的关系不大。对储层物性影响不大但有利于储集性能的是以高岭石为主的粘土矿物组合类型及粘土矿物的早期自生（伊利石／蒙皂石间层矿物）衬垫式以及非自生（伊利石）衬垫式产状。  相似文献   

The impact of the parking situation in shopping centres on store choice behaviour     

Peter van der Waerden  Aloys Borgers  Harry Timmermans 《GeoJournal》1998,45(4):309-315

The article discusses the effects of changing the parking situation in the surrounding of shopping centres on consumers store choice behaviour. To get insight into these effects a hierarchical logit model of parking lot and store choice behaviour is estimated and validated. The research is based on before-and-after data of supermarket visitors collected in a major regional shopping centre in a suburban area in The Netherlands. The model is estimated using the before data. At the level of the supermarkets the estimated hierarchical logit model performs very well. The model is less accurate at the level of parking lots but still performs satisfactory. Significant attributes are a constant representing the characteristics of the supermarket, the distance between supermarket and parking lot, the number of parking spaces per parking lot, the location of the parking lot vis-à-vis the origin of the consumer, and the availability of supermarket trolley facilities at the parking lot. Validating the model by reproducing the after data yields less satisfactory results. Especially the model does not perform very well on predicting parking lot choice. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献